OPTICAL FIBRE MATERIAL COMPRISING SILICA-BASED GLASS WITH REDUCED PHOTO DARKENING
    41.
    发明申请
    OPTICAL FIBRE MATERIAL COMPRISING SILICA-BASED GLASS WITH REDUCED PHOTO DARKENING 审中-公开
    包含二氧化硅玻璃的光学材料,具有减少的照片深度

    公开(公告)号:US20100061415A1

    公开(公告)日:2010-03-11

    申请号:US12515662

    申请日:2007-11-20

    Abstract: The invention relates to a waveguide laser or amplifier material comprising a silica glass host material, one or more rare earth elements in total concentration CRE at. %, one or more network modifier elements selected from the group of tri- or penta-valent atoms of the periodic table of the elements in total concentration CNME at. %, wherein the ratio of atomic concentrations of the modifier elements to that of the rare earth elements CNWCRE is larger than or equal to 1, and wherein the total atomic concentration of rare earth and the tri-valent network modifiers, such as aluminium and/or boron, is substantially equal to the atomic concentration of the penta-valent network modifier, such as phosphorous. Such materials exhibit reduced risk of photo darkening.

    Abstract translation: 本发明涉及一种波导激光器或放大器材料,其包括石英玻璃主体材料,总浓度为CRE的一种或多种稀土元素。 %,一个或多个选自元素周期表的三价或五价原子组中的网络改性剂元素的总浓度CNME。 %,其中改性剂元素的原子浓度与稀土元素CNWCRE的原子浓度之比大于或等于1,其中稀土和三价网络改性剂的总原子浓度如铝和/ 或硼基本上等于五价网络改性剂如磷的原子浓度。 这种材料表现出降低照相变暗的风险。

    Electric incandescent and discharge lamps having doped quartz glass
envelopes
    43.
    发明授权
    Electric incandescent and discharge lamps having doped quartz glass envelopes 失效
    具有掺杂石英玻璃信封的电白炽灯和放电灯

    公开(公告)号:US5680010A

    公开(公告)日:1997-10-21

    申请号:US595408

    申请日:1996-02-05

    Abstract: Soft quartz glass having low viscosity and a low thermal coefficient of expansion, high electrical insulation capability and free from release of contaminants, when used as a bulb of an incandescent lamp or as an envelope in an arc vessel of a discharge lamp, is a quartz glass made of ultra-pure quartz (SiO.sub.2), for example having a purity of 99.99 mol-%, doped with stoichiometric compounds of alkaline earth oxides with boron oxide, optionally also with a small quantity of Al.sub.2 O.sub.3 in an overall quantity of the doping substance of between about 0.05% to 0.8%, by weight.

    Abstract translation: 当用作白炽灯的灯泡或放电灯的电弧容器中的封套时,具有低粘度和低热膨胀系数,高电绝缘能力并且不会释放污染物的软石英玻璃是石英 用超纯石英(SiO 2)制成的玻璃,例如纯度为99.99mol%,掺杂有化学计量的碱土金属氧化物与氧化硼的化合物,任选地还含有少量的掺杂物质的总量的Al2O3 在约0.05%至0.8%之间。

    Devices involving silicon glasses
    46.
    发明授权
    Devices involving silicon glasses 失效
    涉及硅玻璃的设备

    公开(公告)号:US4826709A

    公开(公告)日:1989-05-02

    申请号:US161876

    申请日:1988-02-29

    Abstract: A sol-gel process is utilized for producing silicon oxide glasses useful in the manufacture of devices such as semiconductor devices. These glasses are easily deposited by techniques such as spinning. Not only is the glass easily applied, but also has advantageous electrical, etching, and mechanical properties. Thus, these glasses are useful in applications such as passivating layers for integrated circuit devices and as intermediary layers in trilevel lithography for the production of such devices.

    Abstract translation: 溶胶 - 凝胶法用于生产用于制造诸如半导体器件的器件的氧化硅玻璃。 这些玻璃容易通过旋转技术沉积。 不仅玻璃容易应用,而且具有有利的电,蚀刻和机械性能。 因此,这些玻璃在诸如用于集成电路器件的钝化层和用于制造这种器件的三层光刻中的中间层的应用中是有用的。

    Fixation by anion exchange of toxic materials in a glass matrix
    48.
    发明授权
    Fixation by anion exchange of toxic materials in a glass matrix 失效
    通过玻璃基质中有毒物质的阴离子交换固定

    公开(公告)号:US4544499A

    公开(公告)日:1985-10-01

    申请号:US386215

    申请日:1982-06-07

    Abstract: This invention relates to the immobilization of toxic, e.g., radioactive materials, internally in a silicate glass or silica gel matrix for extremely long periods of time. Toxic materials, such as radioactive wastes containing radioactive anions, and in some cases cations, which may be in the form of liquids, or solids dissolved or dispersed in liquids or gases, are internally incorporated into a glass matrix, having hydrous organofunctionalsiloxy groups, e.g., hydrous aminoalkylsiloxy or carboxyorganosiloxy, bonded to silicon atoms of said glass and/or hydrous polyvalent metals bonded to silicon atoms of said glass through divalent oxygen linkages or otherwise immobilized therein, by a process which involves the ion exchange of said toxic, radioactive anions with hydroxyl groups attached to said organofunctionalsiloxy groups or with hydroxyl groups attached to the hydrous polyvalent metal. Thereafter, the resulting glass now characterized by a distribution of internally bonded or immobilized, toxic, radioactive anions can be packaged in suitable containers, and disposed of as by burial, and/or they can be sintered to collapse the pores thereof to disposal or for producing useful radiation sources. The porous glass or a porous silica gel having said silicon-bonded organofunctionalsiloxy groups and/or said hydrous polyvalent metal oxy groups, the pores of said glass or silica gel remaining open and uncollapsed, can be used advantageously as a backfill for an underground radioactive waste burial site and as overpack in the waste disposal container. Also included is a novel method for bonding the polyvalent metal to the porous silica glass or gel by substituting the protons of the silicon-bonded hydroxyl groups thereof with an alkali metal or ammonium cation followed by displacement of said cation with the non-radioactive polyvalent metal cation.

    Abstract translation: 本发明涉及在硅酸盐玻璃或硅胶基质中内部有毒的例如放射性物质固定极长时间。 含有放射性阴离子的放射性废物,以及在某些情况下,可能是液体形式的阳离子或溶解或分散在液体或气体中的固体的有毒材料内部加入到具有含水官能团的甲硅烷氧基的玻璃基质中,例如 ,含水氨基烷基甲硅烷氧基或羧基有机基甲硅烷氧基,通过涉及将所述有毒放射性阴离子与所述有机放射性阴离子的离子交换的方法,通过二价氧键键合到所述玻璃的硅原子和/或与所述玻璃的硅原子键合的含水多价金属, 连接到所述有机电致甲硅烷氧基基团的羟基或与水合多价金属连接的羟基的羟基。 此后,所得玻璃的特征在于内部结合或固定的,有毒的放射性阴离子的分布可以包装在合适的容器中,并通过埋置进行处理,和/或它们可以烧结以将其孔隙塌缩以处理或用于 生产有用的辐射源。 所述多孔玻璃或多孔硅胶具有所述与硅键合的有机铁氧基甲硅烷氧基和/或所述含水多价金属氧基,所述玻璃或硅胶的孔保持开放和未破裂,可有利地用作地下放射性废物的回填 垃圾处理容器内的包装物, 还包括一种通过用碱金属或铵阳离子取代与硅键合的羟基的质子,然后用非放射性多价金属置换所述阳离子来将多价金属键合到多孔石英玻璃或凝胶上的新方法 阳离子。

    Fixation by anion exchange of toxic materials in a glass matrix
    49.
    发明授权
    Fixation by anion exchange of toxic materials in a glass matrix 失效
    通过玻璃基质中有毒物质的阴离子交换固定

    公开(公告)号:US4333847A

    公开(公告)日:1982-06-08

    申请号:US65752

    申请日:1979-08-10

    Abstract: This invention relates to the immobilization of toxic, e.g., radioactive materials, internally in a silicate glass or silica gel matrix for extremely long periods of time. Toxic materials, such as radioactive wastes containing radioactive anions, and in some cases cations, which may be in the form of liquids, or solids dissolved or dispersed in liquids or gases, are internally incorporated into a glass matrix, having hydrous organofunctionalsiloxy groups, e.g., hydrous aminoalkylsiloxy or carboxyorganosiloxy, bonded to silicon atoms of said glass and/or hydrous polyvalent metals bonded to silicon atoms of said glass through divalent oxygen linkages or otherwise immobilized therein, by a process which involves the ion exchange of said toxic, radioactive anions with hydroxyl groups attached to said organofunctionalsiloxy groups or with hydroxyl groups attached to the hydrous polyvalent metal. Thereafter, the resulting glass now characterized by a distribution of internally bonded or immobilized, toxic, radioactive anions can be packaged in suitable containers, and disposed of as by burial, and/or they can be sintered to collapse the pores thereof prior to disposal or for producing useful radiation sources. The porous glass or a porous silica gel having said silicon-bonded organofunctionalsiloxy groups and/or said hydrous polyvalent metal oxy groups, the pores of said glass or silica gel remaining open and uncollapsed, can be used advantageously as a backfill for an underground radioactive waste burial site and as overpack in the waste disposal container. Also included is a novel method for bonding the polyvalent metal to the porous silica glass or gel by substituting the protons of the silicon-bonded hydroxyl groups thereof with an alkali metal or ammonium cation followed by displacement of said cation with the non-radioactive polyvalent metal cation.

    Abstract translation: 本发明涉及在硅酸盐玻璃或硅胶基质中内部有毒的例如放射性物质固定极长时间。 含有放射性阴离子的放射性废物,以及在某些情况下,可能是液体形式的阳离子或溶解或分散在液体或气体中的固体的有毒材料内部加入到具有含水官能团的甲硅烷氧基的玻璃基质中,例如 ,含水氨基烷基甲硅烷氧基或羧基有机基甲硅烷氧基,通过涉及将所述有毒放射性阴离子与所述有机放射性阴离子的离子交换的方法,通过二价氧键键合到所述玻璃的硅原子和/或与所述玻璃的硅原子键合的含水多价金属, 连接到所述有机电致甲硅烷氧基基团的羟基或与水合多价金属连接的羟基的羟基。 此后,所得玻璃的特征在于内部结合或固定的,有毒的放射性阴离子的分布可以包装在合适的容器中,并且通过埋置进行处理和/或它们可以在处理之前烧结以使其孔隙塌缩,或 用于生产有用的辐射源。 所述多孔玻璃或多孔硅胶具有所述与硅键合的有机铁氧基甲硅烷氧基和/或所述含水多价金属氧基,所述玻璃或硅胶的孔保持开放和未破裂,可有利地用作地下放射性废物的回填 垃圾处理容器内的包装物, 还包括一种通过用碱金属或铵阳离子取代与硅键合的羟基的质子,然后用非放射性多价金属置换所述阳离子来将多价金属键合到多孔石英玻璃或凝胶上的新方法 阳离子。

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