Abstract:
A vapor phase deposition method and apparatus for the application of thin layers and coatings on substrates. The method and apparatus are useful in the fabrication of electronic devices, micro-electromechanical systems (MEMS), Bio-MEMS devices, micro and nano imprinting lithography, and microfluidic devices. The apparatus used to carry out the method provides for the addition of a precise amount of each of the reactants to be consumed in a single reaction step of the coating formation process. The apparatus provides for precise addition of quantities of different combinations of reactants during a single step or when there are a number of different individual steps in the coating formation process. The precise addition of each of the reactants in vapor form is metered into a predetermined set volume at a specified temperature to a specified pressure, to provide a highly accurate amount of reactant.
Abstract:
An improved vapor-phase deposition method and apparatus for the application of multilayered films/coatings on substrates is described. The method is used to deposit multilayered coatings where the thickness of an oxide-based layer in direct contact with a substrate is controlled as a function of the chemical composition of the substrate, whereby a subsequently deposited layer bonds better to the oxide-based layer. The improved method is used to deposit multilayered coatings where an oxide-based layer is deposited directly over a substrate and an organic-based layer is directly deposited over the oxide-based layer. Typically, a series of alternating layers of oxide-based layer and organic-based layer are applied.
Abstract:
A process for producing a film of a hydrophilic polymer on the inner surfaces of a fluidic component is provided comprising subjecting the inner surfaces of the fluidic component to a physicochemical pre-treatment, contacting the inner surfaces of the fluidic component with a solution of the hydrophilic polymer, replacing the solution of the hydrophilic polymer with a gaseous medium in such a manner that firstly the inner surfaces of the fluidic component remain wetted with part of the polymer solution, and removing the solvent to produce a film of the hydrophilic polymer on the inner surfaces of the fluidic component. The hydrophilic polymer used has a surface wettability for aqueous solutions which is higher than the surface wettability of the inner surfaces of the fluidic component itself.
Abstract:
A process is provided for making a composite work article suitable for fabricating rigid sheet metal can components. A steel sheet having first and second surfaces is pre-treated to enhance reception and retention of a multi-layer polymer coating on the pre-treated first surface. The multi-layer polymer coating is melt extruded on the pre-treated first surface and beyond opposite lateral edges of the work article to establish overhang portions, then solidified. The multi-layer polymeric coating has a tie polymeric layer contacting the pre-treated first surface, and a finish-surface polymeric layer. The solidified overhang portions are trimmed, and the extruded multi-layer polymeric coating is subjected to finish-treatment, involving heating the extruded multi-layer polymeric coating at least to a melt temperature thereof, then cooling the multi-layer polymeric coating through glass-transition temperature thereof at a sufficiently rapid rate to establish amorphous non-directional characteristics in the polymeric coating.
Abstract:
The invention relates to method of coating the surface of an inorganic substrate of glass, silicon dioxide, ceramics or carbon, which method comprises a step of cleaning the surface of the substrate by subjecting the surface to a reducing gas plasma, a step of activating the surface by generating radicals on the surface of the substrate by subjecting the surface to a reducing gas plasma and forming a first layer on the substrate surface using a plasma enhanced polymerization process employing one or more monomers comprising monomers with a sufficient low molecular weight for them to be in their gaseous state in the gas plasma, selected from the group consisting of C1-C16 alkanes, C2-C16 alkanes, C2-C16 alkynes, C2-C16 alkynes, styrene, aromatic monomers of styrene compounds, monomers of vinyl- and acrylate-compounds.
Abstract:
Flat-rolled steel strip, free of surface iron oxide, is provided with a corrosion-protection metallic coating on both surfaces, followed by continuous-line polymeric coating operations in which a single surface is pre-treated so as to activate that surface for adhesion of molten extruded thin-film polymeric material for in-line travel. Polymeric materials are formulated to provide maleic-anhydride modified polypropylene, which is melted and pressurized for extrusion as a molten thin-film tie-layer for first contacting that activated surface; and, thin-film intermediate and finish layers are each formulated to contain a selected percentage of polybutylene; which are extruded as molten films in overlaying relationship to said first contacting tie-layer. Polymeric finish-processing re-melts the polymeric materials; and, following a selected interval of in-line travel in that re-melted condition, rapidly cools those polymeric materials through glass-transition temperature so as to establish amorphous characteristics throughout said materials. End-usage product comprise flat-rolled mild steel can stock for fabricating one-piece drawn, and drawn and ironed, can bodies with interior polymeric coating and an exterior corrosive-protection metal coating, such as matte-finish electrolytic tin plate.
Abstract:
A passivation layer is deposited onto the surface of a substrate followed by deposition of a polymer layer, through the application of a plasma enhanced chemical vapor deposition process, in which the substrate is placed on a chuck within a reaction chamber and fluorocarbon gas is introduced into the reaction chamber under the influence of at least one plasma source. The fluorocarbon gas can be a CFX gas. The at least one plasma source can include a first plasma source that ionizes the fluorocarbon gas by applying RF plasma energy, and a second plasma source that applies a near-zero self-bias to the substrate at an RF frequency during deposition of the passivation layer and a greater bias during deposition of the polymer layer. The passivation layer is deposited prior to the polymer layer to protect the surface of the substrate from damage during the deposition of the polymer layer.
Abstract:
A surface functional member comprising: a support having a surface bonded to a graft polymer chain having a polar group; and an adsorbing layer comprising particles capable of bonding to the polar group.
Abstract:
Processes and apparatus for manufacturing an engineered-composite combining rigid flat-rolled sheet metal continuous-strip and selected polyester thermoplastics, which are formed into distinct polymeric layers for melted extrusion deposition on a single surface, at a time, using pressure dies, and other steps, for forming a uniform coat of distinct polymeric layers, which provide high green-strength-adhesion during continuous-in-line travel; and including dual-surface finishing for complete bonding of the polymeric layers on both metallic surfaces.
Abstract:
There is disclosed a method of treating running faces subjected to wear of a workpiece in which ions or molecule chain components of fluorocarbon molecules are arranged on the surface of the workpiece. It is especially preferred to attach ions of polyfluoroether molecules. The attachment can be effected by adhesion or by chemical bonding. Principally the method according to the invention can be applied to metallic and ceramic materials, wherein especially good experiences have been made with the surface treatment of aluminum workpieces, ceramic inserts etc.