Abstract:
The present invention relates to a process for the continuous preparation of organic mono- or polyisocyanates by the reaction of the mono- or polyamines corresponding to the mono- or polyisocyanates with phosgene dissolved in an organic solvent. The phosgene solution and the amine component, optionally also in the form of a solution, are brought together inside a nozzle (1) by subjecting the stream of one component to a constriction (3) and supplying the other component into this constriction (3) from the side as partial streams through several apertures (5).
Abstract:
A multistage vortex reactor for contacting a gas stream with a gas, a fluid or other stream, comprising a housing having end walls and a peripheral side wall defining an elongated generally cylindrical vortex chamber having an inlet end and an outlet end, a first inlet in the inlet end of the vortex chamber for introducing a first gas stream in a swirling motion into the vortex chamber, a second inlet for introducing a second gas stream adjacent the inlet end of the vortex chamber for flowing around at least a part of the vortex chamber for separating the first stream from said chamber walls, a supply duct divides a gas stream into at least a first gas stream and a second gas stream and introduces the first gas stream into the first inlet in the vortex chamber and the second gas stream into the second inlet, an injector for introducing a liquid into the first gas stream in the vortex chamber, and an outlet for continuously removing gas from the vortex chamber.
Abstract:
Process for effecting rapid and homogenous intimate contact of substances which occur in different phases. The process includes a step of producing contact between a helicoidal flow of substances, at least partially in the gaseous state, and a rectilinear flow which is coaxial with the first flow, of liquid or solid substances, at the outlet of a flow passage having a downstream constricted aperture, the amount of movement of the helicoidal flow at the outlet being at least 100 times greater than that of the rectilinear flow. This process can be used in particular for producing mixtures or for drying substances.
Abstract:
Process and apparatus for pyrolysis of a heavy hydrocarbon feedstock in which the feedstock is countercurrently contacted with a hot hydrogenating gas stream flowing spirally from the periphery of a substantially circular reactor (1). The hydrocarbon feedstock is injected through an inlet (4) located toward the center of reactor (1). The hot hydrogenating gas is preferably formed by combustion, using a steam-oxygen mixture injected through inlet (2), of carbonaceous by-products from the pyrolysis. Product is removed centrally through outlet (3).
Abstract:
The entrainment of reaction medium in the vapor phase and the entrainment of gaseous phase in liquid phase are decreased in a chlorine dioxide generator (12) producing a gaseous mixture of chlorine dioxide, chlorine and steam from a boiling reaction medium (14) and wherein generator liquor is recycled with make up chemicals. These results are achieved by generator modifications, which include tangential entry (30) of recycled liquor to the generator (12) in the vapor space (16) above the liquid level in the generator (12), and the provision of a baffle (34, 50) projecting inwardly from the generator wall in the vapor space (16) and arranged to be above the trajectory of the recycled liquor as it enters the generator (12). These modifications enable the generator volume to be decreased substantially, with consequentially decreased capital costs.
Abstract:
Animal feed grade phosphates such as mono-calcium phosphate, di-calcium phosphate or mixtures thereof are produced by direct reaction between phosphoric acid and Ca-containing materials. A finely ground, preheated calcium carbonate suspension is brought to react with a suitable quantity of preheated phosphoric acid by introducing the reactants into a short, tubular reaction zone, open at one end, whereby development of gas and intensive mixing of the reactants in the reaction zone take place. The gas formed by the reaction expels or ejects the foaming reaction mixture from the tube-like reaction zone, the reaction being substantially completed while the individual particles of the mixture are freely suspended in air or gas, whereafter the reacted mixture is collected in the form of a free-flowing granulate having improved handling properties, without any further quenching treatment of the granules. An apparatus for carrying out the process includes a reaction chamber connected with separate feed lines for calcium carbonate suspension and phosphoric acid, respectively, and means for collecting and further processing the resultant reaction product. The reaction chamber has the form of a tube reactor having an open end portion which forms a discharge which is arranged for cooperation with a suspension chamber and a collecting device arranged at the lower end of the chamber.
Abstract:
An apparatus for carrying out chlorinating reactions when extracting metalsuch as titanium, zirconium or the like during the extraction of uranium and thorium during the reprocessing of burned-off fuel and/or breeder elements for core reactors and during the purification of coal and graphite. The device comprises a shaft or blast furnace which is heated by a direct flow of current and while being coaxially surrounded by a mantle or shell communicates through a connection or adapter piece with a subsequent condenser of graphite. The device according to the present invention is characterized primarily in that the shell of the furnace and the adapter piece connecting the furnace with the condenser are made of graphite. The shell of the furnace, the condenser and the adapter piece connecting the shell with the condenser are arranged within a steel casing designed in a gas-tight manner.
Abstract:
Continuous manufacture of propylene oxide by turbulent jet mixing of propylene chlorohydrin solution with aqueous alkali, mixing with steam to produce a two-phase mixture and a special working-up process following turbulent passage through a reaction zone with a short residence time. Propylene oxide is obtained in high yield and high space-time yield.
Abstract:
Multistage vortical mass contact between one medium in continuous phase and a second medium in discontinuous particulate phase is effected by providing a plurality of vortical contact chambers in concentric and coplanar relationship, one within the next. The continuous medium is caused to flow inwardly from outer stages to inner stages and establish a vortical flow in each stage. The particulate medium is introduced into the flow of the continuous phase medium and suspended therein by its vortical flow and is caused to move outwardly from inner stages to outer stages countercurrent to the flow of said continuous phase medium.
Abstract:
IN THE PARTICULAR EMBODIMENTS OF THE INVENTION DESCRIBED HEREIN, GAS-LIQUID REACTIONS ARE CARRIED OUT BY CONTINUOUSLY INJECTING THE NORMALLY GASEOUS REACTANT INTO A CONFINED STREAM OF THE LIQUID REACTANT AND PASSING THE GAS-LIQUID MIXTURE THROUGH A CONFINED TORTUOUS FLOW PATH SO AS TO INDUCE TURBULENCE IN THE MIXTURE. TYPICAL REACTIONS ARE AMMONIA-PHOSPHORIC ACID REACTIONS AND CHLORINATION AND HYDROGENATION REACTIONS.