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    HYDROTREATING CATALYST FOR HYDROCARBON OIL AND METHOD FOR PRODUCING SAME, AND HYDROCARBON OIL HYDROTREATING METHOD USING SAME
    83.
    发明申请
    HYDROTREATING CATALYST FOR HYDROCARBON OIL AND METHOD FOR PRODUCING SAME, AND HYDROCARBON OIL HYDROTREATING METHOD USING SAME 有权
    烃油的加氢催化剂及其生产方法，以及使用相同的油气加氢方法

    公开(公告)号：US20120318717A1

    公开(公告)日：2012-12-20

    申请号：US13581997

    申请日：2011-03-22

    Applicant: Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

    Inventor： Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

    IPC: B01J31/38 ,  C10G45/10

    CPC classification number: B01J31/38 ,  B01J21/04 ,  B01J21/063 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0033 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0207 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/06 ,  C10G45/08

    Abstract: Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.

    Abstract translation: 提供：具有加氢脱硫活性的烃油的加氢处理催化剂，其另外通过以下方式进一步提高：在含有氧化铝水合物颗粒的水溶胶的同时并连续地将含有钛的酸性化合物的水溶液和含有碱性化合物的水溶液加入到含有水合氧化铝颗粒的水溶胶中 10至100℃，pH为4.5至6.5; 洗涤所得物以除去污染的离子; 在脱水后形成洗涤后的产品，使其具有可形成的水分含量; 干燥结果; 用含有至少一种周期表6族金属化合物，至少一种周期表第8-10族金属化合物，至少一种磷化合物和至少一种类型的磷化合物的催化组分水溶液浸渍干燥产物 的糖; 并干燥所得物; 催化剂的制造方法; 以及使用该催化剂的烃油的加氢脱硫处理方法。

    HYDROCRACKING CATALYST
    84.
    发明申请
    HYDROCRACKING CATALYST 有权
    水解催化剂

    公开(公告)号：US20120055846A1

    公开(公告)日：2012-03-08

    申请号：US13266713

    申请日：2010-04-15

    Applicant: László Domokos ,  Cornelis Ouwehand

    Inventor： László Domokos ,  Cornelis Ouwehand

    IPC: C10G47/14 ,  B01J37/08 ,  B01J29/10 ,  B01J29/08 ,  B01J29/80

    CPC classification number: B01J29/166 ,  B01J29/084 ,  B01J29/146 ,  B01J29/7007 ,  B01J29/7815 ,  B01J29/80 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0201 ,  B01J2229/16 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/40 ,  B01J2229/42 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G2300/70

    Abstract: Process of preparing a hydrocracking catalyst carrier comprising amorphous binder and zeolite Y, which process comprises subjecting zeolite Y having a silica to alumina molar ratio of at least 10 to calcination at a temperature of from 700 to 1000° C., hydrocracking catalyst carrier comprising amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, the infrared spectrum of which catalyst has a peak at 3690 cm−1, substantially reduced peaks at 3630 cm−1 and 3565 cm−1 and no peak at 3600 cm−1, hydrocracking catalyst carrier comprising an amorphous binder and zeolite Y having a silica to alumina molar ratio of at least 10, which catalyst has an acidity as measured by exchange with perdeuterated benzene of at most 20 micro-mole/gram, hydrocracking catalyst derived from such carrier and hydrocracking process with the help of such catalyst.

    Abstract translation: 制备包含无定形粘合剂和沸石Y的加氢裂化催化剂载体的方法，该方法包括将二氧化硅与氧化铝摩尔比至少为10的沸石Y在700至1000℃的温度下煅烧，加氢裂化催化剂载体包含非晶态 粘结剂和二氧化硅与氧化铝摩尔比至少为10的沸石Y，其催化剂在3690cm -1处具有峰值的红外光谱，在3630cm-1和3565cm -1处基本上减少的峰，在3600cm处没有峰 -1，包含无定形粘合剂的加氢裂化催化剂载体和二氧化硅与氧化铝摩尔比至少为10的沸石Y，该催化剂具有通过与每氘代苯交换至多20微摩尔/克的加氢裂化催化剂得到的酸度 从这种载体和加氢裂化过程中借助于这种催化剂。

    Selective hydrogenation catalyst for pyrolysis gasoline
    87.
    发明授权
    Selective hydrogenation catalyst for pyrolysis gasoline 有权
    用于热解汽油的选择性氢化催化剂

    公开(公告)号：US06576586B2

    公开(公告)日：2003-06-10

    申请号：US09767238

    申请日：2001-01-22

    Applicant: Li Siqin ,  Men Xiaotang ,  Gensheng Liu ,  Shunqin Liang ,  Xiaogong Zhang

    Inventor： Li Siqin ,  Men Xiaotang ,  Gensheng Liu ,  Shunqin Liang ,  Xiaogong Zhang

    IPC: B01J2358

    CPC classification number: C10G45/40 ,  B01J21/04 ,  B01J23/58 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085

    Abstract: A selective hydrogenation catalyst for pyrolysis gasoline. The catalyst mainly consists of a support of &dgr;, &agr; mixed alumina covered by palladium and alkali metal and/or alkaline-earth metal which are distributed on the support surface, and the support has 0.5 to 09. ml/g of specific pore volume. 40 to 200 Å pores account for more than 85% of the total pore volume. The specific surface area is 70 to 140 m2/g, and &agr; crystal structure in the alumina support is 0.5 to 5% based on the weight percentage of &dgr;, &agr; mixed alumina support. The catalyst includes palladium in amount of 0.05 to 0.4 wt %, alkali metal and/or alkaline-earth metal in amount of 0.05 to 2.0 wt %.

    Abstract translation: 用于热解汽油的选择性氢化催化剂。 催化剂主要由分布在载体表面上的由钯和碱金属和/或碱土金属覆盖的δ，α混合氧化铝的载体组成，载体的比孔数为0.5至09.ml / g。 40至200埃的孔隙占总孔隙体积的85％以上。 比表面积为70〜140m2 / g，氧化铝载体中的α晶体结构相对于δ，α混合氧化铝载体的重量百分比为0.5〜5％。 催化剂的含量为0.05〜0.4重量％的钯，碱金属和/或碱土金属的含量为0.05〜2.0重量％。

    Combustion catalysts and processes for removing organic compounds
    88.
    发明申请
    Combustion catalysts and processes for removing organic compounds 失效
    燃烧催化剂和除去有机化合物的方法

    公开(公告)号：US20020155051A1

    公开(公告)日：2002-10-24

    申请号：US10123312

    申请日：2002-04-17

    Applicant: TOSOH CORPORATION

    Inventor： Wataru Kobayashi ,  Masao Nakano

    IPC: B01D053/68

    CPC classification number: B01J21/066 ,  B01D53/8662 ,  B01D53/8668 ,  B01J21/06 ,  B01J21/063 ,  B01J23/42 ,  B01J29/068 ,  B01J29/18 ,  B01J29/40 ,  B01J29/7007 ,  B01J35/0006 ,  B01J35/10 ,  B01J35/1085 ,  B01J2229/20

    Abstract: Catalysts for removing organic compounds from a gas stream containing the same and processes for removing organic compounds from the gas stream using the catalysts are disclosed. According to the first aspect, a combustion catalyst for removing organic compounds comprises a mixture of a zeolite and a metal oxide containing at least one of the elements of the platinum group. According to the second aspect, a combustion catalyst for removing organic compounds comprises an alumina having such a pore size distribution that, where nullanull represents a pore radius in null at the maximum of the pore size distribution curve, the accumulated pore volume of pores having radii in the range of nullanull null25 null is at least 65% of the total volume of all the pores, said alumina containing less than 1% by weight of rare earth elements and being loaded with one or more elements of the platinum group. According to the third aspect, a process for removing organic compounds, said process comprising the step of contacting organic compounds with either one of the catalysts according to the first and second aspects of the invention.

    Abstract translation: 公开了从含有该有机化合物的气流中除去有机化合物的催化剂和使用该催化剂从气流中除去有机化合物的方法。 根据第一方面，用于除去有机化合物的燃烧催化剂包括沸石和含有至少一种铂族元素的金属氧化物的混合物。 根据第二方面，用于除去有机化合物的燃烧催化剂包括具有孔径分布的氧化铝，其中“a”表示孔径分布曲线最大值处的孔半径，孔的累积孔体积 具有在“a”±25范围内的半径是所有孔的总体积的至少65％，所述氧化铝含有少于1重量％的稀土元素并且装载有一种或多种铂的元素 组。 根据第三方面，一种除去有机化合物的方法，所述方法包括使有机化合物与根据本发明的第一和第二方面的任一种催化剂接触的步骤。

    Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production
    89.
    发明授权
    Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production 失效
    单峰和多模式催化剂载体和具有窄孔径分布及其生产的催化剂

    公开(公告)号：US5935898A

    公开(公告)日：1999-08-10

    申请号：US711989

    申请日：1996-09-10

    Applicant: Peter Trubenbach ,  Alfred Hagemeyer ,  Gunter Lauth ,  Uwe Dingerdissen ,  Franz Josef Brocker ,  Klemens Flick

    Inventor： Peter Trubenbach ,  Alfred Hagemeyer ,  Gunter Lauth ,  Uwe Dingerdissen ,  Franz Josef Brocker ,  Klemens Flick

    IPC: C12M1/40 ,  B01J21/00 ,  B01J27/00 ,  B01J29/00 ,  B01J35/10 ,  B01J37/00 ,  B01J23/00

    CPC classification number: B01J37/0018 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/108 ,  B01J35/1085

    Abstract: Monomodal or polymodal catalyst supports or catalysts having a BET specific surface area of from 0.01 to 250 m.sup.2 /g and a monomodal or polymodal pore size distribution having a mean pore diameter of from 50 to 300,000 nm measured by the mercury pressure porosimetry method, whereina) from 10 to 95% of the pore volume is at from 0.1 to 3 times the mean pore diameter and/orb) from 10 to 80% of the pore volume is at from 0.4 to 3 times the mean pore diameter and/orc) from 50 to 95% of the pore volume is at from 0.1 to 1 times the mean pore diameter and/ord) from 50 to 80% of the pore volume is at from 0.4 to 1 times the mean pore diameter ande) the width at half height of the pore size distribution is less than 0.5 times the mean pore diameter,which are useful for preparing chlorine from hydrogen chloride in a non-steady-state Deacon process, for the reaction of ethylbenzene to give styrene in a non-steady-state oxydehydrogenation, for preparing aziridine from ethanolamine, in reductions, hydrogenations, oxidations, dehydrogenations, acid- or base-catalyzed reactions or reactions in a fluidized bed, for removing combustion residues from diesel exhaust gases and for removing NO.sub.x from waste gases, in bioreactors together with bacteria and as biocatalyst supports with immobilized enzymes or microbes, and a process for producing said monomodal or polymodal catalyst supports or catalysts.

    Abstract translation: 单峰或多模式催化剂载体或BET比表面积为0.01至250m 2 / g的催化剂载体和通过汞压孔隙度法测量的平均孔径为50至300,000nm的单峰或多模孔径分布，其中a ）孔体积的10至95％为平均孔径的0.1至3倍和/或b）孔体积的10至80％为平均孔径的0.4至3倍和/或c ）孔体积的50至95％为平均孔径的0.1至1倍，和/或d）孔体积的50至80％为平均孔径的0.4至1倍，e） 孔尺寸分布的半高宽度小于平均孔径的0.5倍，这可用于在非稳态Deacon方法中从氯化氢制备氯，用于乙苯的反应， 稳态氧化脱氢，用于从乙醇胺制备氮丙啶，还原 ns，氢化，氧化，脱氢，酸或碱催化的反应或在流化床中的反应，用于从生物反应器中连同细菌和作为生物催化剂载体与固定化酶一起从柴油机排气中除去燃烧残余物并从废气中除去NOx 或微生物，以及用于生产所述单峰或多模式催化剂载体或催化剂的方法。

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