Abstract:
A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a --Ar--(OH).sub.b I wherein R* is a hydrocarbyl group selected from the group consisting of hydrocarbyl groups of from about 8 to about 30 carbon atoms and polymers of at least 30 carbon atoms, Ar is an aromatic moiety having 0 to 4 optional substituents selected from the group consisting of lower alkyl, lower alkoxyl, nitro, halo or combinations of two or more of said optional substituents, and a and b are each independently an integer of 1 up to 5 times the number of aromatic nuclei present in Ar with the proviso that the sum of a and b does not exceed the unsatisfied valences of Ar;(iii) mixtures of (i) and (ii); and(B) as a second component, the reaction product of (B)(I) a hydrocarbyl-substituted carboxylic acylating agent with (B)(II) one or more amines, one or more alcohols, or a mixture of one or more amines and/or one or more alcohols, the hydrocarbyl substituent of said agent (B)(I) being selected from the group consisting of(i') one or more mono-olefins of from about 8 to about 30 carbon atoms;(ii') mixtures of one or more mono-olefins of from about 8 to about 30 carbon atoms with one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of polymers of mono-1-olefins of from 2 to 8 carbon atoms, or the chlorinated or brominated analogs of such polymers; and(iii') one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of(a) polymers of mono-olefins of from about 8 to about 30 carbon atoms;(b) interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with mono-olefins of from about 8 to about 30 carbon atoms;(c) one or more mixtures of homopolymers and/or interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with homopolymers and/or interpolymers of mono-olefins of from about 8 to about 30 carbon atoms; and(d) chlorinated or brominated analogs of (a), (b), or (c).
Abstract:
A new alkylated quinizarin, 2(2-ethylhexyl) quinizarin, useful for marking water immiscible organic liquids; marked water immiscible organic liquids; and a method of marking said liquids with an additive which may be subsequently extracted from said liquid and easily identified by visual inspection. The method comprises dissolving in the liquid to be marked an additive selected from the group consisting of an alkylated quinizarin, the reaction product of diazotized ortho tolidine and pnonylphenol and of diazotized xylidine and p-nonylphenol. The additive is detected by extraction from the marked liquid by means of a water soluble polar organic solvent containing a base and from 0 to about 75 percent by weight of water to yield a distinctively colored extract which is identified by visual inspection. The identification may be further corroborated by chromatographic separation of the additive or by spectrophotometric analysis.
Abstract:
Liquid hydrocarbon distillate fuel compositions are provided comprising a hydrocarbonaceous distillate fuel boiling in a gasoline range containing an aliphatic hydrocarbon substituted hydrazine. The aliphatic hydrocarbon radical is relatively free of aliphatic unsaturation and is of from about 400-5,000 molecular weight. The hydrazines useful in preparing the compounds of this invention may be mono- or di-substituted on one of the nitrogens, while the second nitrogen must have at least one hydrogen atom present prior to reaction with the aliphatic hydrocarbon.
WHEREIN RR1 IS SELECTED FROM THE GROUP OF TERTIARY BUTYL, TERTIARY AMYL, TERTIARY OCTYL AND TERTIARY DODECYL; R2 IS ALKYL WITH 1 TO 12 CARBON ATOMS, PREFERABLY UNSUBSTITUTED ALKYL WITH 1 TO 4 CARBON ATOMS SUCH AS METHYL OR TERTIARY BUTYL; R'' IS ALKYL WITH 1 TO 12 CARBON ATOMS WHICH CAN BE SUBSTITUTED WITH A HYDROXYL, HALOGEN OR MERCAPTO GROUP, PREFERABLY ALKYL WITH 1 TO 4 CARBON ATOMS SUCH AS METHYL, HYDROXY ETHYL OR HYDROXY PROPYL; N IS AN INTEGER FROM 0 TO 12, PREFERABLY 0 TO 2; AND WITH THE PROVISO THAT THE -OH GROUP IS ORTHO OR R1. SUCH COMPOUNDS ARE USEFUL TO STABILIZE ISOCYANATES AGAINST DISCOLORATION DURING STORAGE.
Abstract:
LUBRICATING OIL AND/OR LIQUID FUEL COMPOSITIONS CONTAIN OIL-SOLUBLE AZO COMPOUNDS. THE AZO COMPOUNDS IMPART TO THE COMPOSITIONS IMPROVED DISPERANT CHARACTERISTICS, CORROSION INHIBITION AND ANTI-WEAR PROPERTIES. THE PREDOMINANT OIL-SOLUBLE AZO REACTION PRODUCT MAY BE REPRESENTED BY THE FOLLOWING FORMULAS:
Y-C(=X)-NH-N(-R)-C(=X)-Y, OR Z-(OOC-NH-N(-R)-COO-E)N
WHEREIN R REPRESENTS AN OIL-SOLUBILIZING, SYNTHETIC, POLYMERIC ORGANIC RADICAL CONTAINING AT LEAST 20 CARBON ATOMS, Y IS INDEPENDENTLY SELECTED FROM THE GROUP CONSISTING OF -OR1-NR2R3 AND -SR4. R1,R2,R3 AND R4 ARE INDEPENDENTLY SELECTED FROM HYDROGEN, ALKYL, CYCLOALKYL, ARYL, ALKARYL AND ARALKYL, X IS INDENPENDENTLY SELECTED FROM OXYGEN, SULFUR AND =NR5, WITH PROVISO THAT WHEN X IS =NR5, Y IS -NR2R3, R5 IS SELECTED FROM THE GROUP CONSISTING OF ALKYL, CYCLOALKYL, ARYL AND ALKARYL. Z REPRESENTS A POLYVALENT ORGANIC RADICAL HAVING A VALENCE OF " AND SELECTED FROM HYDROCARBON, OXXAHYDROCARBON, AZAHYDROCARBON AND THIAHYDROCARBON RADICALS AND THEIR OXYGENATED AND HALOGENATED DERIVATIVES, E IS A MONOVALENT RADICAL SELECTED FROM ALKYL, CYCLOALKYL, ARALKYL, ARYL AND ALKARYL, AND N IS AN INTEGER FROM 2 TO 5.