Abstract:
This invention declares the method of preparation of cerium oxide supported palladium-gold catalysts and the process of destruction of volatile organic compounds in air to remove volatile organic compounds using the above catalysts. Destruction of volatile organic compounds in air stream over these catalysts is carried out in a fixed bed reactor to remove volatile organic compounds in air.
Abstract:
A nitrogen oxide storage catalyst is provided, which has two catalytically active coatings on a support body. The lower coating applied directly to the support body has a nitrogen oxide storage function and includes platinum as a catalytically active component applied to a homogeneous magnesium-aluminum mixed oxide in combination with a nitrogen oxide storage material, in which a nitrogen oxide storage component is likewise present and applied to a homogeneous magnesium-aluminum mixed oxide. The second layer is notable for three-way catalytic activity, and includes palladium applied to aluminum oxide and barium oxide or strontium oxide, but no platinum.
Abstract:
An exhaust aftertreatment system that includes a suitable combination of particulate catalyst materials is used to effectively reduce an amount of NOX to N2 and water in a high-oxygen content exhaust flow from an engine that is controlled to operate by cyclically burning lean and rich mixtures of air and fuel. The catalyst materials of the exhaust aftertreatment system comprise (1) lanthanum-based perovskite oxide particles to oxidize NO to NO2, (2) barium oxide particles to temporarily store NO2, (3) copper oxide nanoparticles chemically deposited onto particles of cerium oxides to reduce NOX to N2 and to generate NH3, and (4) particles of a selective reduction catalyst to temporarily store NH3 and to reduce any residual NOX to N2 and water before the exhaust flow from the engine is discharged to the atmosphere.
Abstract:
The catalyst of the invention is a particulate catalyst in the form of particles having a minimum dimension of at least 0.8 mm, including a transition metal or a compound thereof dispersed on a porous support material, characterised in that said catalyst particles comprise at least 35% w/w total transition metal; and the transition metal surface area of said catalyst is at least 110 m2 per gram of transition metal and the tapped bulk density of a bed of the catalyst particles is at least 0.7 g/ml. The method of making a catalyst includes multiple steps of impregnation of a porous support with a metal ammine solution followed by drying, calcination and reduction of the dried material. The catalyst is useful in hydrogenation reactions.
Abstract:
An environment-friendly porous bead-satellite nanoparticles composite which has excellent recovery and repeated usage performance and can be used as a catalyst, an antiviral agent, or an antimicrobial, and a fabrication method thereof are provided. The porous bead-satellite nanoparticles composite includes a porous bead, a molecule having a first end coupled to the surface of the porous bead and including a functional group at a second end, and satellite nanoparticles coupled to the functional group, wherein the porous bead may have a core-shell structure including a cluster core of nanoparticles and a porous bead shell covering the cluster core.
Abstract:
A fuel cell supported catalyst includes an underlying support structure having at least one of a metal oxide and a metal phosphate. Catalyst particles are arranged onto and in engagement with the support structure. An intermediate conductive, corrosion-resistant layer, such as boron-doped-diamond, is arranged onto and in engagement with the support structure to surround the catalyst particles. The supported catalyst is produced by depositing the intermediate layer onto the support structure after the catalyst particles have been deposited on the underlying support structure, in one example. In another example, voids are provided in the intermediate layer, which has been deposited onto the underlying support structure, to subsequently receive the catalyst particles.
Abstract:
Provided is an emission treatment system and method for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system has an oxidation catalyst upstream of a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia. Also provided is a method for disposing an SCR catalyst composition on a wall flow monolith that provides adequate catalyst loading, but does not result in unsuitable back pressures in the exhaust.
Abstract:
Disclosed is a particulate filter, which is adapted to be disposed in an exhaust passage of an engine to trap particulate matter contained in exhaust gas discharged from the engine. The particulate filter comprises a filter body having a porous partition wall which defines a plurality of exhaust gas channels allowing the exhaust gas to pass therethrough, and a catalyst layer formed on a surface of the porous partition wall. The catalyst layer includes a Zr-based composite oxide which contains zirconium (Zr), and a rare-earth metal except cerium, wherein a content ratio of an oxide of the non-cerium rare-earth metal to a total amount of ZrO2 and the oxide of the non-cerium rare-earth metal in the Zr-based composite oxide is set in the range of greater than 33 mol % to less than 40 mol %. The particulate filter of the present invention can achieve a higher PM burning rate to burn PM within a shorter period of time. In addition, the higher PM burning rate makes it possible to provide enhanced fuel economy performance in an engine designed to perform a post-injection control.
Abstract:
Provided is an exhaust gas cleaner by which nitrogen oxides contained in an exhaust gas can be efficiently removed in a wide temperature range from a low temperature. The exhaust gas cleaner (10) is for use in purifying the exhaust gas discharged from an internal combustion engine (15) in which fuel is fed under periodical rich or lean conditions and burned. The cleaner (10) comprises: a reforming means (11) which generates a reforming gas comprising hydrogen and carbon monoxide; a means of low-temperature oxidation (12) which contains palladium and which thereby can oxidize and adsorb nitrogen oxides at low temperatures and oxidize the hydrogen and carbon monoxide; and a purifying means (13) which under lean conditions adsorbs nitrogen oxides and which under rich conditions releases the adsorbed nitrogen oxides and removes the released nitrogen oxides with the hydrogen and carbon monoxide present in the channel. By contriving the layout of the reforming means (11), means of low-temperature oxidation (12), and purifying means (13), nitrogen oxides contained in an exhaust gas can be removed in a wide temperature range from a low temperature.
Abstract:
Disclosed is a particulate filter, which is adapted to be disposed in an exhaust passage of an engine to trap particulate matter contained in exhaust gas discharged from the engine. The particulate filter comprises a filter body having a porous partition wall which defines a plurality of exhaust gas channels allowing the exhaust gas to pass therethrough, and a catalyst layer formed on a surface of the porous partition wall. The catalyst layer includes a Zr-based composite oxide which contains zirconium (Zr), and a rare-earth metal except cerium, wherein a content ratio of an oxide of the non-cerium rare-earth metal to a total amount of ZrO2 and the oxide of the non-cerium rare-earth metal in the Zr-based composite oxide is set in the range of greater than 33 mol % to less than 40 mol %. The particulate filter of the present invention can achieve a higher PM burning rate to burn PM within a shorter period of time. In addition, the higher PM burning rate makes it possible to provide enhanced fuel economy performance in an engine designed to perform a post-injection control.