公开(公告)号：US09700874B2

公开(公告)日：2017-07-11

申请号：US14560421

申请日：2014-12-04

Applicant: KiOR, Inc.

Inventor： Robert Bartek ,  Michael Brady ,  Dennis Stamires

IPC: B01J21/00 ,  B01J21/16 ,  C10G1/00 ,  C10G3/00 ,  B01J23/00 ,  C10L1/08 ,  C10G1/06 ,  C10G1/08 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/18 ,  C10B53/02 ,  C10B57/06

CPC classification number: B01J21/16 ,  B01J21/005 ,  B01J23/005 ,  B01J23/007 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/1806 ,  C10B53/02 ,  C10B57/06 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08 ,  C10G3/44 ,  C10G3/45 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L1/08 ,  Y02E50/13 ,  Y02E50/14 ,  Y02E50/15 ,  Y02E50/32 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for biomass catalytic cracking is disclosed herein. More specifically, the process is in presence of is a mixed metal oxide catalyst represented by the formula (X1O).(X2O)a.(X3YbO4) wherein X1, X2 and X3 are alkaline earth elements selected from the group of Mg, Ca, Be, Ba, and mixture thereof, and Y is a metal selected from the group of Al, Mn, Fe, Co, Ni, Cr, Ga, B, La, P and mixture thereof, wherein the catalyst is formed by calcining at least one compound comprising at least one alkaline earth element and a metal element.

公开(公告)号：US09657232B2

公开(公告)日：2017-05-23

申请号：US14356781

申请日：2012-11-12

Applicant: SHELL OIL COMPANY

Inventor： Alan Anthony Del Paggio ,  Michael John Roberts ,  Terry Louise Marker ,  Larry Gordon Felix ,  Martin Brendan Linck

IPC: C10G1/00 ,  C10K1/02 ,  C10B49/10 ,  C10B53/02 ,  C10B57/06 ,  B01J37/20 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J35/00 ,  B01J35/02 ,  B01J37/02 ,  C10G1/08 ,  C10G3/00 ,  C10G1/06 ,  C10L1/02

CPC classification number: C10B57/06 ,  B01D45/12 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J35/0026 ,  B01J35/026 ,  B01J37/0201 ,  B01J37/20 ,  C10B47/00 ,  C10B49/10 ,  C10B53/02 ,  C10B57/12 ,  C10G1/002 ,  C10G1/008 ,  C10G1/02 ,  C10G1/06 ,  C10G1/08 ,  C10G3/50 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10K1/024 ,  C10L1/023 ,  C10L1/026 ,  C10L2200/0469 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/02 ,  Y02E50/13 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P20/145 ,  Y02P30/20

Abstract: A process for converting biomass to products is described. Biomass is contacted with hydrogen in the presence of a fluidized bed of hydropyrolysis catalyst in a reactor vessel under hydropyrolysis conditions; and products and char are removed from the reactor vessel. The products leave the fluidized bed at an exit bed velocity, the char has a settling velocity that is less than the exit bed velocity and hydropyrolysis catalyst has a settling velocity that is greater than the exit bed velocity.

公开(公告)号：US09644152B2

公开(公告)日：2017-05-09

申请号：US14486021

申请日：2014-09-15

Applicant: SHELL OIL COMPANY

Inventor： Andries Quirin Maria Boon ,  Joseph Broun Powell ,  Lamar Lane Joffrion ,  Kimberly Ann Johnson ,  Hubert Willem Schenck

IPC: C10G1/06 ,  C10G1/00 ,  C10L1/04 ,  C10K3/04 ,  C10G3/00 ,  C10J3/54 ,  C10J3/74 ,  C10L1/02 ,  C10G1/08 ,  C01B3/16

CPC classification number: C10G1/06 ,  C01B3/16 ,  C01B2203/0288 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/046 ,  C01B2203/0475 ,  C01B2203/148 ,  C01B2210/0009 ,  C01B2210/001 ,  C01B2210/0014 ,  C01B2210/0025 ,  C10G1/002 ,  C10G1/08 ,  C10G1/083 ,  C10G3/42 ,  C10G3/52 ,  C10G2300/1014 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/42 ,  C10J3/54 ,  C10J3/74 ,  C10J2300/1223 ,  C10J2300/1823 ,  C10K3/04 ,  C10L1/02 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  C10L2290/10 ,  Y02E50/32 ,  Y02P20/145 ,  Y02P30/20

Abstract: A bottom fraction of a product of a hydrocatalytic reaction is gasified to generate hydrogen for use in further hydrocatalytic reactions. In one embodiment, an overhead fraction of the hydrocatalytic reaction is further processed to generate higher molecular weight compounds. In another embodiment, a product of the further processing is separated into a bottom fraction and an overhead fraction, where the bottom fraction is also gasified to generate hydrogen for use in further hydrocatalytic reactions.

公开(公告)号：US09545609B2

公开(公告)日：2017-01-17

申请号：US14076205

申请日：2013-11-09

Applicant: Douglas M. Van Thorre ,  Michael L. Catto

Inventor： Douglas M. Van Thorre ,  Michael L. Catto

IPC: B01J8/10 ,  B01J19/12 ,  C10G1/02 ,  C10G1/10 ,  B01J8/08 ,  C10G1/08

CPC classification number: B01J8/10 ,  B01J8/087 ,  B01J19/126 ,  B01J2208/00442 ,  B01J2219/00006 ,  C10G1/02 ,  C10G1/08 ,  C10G1/10

Abstract: A pyrolysis oil composition by an oxygen-starved microwave process from an organic-carbon-containing feedstock is described. Feedstock is introduced into a substantially microwave-transparent reaction chamber. A microwave source emits microwaves which are directed through the microwave-transparent wall of the reaction chamber to impinge on the feedstock within the reaction chamber. The microwave source may be rotated relative to the reaction chamber. The feedstock is subjected to microwaves until the desired reaction occurs to produce a fuel. A catalyst can be mixed with the feedstock to enhance the reaction process.

Abstract translation: 描述了通过来自含有机碳原料的缺氧微波方法的热解油组合物。 原料被引入基本上微波透明的反应室中。 微波源发射微波，其被引导通过反应室的微波透明壁以撞击反应室内的原料。 微波源可以相对于反应室旋转。 原料经受微波，直到发生所需的反应以产生燃料。 可以将催化剂与原料混合以增强反应过程。

公开(公告)号：US09447350B2

公开(公告)日：2016-09-20

申请号：US13964873

申请日：2013-08-12

Applicant: Inaeris Technologies, LLC

Inventor： Maria Magdalena Ramirez-Corredores ,  Changan Zhang

IPC: C10G3/00 ,  C10L1/19 ,  C10L1/02 ,  C10L1/04 ,  C11B13/00 ,  C11C3/00 ,  C10G1/02 ,  C10G1/08 ,  C10G1/00

CPC classification number: C10L1/19 ,  C10G1/02 ,  C10G1/08 ,  C10G3/42 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1037 ,  C10G2300/301 ,  C10G2300/80 ,  C10G2300/802 ,  C10L1/02 ,  C10L1/04 ,  C11B13/00 ,  C11C3/00 ,  Y02E50/13 ,  Y02P30/20 ,  Y02W30/74

Abstract: A process and system for separating a light fraction, a bio-distillate fraction, and a heavy fraction from a bio-oil, and for producing a renewable distillate including at least in part the bio-distillate fraction and a stabilizing additive, is provided. In addition, a process and system is provided for upgrading a bio-oil by use of a diluent and/or a recycle stream from the upgrading process to reduce fouling in upgrading equipment, such as a preheater and a hydrodeoxygenation unit.

Abstract translation: 提供了用于从生物油分离轻馏分，生物馏出物馏分和重馏分，以及用于生产至少部分包括生物馏分和稳定添加剂的可再生馏出物的方法和系统。 此外，提供了一种通过使用稀释剂和/或来自升级过程的再循环流来升级生物油的方法和系统，以减少升级设备如预热器和加氢脱氧单元中的结垢。

公开(公告)号：US09339796B2

公开(公告)日：2016-05-17

申请号：US13896578

申请日：2013-05-17

Applicant: Petroraza SAS

Inventor： Jose Edgar Patiño ,  Farid Bernardo Cortés

IPC: B01J23/755 ,  B01J35/00 ,  C10G49/04 ,  B01J23/89 ,  E21B43/00 ,  B01J35/02 ,  B01J21/04 ,  B01J35/10 ,  B01J37/02 ,  C10G1/08 ,  C10G11/02 ,  B01J23/78

CPC classification number: C10G11/04 ,  B01J21/04 ,  B01J23/755 ,  B01J23/78 ,  B01J23/892 ,  B01J23/8946 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/0207 ,  C10G1/08 ,  C10G11/02 ,  C10G49/04 ,  C10G2300/4037 ,  E21B43/00

Abstract: Novel catalysts comprising nickel oxide nanoparticles supported on alumina nanoparticles, methods of their manufacture, heavy oil compositions contacted by these nanocatalysts and methods of their use are disclosed. The novel nanocatalysts are useful, inter alia, in the upgrading of heavy oil fractions or as aids in oil recovery from well reservoirs or downstream processing.

Abstract translation: 公开了包含负载在氧化铝纳米颗粒上的氧化镍纳米粒子的新型催化剂，其制造方法，与这些纳米催化剂接触的重油组合物及其使用方法。 新型纳米催化剂尤其可用于重油馏分的升级或作为从油井或下游加工中回收油的辅助工具。

公开(公告)号：US09238779B2

公开(公告)日：2016-01-19

申请号：US13453801

申请日：2012-04-23

Applicant: Johan Willem Gosselink ,  John William Harris ,  Andries Hendrik Janssen ,  Sander Van Paasen ,  Colin John Schaverien ,  Nicolaas Wilhelmus Joseph Way

Inventor： Johan Willem Gosselink ,  John William Harris ,  Andries Hendrik Janssen ,  Sander Van Paasen ,  Colin John Schaverien ,  Nicolaas Wilhelmus Joseph Way

IPC: C07C1/00 ,  C10G1/08 ,  C10B49/22 ,  C10B53/02 ,  C10B57/06 ,  C10G3/00 ,  C10G11/18 ,  C10L1/02 ,  C10L1/04 ,  B01J8/18

CPC classification number: C10G1/08 ,  B01J8/18 ,  C10B49/22 ,  C10B53/02 ,  C10B57/06 ,  C10G3/50 ,  C10G3/57 ,  C10G11/18 ,  C10G2300/1011 ,  C10G2300/4006 ,  C10G2300/807 ,  C10L1/02 ,  C10L1/04 ,  Y02E50/14 ,  Y02P20/145 ,  Y02P30/20

Abstract: A process for converting a solid biomass material is provided. The solid biomass material is contacted with a catalytic cracking catalyst at a temperature of more than 400° C. in a riser reactor to produce one or more cracked products. The riser reactor is an external riser reactor with a curve and/or low velocity zone at its termination and wherein a part of the catalytic cracking catalyst has deposited in the curve and/or low velocity zone.

Abstract translation: 提供了一种转化固体生物质材料的方法。 固体生物质材料在提升管反应器中在超过400℃的温度下与催化裂化催化剂接触以产生一种或多种裂化产物。 提升管反应器是在其端接处具有曲线和/或低速区的外部提升管反应器，并且其中一部分催化裂化催化剂沉积在曲线和/或低速区中。

公开(公告)号：US20160002544A1

公开(公告)日：2016-01-07

申请号：US14789603

申请日：2015-07-01

Applicant: Anellotech, Inc.

Inventor： Charles M. Sorensen, JR. ,  Ruozhi Song ,  Terry J. Mazanec

IPC: C10G45/32 ,  C10L1/04 ,  C10L10/12 ,  C10G45/02

CPC classification number: C10G45/32 ,  C10G1/002 ,  C10G1/08 ,  C10G1/10 ,  C10G3/42 ,  C10G45/02 ,  C10G2400/30 ,  C10L1/04 ,  C10L10/12 ,  C10L2200/0469 ,  C10L2270/04 ,  C10L2290/02 ,  C10L2290/54 ,  Y02P30/20

Abstract: Methods of separating and purifying products from the catalytic fast pyrolysis of biomass are described. In a preferred method, a portion of the products from a pyrolysis reactor are recovered and purified using a hydrotreating step that reduces the content of sulfur, nitrogen, and oxygen components, and hydrogenates olefins to produce aromatic products that meet commercial quality specifications.

Abstract translation: 描述了从生物质的催化快速热解中分离和纯化产物的方法。 在优选的方法中，使用降低硫，氮和氧组分含量的加氢处理步骤回收和纯化来自热解反应器的一部分产物，并将烯烃氢化以产生满足商业质量规格的芳族产物。

公开(公告)号：US09193926B2

公开(公告)日：2015-11-24

申请号：US12969263

申请日：2010-12-15

Applicant: Tom N. Kalnes

Inventor： Tom N. Kalnes

IPC: C10L1/00 ,  C10L1/18 ,  C10L1/02 ,  C10B53/02 ,  C10C5/00 ,  C10G1/02 ,  C10G1/06 ,  C10G1/08 ,  C10L1/182 ,  C10G3/00 ,  C10L1/16

CPC classification number: C10L1/023 ,  C10B53/02 ,  C10C5/00 ,  C10G1/02 ,  C10G1/06 ,  C10G1/08 ,  C10G3/42 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/104 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/305 ,  C10G2300/4043 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/1616 ,  C10L1/18 ,  C10L1/1824 ,  C10L2200/0423 ,  C10L2200/0469 ,  C10L2290/02 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P20/145 ,  Y02P30/10 ,  Y02P30/20

Abstract: Fuel compositions exhibiting reduced greenhouse gas (GHG) emissions, based on a lifecycle assessment from the time of cultivation of feedstocks (in the case of plant materials) or extraction of feedstocks (in the case of fossil fuels) required for the compositions (up to and including the ultimate combustion of the fuel composition by the end user) are disclosed. The reduced level of emissions (“carbon footprint”) is achieved by incorporating a pyrolysis derived component having a higher heating value than ethanol and meeting other applicable standards for fossil fuel (e.g., petroleum) derived components conventionally used for the same purpose, such as transportation fuels. Advantageously, fuel compositions comprising pyrolysis derived gasoline can exhibit lower GHG emissions than gasoline derived solely from petroleum, or even conventional blends of petroleum derived gasoline and ethanol.

Abstract translation: 基于从原料（在植物材料的情况下）培养或提取组合物所需的原料（在化石燃料的情况下）的生命周期评估，燃料组合物显示减少的温室气体（GHG）排放量（直到 并且包括最终用户对燃料组合物的最终燃烧）。 降低的排放水平（“碳足迹”）通过引入具有比乙醇更高的热值的热解衍生组分并满足通常用于相同目的的化石燃料（例如，石油）衍生组分的其它适用标准来实现，例如 运输燃料。 有利地，包含热解衍生的汽油的燃料组合物可以比仅由石油衍生的汽油或甚至石油衍生的汽油和乙醇的常规共混物表现出较低的温室气体排放。

公开(公告)号：US20150217251A1

公开(公告)日：2015-08-06

申请号：US14685798

申请日：2015-04-14

Applicant: Lummus Technology Inc.

Inventor： Ujjal K. Mukherjee ,  Mario C. Baldassari ,  Marvin I. Greene

IPC: B01J8/18 ,  C10G67/02 ,  B01J19/24

CPC classification number: B01J8/18 ,  B01J19/245 ,  B01J2208/00796 ,  B01J2219/24 ,  C10G1/08 ,  C10G1/086 ,  C10G47/26 ,  C10G65/10 ,  C10G65/12 ,  C10G67/02 ,  C10G67/049 ,  C10G2300/701

Abstract: A process for upgrading residuum hydrocarbons including: feeding pitch, hydrogen, and a partially spent catalyst recovered from a hydrocracking reactor to an ebullated bed pitch hydrocracking reactor; contacting the pitch, hydrogen, and the catalyst in the ebullated bed pitch hydrocracking reactor at reaction conditions of temperature and pressure sufficient to convert at least a portion of the pitch to distillate hydrocarbons; and separating the distillate hydrocarbons from the catalyst. In some embodiments, the process may include selecting the ebullated bed pitch hydrocracking reactor reaction conditions to be at or below the level where sediment formation would otherwise become excessive and prevent continuity of operations.

Abstract translation: 一种用于升级残油烃的方法，包括：将沥青，氢气和从加氢裂化反应器回收的部分废催化剂进料到沸腾床沥青加氢裂化反应器; 在沸腾床沥青加氢裂化反应器中的沥青，氢气和催化剂在足以将至少一部分沥青转化成馏出物烃的温度和压力的反应条件下接触; 并将馏出物烃与催化剂分离。 在一些实施方案中，该方法可以包括选择沸腾床沥青加氢裂化反应器反应条件处于或低于沉淀物形成否则将变得过大并防止操作连续性的水平。