公开(公告)号：US11845692B2

公开(公告)日：2023-12-19

申请号：US17955626

申请日：2022-09-29

Applicant: CORNING INCORPORATED

Inventor： Timothy James Kiczenski ,  Peter Joseph Lezzi ,  Michelle Diane Pierson-Stull ,  Jingshi Wu

IPC: C03C3/091 ,  C03C3/095 ,  C03C3/087 ,  C03C4/02

CPC classification number: C03C4/02 ,  C03C3/087 ,  C03C3/091 ,  C03C3/095 ,  C03C2201/3423 ,  C03C2201/36 ,  C03C2201/50

Abstract: The disclosure relates to highly temperable colored glass compositions. The colored glass compositions have high coefficients of thermal expansion and high Young's moduli that advantageously absorb in the ultraviolet and/or blue wavelength ranges. Methods of making such glasses are also provided.

公开(公告)号：US20180273424A1

公开(公告)日：2018-09-27

申请号：US15992408

申请日：2018-05-30

Applicant: ASAHI GLASS COMPANY, LIMITED ,  TSUBOTA LABORATORY, INC.

Inventor： Hideyuki Hirakoso ,  Takahiro Mashimo ,  Kensuke Nagai ,  Kazuo Tsubota ,  Toshihide Kurihara ,  Hidemasa Torii

IPC: C03C17/34 ,  C03C17/42 ,  G02B5/22 ,  C03C17/245 ,  C03C17/32

CPC classification number: C03C17/3417 ,  C03C17/007 ,  C03C17/245 ,  C03C17/32 ,  C03C17/42 ,  C03C2201/36 ,  C03C2217/445 ,  C03C2217/485 ,  C03C2217/70 ,  C03C2217/734 ,  C03C2217/74 ,  G02B5/22

Abstract: A wavelength-selective transmissive glass article has light transmittance Tmore than 315 nm and 400 nm or less at a wavelength of more than 315 nm and 400 nm or less of 1% or more. In addition, the wavelength-selective transmissive glass article has light transmittance T315 nm or less at a wavelength of 315 nm or less of 60% or less.

公开(公告)号：US09156733B2

公开(公告)日：2015-10-13

申请号：US13810008

申请日：2010-07-14

Applicant: Mingjie Zhou ,  Yanbo Qiao ,  Wenbo Ma

Inventor： Mingjie Zhou ,  Yanbo Qiao ,  Wenbo Ma

IPC: C09K11/77 ,  C03C3/083 ,  C03C4/12 ,  C03C21/00 ,  C03C3/06 ,  C03C23/00

CPC classification number: C03C21/005 ,  C03C3/06 ,  C03C4/12 ,  C03C23/0095 ,  C03C2201/10 ,  C03C2201/3423 ,  C03C2201/3458 ,  C03C2201/36 ,  C03C2201/54 ,  C03C2203/50 ,  C09K11/7774

Abstract: A preparation method of rare earth ions doped alkaline earth metal silicate luminescent glass is provided. The steps involve: step 1, mixing the source compounds of cerium, terbium and alkaline earth metals and putting the mixture into solvent to get a mixed solution; step 2, impregnating the nanometer pores glass with the mixed solution obtained in step 1; step 3: calcining the impregnated nanometer pores glass obtained in step 2 in a reducing atmosphere, cooling to room temperature, then obtaining the cerium and terbium co-doped alkaline earth metal silicate luminescent glass. Besides, the rare earth ions doped alkaline earth metal silicate luminescent glass prepared with aforesaid method is also provided. In the prepared luminescent glass, cerium ions can transmit absorbed energy to terbium ions under the excitation of UV light due to the co-doping of cerium ions. As a result, the said luminescent glass has higher luminous intensity than the glass only doped with terbium.

Abstract translation: 提供了稀土离子掺杂的碱土金属硅酸盐发光玻璃的制备方法。 步骤包括：步骤1，混合铈，铽和碱土金属的源化合物，并将混合物置于溶剂中以得到混合溶液; 步骤2，用步骤1中获得的混合溶液浸渍纳米孔玻璃; 步骤3：将在步骤2中获得的浸渍的纳米孔玻璃在还原气氛中煅烧，冷却至室温，然后获得共混掺杂的铈和铽的碱土金属硅酸盐发光玻璃。 此外，还提供了用上述方法制备的稀土离子掺杂的碱土金属硅酸盐发光玻璃。 在制备的发光玻璃中，由于铈离子的共同掺杂，铈离子可以在UV光的激发下将吸收的能量传递给铽离子。 结果，所述发光玻璃比仅掺杂铽的玻璃具有更高的发光强度。

公开(公告)号：US08494013B2

公开(公告)日：2013-07-23

申请号：US12908102

申请日：2010-10-20

Applicant: Stuart Gray ,  Shenping Li ,  Ji Wang

Inventor： Stuart Gray ,  Shenping Li ,  Ji Wang

IPC: H01S3/30 ,  C03B37/075 ,  C03B37/01 ,  C03C13/00 ,  G02B6/00 ,  G02B6/02

CPC classification number: C03B37/014 ,  C03B37/01446 ,  C03B2201/08 ,  C03B2201/22 ,  C03B2201/31 ,  C03B2201/34 ,  C03B2201/36 ,  C03B2203/23 ,  C03C4/0071 ,  C03C13/047 ,  C03C2201/22 ,  C03C2201/31 ,  C03C2201/36 ,  H01S3/06712 ,  H01S3/06716 ,  H01S3/06733 ,  Y02P40/57

Abstract: Photodarkening resistant optical fiber lasing media and fiber lasers incorporating the same are disclosed. In one embodiment, an optical fiber lasing medium includes a core portion formed from silica-based glass comprising a rare-earth dopant and deuterium, the core portion having an index of refraction nc, a numerical aperture NAc. A concentration of defect color centers in the core portion is less than 1×1016/cm3. Deuterium is combined with the defect color centers to form reacted defect color centers that do not absorb ultraviolet and visible wavelengths of light. A first cladding portion is formed from silica-based glass, the first cladding portion surrounding and directly contacting the core portion and having an index of refraction n1, wherein the index of refraction n1 of the first cladding portion is less than the index of refraction nc of the core portion. Methods of forming the photodarkening resistant optical fiber lasing media are also disclosed.

Abstract translation: 公开了防光纤光纤激光介质和结合光纤激光器的光纤激光器。 在一个实施例中，光纤激光介质包括由包含稀土掺杂剂和氘的二氧化硅基玻璃形成的芯部分，芯部分具有折射率nc，数值孔径NAc。 核心部分的缺陷颜色中心的浓度小于1×1016 / cm3。 氘与缺陷色中心结合，形成不吸收紫外和可见波长光的反应缺陷色中心。 第一包层部分由二氧化硅基玻璃形成，第一包层部分围绕并直接接触芯部并具有折射率n1，其中第一包层部分的折射率n1小于折射率nc 的核心部分。 还公开了形成光抗剥离光纤激光介质的方法。

公开(公告)号：US20120148770A1

公开(公告)日：2012-06-14

申请号：US13391527

申请日：2010-08-20

Applicant: Tianjun Rong ,  Samuel Conzone ,  Martin Lawrence Panchula

Inventor： Tianjun Rong ,  Samuel Conzone ,  Martin Lawrence Panchula

IPC: B32B1/02 ,  C03C3/076 ,  C03C3/083 ,  C03C3/06 ,  C03C3/095

CPC classification number: C03C3/06 ,  A61J1/00 ,  A61J1/03 ,  A61J1/065 ,  C03C4/20 ,  C03C2201/36 ,  Y10T428/131

Abstract: A high silica glass composition comprising about 82 to about 99.9999 wt. % SiO2 and from about 0.0001 to about 18 wt. % of at least one dopant selected from Al2O3, CeO2, TiO2, La2O3, Y2O3, Nd2O3, other rare earth oxides, and mixtures of two or more thereof. The glass composition has a working point temperature ranging from 600 to 2,000° C. These compositions exhibit stability similar to pure fused quartz, but have a moderate working temperature to enable cost effective fabrication of pharmaceutical packages. The glass is particularly useful as a packaging material for pharmaceutical applications, such as, for example pre-filled syringes, ampoules and vials.

Abstract translation: 一种高二氧化硅玻璃组合物，包含约82-约99.9999wt。 ％SiO 2和约0.0001至约18wt。 选自Al 2 O 3，CeO 2，TiO 2，La 2 O 3，Y 2 O 3，Nd 2 O 3，其它稀土氧化物中的至少一种掺杂剂的％，以及其两种或更多种的混合物。 玻璃组合物的工作点温度范围为600至2000℃。这些组合物表现出与纯熔融石英相似的稳定性，但具有适度的工作温度以使药物包装成本有效地制造。 该玻璃特别可用作药物应用的包装材料，例如预填充注射器，安瓿和小瓶。

公开(公告)号：US20120069858A1

公开(公告)日：2012-03-22

申请号：US12908102

申请日：2010-10-20

Applicant: Stuart Gray ,  Shenping Li ,  Ji Wang

Inventor： Stuart Gray ,  Shenping Li ,  Ji Wang

IPC: H01S3/30 ,  G02B6/02 ,  B29D11/00 ,  G02B6/028

CPC classification number: C03B37/014 ,  C03B37/01446 ,  C03B2201/08 ,  C03B2201/22 ,  C03B2201/31 ,  C03B2201/34 ,  C03B2201/36 ,  C03B2203/23 ,  C03C4/0071 ,  C03C13/047 ,  C03C2201/22 ,  C03C2201/31 ,  C03C2201/36 ,  H01S3/06712 ,  H01S3/06716 ,  H01S3/06733 ,  Y02P40/57

Abstract: Photodarkening resistant optical fiber lasing media and fiber lasers incorporating the same are disclosed. In one embodiment, an optical fiber lasing medium includes a core portion formed from silica-based glass comprising a rare-earth dopant and deuterium, the core portion having an index of refraction nc, a numerical aperture NAc. A concentration of defect color centers in the core portion is less than 1×1016/cm3. Deuterium is combined with the defect color centers to form reacted defect color centers that do not absorb ultraviolet and visible wavelengths of light. A first cladding portion is formed from silica-based glass, the first cladding portion surrounding and directly contacting the core portion and having an index of refraction n1, wherein the index of refraction n1 of the first cladding portion is less than the index of refraction ncof the core portion. Methods of forming the photodarkening resistant optical fiber lasing media are also disclosed.

Abstract translation: 公开了防光纤光纤激光介质和结合光纤激光器的光纤激光器。 在一个实施例中，光纤激光介质包括由包含稀土掺杂剂和氘的二氧化硅基玻璃形成的芯部分，芯部分具有折射率nc，数值孔径NAc。 核心部分的缺陷颜色中心的浓度小于1×1016 / cm3。 氘与缺陷色中心结合，形成不吸收紫外和可见波长光的反应缺陷色中心。 第一包层部分由二氧化硅基玻璃形成，第一包层部分包围并直接接触芯部并且具有折射率n1，其中第一包层部分的折射率n1小于折射率ncof 核心部分。 还公开了形成光抗剥离光纤激光介质的方法。

公开(公告)号：US07905932B2

公开(公告)日：2011-03-15

申请号：US11897406

申请日：2007-08-30

Applicant: Tatsuhiro Sato

Inventor： Tatsuhiro Sato

IPC: C03C8/02 ,  C03C8/00 ,  C03C8/14 ,  C03C8/20 ,  C03C6/06

CPC classification number: C03C1/00 ,  C03B19/063 ,  C03B32/005 ,  C03B2201/12 ,  C03B2201/20 ,  C03B2201/24 ,  C03B2201/36 ,  C03C3/06 ,  C03C3/112 ,  C03C4/20 ,  C03C2201/12 ,  C03C2201/23 ,  C03C2201/24 ,  C03C2201/26 ,  C03C2201/32 ,  C03C2201/3411 ,  C03C2201/3435 ,  C03C2201/36

Abstract: A mixed quartz powder contains quartz powder and two or more types of doping element in an amount of from 0.1 to 20 mass %. The aforementioned doped elements include a first dope element selected from the group consisting of N, C and F, and a second dope element selected from the group consisting of Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, the lanthanides and the actinides. The “quartz powder” is a powder of crystalline quartz or it is a powder of glassy SiO2 particles. It is made form natural occurring quartz or it is fabricated synthetically. The “quartz powder” may be doped. The compounding ratio of the total amount (M1) of the aforementioned first elements and the total amount (M2) of the aforementioned second elements as the ratio of the number of atoms (M1)/(M2) is preferably from 0.1 to 20. Al as well as the aforementioned doped elements is preferably included in a mixed quartz powder of this invention.

Abstract translation: 混合石英粉含有0.1〜20质量％的石英粉和2种以上的掺杂元素。 上述掺杂元素包括选自N，C和F的第一掺杂元素和选自Mg，Ca，Sr，Ba，Sc，Y，Ti，Zr，Hf的第二掺杂元素， 镧系元素和锕系元素。 “石英粉”是结晶石英粉，或是玻璃状SiO 2粉末的粉末。 它由天然石英制成，或者由合成制成。 可以掺杂“石英粉”。 上述第一元素的总量（M1）与上述第二元素的总量（M2）的配位比优选为0.1〜20。作为原子数（M1）/（M2）的比例，优选为0.1〜20。 以及上述掺杂元素优选包括在本发明的混合石英粉末中。

公开(公告)号：US20110026106A1

公开(公告)日：2011-02-03

申请号：US12907622

申请日：2010-10-19

Applicant: Teruno NAKAGUMA ,  Kentaro ICHII ,  Shoji TANIGAWA

Inventor： Teruno NAKAGUMA ,  Kentaro ICHII ,  Shoji TANIGAWA

IPC: H01S3/067 ,  G02B6/036 ,  H01S3/063

CPC classification number: H01S3/06716 ,  C03C3/06 ,  C03C13/045 ,  C03C2201/10 ,  C03C2201/12 ,  C03C2201/14 ,  C03C2201/28 ,  C03C2201/31 ,  C03C2201/3488 ,  C03C2201/36 ,  G02B6/024 ,  G02B6/036 ,  G02B6/03605 ,  G02B6/03633 ,  G02B6/03638 ,  G02B6/03644 ,  G02B6/03661 ,  H01S3/06712 ,  H01S3/06729 ,  H01S3/0675 ,  H01S3/094007 ,  H01S3/1608 ,  H01S3/1618 ,  H01S3/1691 ,  H01S3/1693

Abstract: An ytterbium-doped optical fiber of the present invention includes: a core which contains ytterbium, aluminum, and phosphorus and does not contain germanium; and a cladding which surrounds this core. The ytterbium concentration in the core in terms of ytterbium oxide is 0.09 to 0.68 mole percent. The molar ratio between the phosphorus concentration in the core in terms of diphosphorus pentoxide and the above ytterbium concentration in terms of ytterbium oxide is 3 to 30. The molar ratio between the aluminum concentration in the core in terms of aluminum oxide and the above ytterbium concentration in terms of ytterbium oxide is 3 to 32. The molar ratio between the above aluminum concentration in terms of aluminum oxide and the above phosphorus concentration in terms of diphosphorus pentoxide is 1 to 2.5.

Abstract translation: 本发明的镱掺杂光纤包括：含有镱，铝和磷并且不含锗的芯; 以及围绕该芯的包层。 以镱氧化物计，核心中的镱浓度为0.09〜0.68摩尔％。 以氧化镱表示的核心中的磷浓度与上述镱的氧化镱浓度之间的摩尔比为3〜30。以氧化铝计的核心中的铝浓度与上述镱的浓度 氧化镱的数量为3〜32。以氧化铝计的上述铝浓度与上述磷浓度之间的摩尔比为1〜2.5。

公开(公告)号：US20080261800A1

公开(公告)日：2008-10-23

申请号：US11738030

申请日：2007-04-20

Applicant: Jie Yuan ,  Jennifer Y. Sun ,  Renguan Duan

Inventor： Jie Yuan ,  Jennifer Y. Sun ,  Renguan Duan

IPC: C04B35/505

CPC classification number: C03C3/06 ,  C03B32/00 ,  C03B2201/24 ,  C03B2201/34 ,  C03B2201/36 ,  C03C2201/3411 ,  C03C2201/36 ,  C03C2203/54 ,  H01L21/67069 ,  H01L21/68721 ,  H01L21/68735 ,  H01L21/68757 ,  Y02P40/57 ,  Y10S156/915

Abstract: A method of fabricating doped quartz component is provided herein. In one embodiment, the doped quartz component is a yttrium doped quartz ring configured to support a substrate. In another embodiment, the doped quartz component is a yttrium and aluminum doped cover ring. In yet another embodiment, the doped quartz component is a yttrium, aluminum and nitrogen containing cover ring.

Abstract translation: 本文提供了一种制造掺杂石英组分的方法。 在一个实施例中，掺杂的石英组件是被配置为支撑衬底的掺钇的石英环。 在另一个实施例中，掺杂的石英组件是掺钇和铝的覆盖环。 在另一个实施方案中，掺杂的石英组分是含钇，铝和氮的覆盖环。

公开(公告)号：US07407604B2

公开(公告)日：2008-08-05

申请号：US11029556

申请日：2005-01-05

Applicant: Bernard H. Kear ,  Christopher D. Haines ,  George H. Sigel ,  Lisa C. Klein ,  Varadh Ranganathan

Inventor： Bernard H. Kear ,  Christopher D. Haines ,  George H. Sigel ,  Lisa C. Klein ,  Varadh Ranganathan

IPC: C09K11/02 ,  C09K11/59 ,  C09K11/64 ,  C09K11/79

CPC classification number: C09K11/7706 ,  C03B19/06 ,  C03B19/106 ,  C03B19/1065 ,  C03B19/14 ,  C03B37/018 ,  C03B2201/34 ,  C03B2201/36 ,  C03C1/006 ,  C03C1/026 ,  C03C4/12 ,  C03C2201/3411 ,  C03C2201/3429 ,  C03C2201/3447 ,  C03C2201/3458 ,  C03C2201/3476 ,  C03C2201/36 ,  C03C2203/22 ,  C03C2203/40 ,  C09K11/7774 ,  H01S3/06754 ,  H01S3/1608 ,  H01S3/169 ,  Y10S977/778 ,  Y10S977/811 ,  Y10S977/834

Abstract: A new class of nanostructured RE-doped SiO2-base materials that display superior fluorescence properties is provided. In particular, high gain combined with a broad and flat spectral band width is observed in material composed of a high fraction of a nano-dispersed metastable silicate phase in a glassy SiO2 matrix, produced by partial devitrification (crystallization) of several glassy Al2O3/Er2O3- and Y2O3/Er2O3-doped SiO2 compositions. Also, a highly deconvoluted spectral emission, with several prominent peaks, is observed in completely devitrified material, consisting of a uniform nano-dispersion of an equilibrium silicate phase in a crystobalite SiO2 matrix. Such enhanced fluorescence properties were observed in heat treated nanopowders prepared by vapor-phase, solgel, rapid solidification, and spray-pyrolysis methods.

Abstract translation: 提供了一类新型的具有优异荧光性能的纳米结构的RE掺杂SiO 2基体材料。 特别地，在通过部分失透反应产生的玻璃状SiO 2基体中的高分数纳米分散的亚稳态硅酸盐相组成的材料中观察到具有宽的和平坦的光谱带宽的高增益（ 几个玻璃状的Al 2 O 3 / O 2 O 3 - 和Y 2的结晶， O 3组成的二氧化硅组合物。 此外，在完全失透的材料中观察到具有几个突出的峰的高度去卷积的光谱发射，由平底硅酸盐相在均匀的SiO 2基体中的均匀的纳米分散体组成。 在通过气相，溶胶凝胶，快速凝固和喷雾热解方法制备的热处理纳米粉末中观察到这种增强的荧光性质。