Process to Remove Dissolved AlCl3 from Ionic Liquid
    41.
    发明申请
    Process to Remove Dissolved AlCl3 from Ionic Liquid 有权
    从离子液体中除去溶解的AlCl3的工艺

    公开(公告)号:US20100130799A1

    公开(公告)日:2010-05-27

    申请号:US12324570

    申请日:2008-11-26

    Abstract: Disclosed herein are processes in which precipitation permits removal of metal halides (e.g. AlCl3) from ionic liquids. After precipitation, the precipitated metal halides can be physically separated from the bulk ionic liquid. More effective precipitation can be achieved through cooling or the combination of cooling and the provision of metal halide seed crystals. The ionic liquids can be regenerated ionic liquid catalysts, which contain excess metal halides after regeneration. Upon removal of the excess metal halides, they can be reused in processes using ionic liquid catalysts, such as alkylation processes.

    Abstract translation: 本文公开了沉淀允许从离子液体除去金属卤化物(例如AlCl 3)的方法。 沉淀后,沉淀的金属卤化物可以与本体离子液体物理分离。 通过冷却或冷却和提供金属卤化物晶种可以实现更有效的沉淀。 离子液体可以是再生后再生的离子液体催化剂,其含有过量的金属卤化物。 在去除过量的金属卤化物时,它们可以在使用离子液体催化剂的方法中再利用,例如烷基化方法。

    Process for upflow fixed-bed hydroprocessing of fischer-tropsch wax
    42.
    发明授权
    Process for upflow fixed-bed hydroprocessing of fischer-tropsch wax 有权
    费托蜡的上流固定床加氢处理工艺

    公开(公告)号:US06359018B1

    公开(公告)日:2002-03-19

    申请号:US09698392

    申请日:2000-10-27

    CPC classification number: C10G49/00

    Abstract: An integrated process for producing a liquid hydrocarbon stream from Fischer-Tropsch hydrocarbon product without having to remove particulate contaminants such as catalyst fines from hot Fischer-Tropsch wax is disclosed. The process involves performing Fischer-Tropsch synthesis, preferably under conditions which favor formation of wax and heavy products (i.e., using a catalyst with high chain growth probabilities), and obtaining a waxy heavy fraction including particulate contaminants. The fraction is subjected to hydroprocessing conditions, preferably upflow hydroprocessing conditions, using a catalyst bed which, through judicious selection of hydroprocessing catalysts and/or flow conditions, permits passage of the particulate contaminants. The particulates are then removed from the upgraded liquid product, for example by filtration, distillation and/or centrifugation. Removal of the particulate contaminants from the upgraded liquid hydrocarbon products is significantly easier than removing the particulates from the unprocessed waxy heavy products.

    Abstract translation: 公开了一种用于从费 - 托烃产物生产液态烃流的综合方法,而不必从热的费托蜡中除去诸如催化剂细粒的微粒污染物。 该方法包括进行费 - 托合成,优选在有利于形成蜡和重产物的条件下(即,使用具有高链生长概率的催化剂),并获得包括颗粒污染物的蜡质重馏分。 使用催化剂床进行加氢处理条件,优选上流加氢处理条件,催化剂床通过明智选择加氢处理催化剂和/或流动条件允许颗粒污染物通过。 然后将微粒从升级的液体产物中除去,例如通过过滤,蒸馏和/或离心。 从升级的液体烃产品中除去颗粒污染物比从未加工的蜡质重质产物中除去颗粒更容易。

    Flow distribution device for downflow catalytic reactors
    46.
    发明授权
    Flow distribution device for downflow catalytic reactors 有权
    用于下流式催化反应器的流量分配装置

    公开(公告)号:US08211375B2

    公开(公告)日:2012-07-03

    申请号:US12575334

    申请日:2009-10-07

    Abstract: The invention is a fluid distribution device for coupling with a fluid distribution conduit or chimney for improving the distribution of downwardly flowing poly-phase mixture including at least one gas phase and at least one liquid phase, above at least one catalyst bed of granular solid catalytic material. The fluid distribution device for receiving the liquid and gas phases has one or more openings in the top and/or upper portion of its height through which a gas phase can enter and has a gas conduit that opens to a mixing cavity within the device. The fluid distribution device further comprises one or more lateral openings for liquid ingress. The lateral opening or openings allow the liquid to enter a liquid conduit that opens to the internal mixing cavity. The mixing cavity allows intimate contact between the liquid and gas phases. Therefore the flow distribution device of the invention provides improved tolerance for tray out of levelness.

    Abstract translation: 本发明是用于与流体分配导管或烟囱耦合的流体分配装置,用于改善向下流动的多相混合物的分布,包括至少一个气相和至少一个液相,至少一个颗粒状固体催化剂催化剂床上方 材料。 用于接收液相和气相的流体分配装置在其高度的顶部和/或上部具有一个或多个开口,气相可通过该开口进入,并具有通向装置内的混合腔的气体导管。 流体分配装置还包括用于液体进入的一个或多个横向开口。 侧向开口或开口允许液体进入通向内部混合腔的液体导管。 混合腔允许液相和气相之间的紧密接触。 因此,本发明的流量分配装置提供了提高盘的平坦度的容限。

    Liquid-liquid separation process via coalescers
    49.
    发明授权
    Liquid-liquid separation process via coalescers 有权
    通过聚结器进行液 - 液分离

    公开(公告)号:US08067656B2

    公开(公告)日:2011-11-29

    申请号:US12324601

    申请日:2008-11-26

    CPC classification number: C07C7/00 B01D17/045 B01J31/0277 B01J31/40 Y02P20/584

    Abstract: A process for separating an ionic liquid from hydrocarbons employs a coalescer material having a stronger affinity for the ionic liquid than the hydrocarbons. The coalescer material can be a high surface area material having a large amount of contact area to which ionic liquid droplets dispersed in the hydrocarbons may adhere. The process includes feeding a mixture comprising ionic liquid droplets dispersed in hydrocarbons to a coalescer comprising the coalescer material. The process further includes a capture step involving adhering at least a portion of the ionic liquid droplets to the coalescer material to provide captured droplets and a coalescing step involving coalescing captured droplets into coalesced droplets. After the capture and coalescence steps, the coalesced droplets are allowed to fall from the coalescer material to separate the ionic liquid from the hydrocarbons and provide a hydrocarbon effluent.

    Abstract translation: 从烃中分离出离子液体的方法采用了比烃类对离子液体具有更强亲合力的聚结剂材料。 聚结器材料可以是具有大量接触面积的高表面积材料,其中分散在烃中的离子液滴可以粘附到该表面积材料上。 该方法包括将包含分散在烃中的离子液滴的混合物进料到包括聚结器材料的聚结器。 该方法还包括捕获步骤,其包括将离子液滴的至少一部分粘附到聚结器材料以提供捕获的液滴,以及聚集步骤,其将捕获的液滴聚结成聚结的液滴。 在捕获和聚结步骤之后,使聚结的液滴从聚结器材料中落下,以将离子液体与烃分离并提供烃流出物。

    METHOD OF FEEDING REACTANTS IN A PROCESS FOR THE PRODUCTION OF ALKYLATE GASOLINE
    50.
    发明申请
    METHOD OF FEEDING REACTANTS IN A PROCESS FOR THE PRODUCTION OF ALKYLATE GASOLINE 审中-公开
    在生产烷基醇汽油的方法中提供反应物的方法

    公开(公告)号:US20110282114A1

    公开(公告)日:2011-11-17

    申请号:US12780452

    申请日:2010-05-14

    Abstract: This application provides a process for the production of alkylate blending components, comprising introducing a hydrocarbon feed stream comprising an olefin to an orifice of a nozzle, at a close distance from the orifice; and wherein the nozzle dispenses a mixture of one or more recirculated streams and the hydrocarbon feed stream through a throat of the nozzle to make alkylate gasoline blending components. This application also provides a process unit for the production of alkylate gasoline, comprising: a) a nozzle having an orifice that dispenses one or more recirculated streams comprising ionic liquid catalyst into a chamber in the nozzle, b) a conduit for introducing a hydrocarbon feed stream comprising an olefin to the orifice at a close distance from the orifice; and c) a throat connecting the chamber in the nozzle to an alkylation zone.

    Abstract translation: 该应用提供了生产烷基化物共混组分的方法,包括在与孔口相距很远的距离处将包含烯烃的烃进料流引入喷嘴的孔口; 并且其中所述喷嘴分配一个或多个再循环流的混合物,并且所述烃进料流通过所述喷嘴的喉部,以制备烷基化汽油调和组分。 该应用还提供了用于生产烷基化汽油的处理单元,其包括:a)具有孔口的喷嘴,其具有将包含离子液体催化剂的一个或多个再循环流分配到喷嘴中的室中的孔口,b)用于引入烃进料的导管 在与所述孔口相距近的位置处包含烯烃至所述孔口; 和c)将喷嘴中的室连接到烷基化区的喉部。

Patent Agency Ranking