Abstract:
The use of nitroxide compounds alone or in combination with aromatic amines, such as substituted phenylenediamines, or phenolic antioxidants provides an effective way to prevent oxidative degradation and gum formation in gasolines, especially unstable coker and pyrolysis gasolines.
Abstract:
Aromatic ethers of polyalkylphenoxyalkanols having the formula: ##STR1## or a fuel soluble salt thereof, wherein R is hydroxy, nitro or --(CH.sub.2).sub.x -NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 are independently hydrogen or lower alkyl having 1 to carbon atoms, and x is 0 or 1; R.sub.1 is hydrogen, hydroxy, nitro or --NR.sub.7 R.sub.8, wherein R.sub.7 and R.sub.8 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.2 and R.sub.3 are independently hydrogen or lower alkyl having 1 to 6 carbon atoms; and R.sub.4 is a polyalkyl group having an average molecular weight in the range of about 450 to 5,000. The compounds of formula I are useful as fuel additives for the prevention and control of engine deposits.
Abstract translation:具有下式的聚烷基苯氧基烷醇的芳香醚:其中R是羟基,硝基或 - (CH2)x-NR5R6,其中R5和R6独立地是氢或具有1至碳的低级烷基 原子,x为0或1; R 1是氢,羟基,硝基或-NR 7 R 8,其中R 7和R 8独立地是氢或具有1至6个碳原子的低级烷基; R2和R3独立地是氢或具有1-6个碳原子的低级烷基; 并且R 4是平均分子量在约450至5,000范围内的聚烷基。 式I化合物可用作预防和控制发动机沉积物的燃料添加剂。
Abstract:
Polylactone aminocarbamates having the formula: ##STR1## wherein R.sub.1 is a hydrocarbyl group having a sufficient number of carbon atoms to render the compound soluble in hydrocarbons boiling in the gasoline or diesel fuel range;R.sub.2 is an alkylene group of about 2 to 5 carbon atoms;A is a polyamine moiety having at least one basic nitrogen atom;and x is an integer from 1 to 25.The polylactone aminocarbamates of formula I are useful as fuel additives for the prevention and control of engine deposits.
Abstract:
The invention is a composition for use in deactivating iron species in hydrocarbon fluids, comprising the products resulting from the reaction of (I), with (II) and (III) is disclosed; wherein (I) is a substituted catechol of the structure ##STR1## where R is chosen from alkyl, aryl, alkaryl, or arylalkyl from about 1 to 20 carbon atoms; wherein (II) is a mixture of polyamines having the repeat structure ##STR2## wherein m ranges from 1 to 10 and where X is an alkyl, branched alkyl, cyclic or branched cyclic alkyl of from 1 to 10 carbon atoms, and where Y is a substituted alkylphenol of structure ##STR3## where R" is chosen from alkyl, aryl, alkaryl, arylalkyl of from about 1 to 22 carbon atoms; wherein (III) is an aldehyde of structure ##STR4## where R' is chosen from hydrogen, and an alkyl of from 1 to 6 carbon atoms. Also disclosed is the function of the said same composition, resulting from the reaction of (I) with (II) and (III), as an antioxidant in hydrocarbon fluids. The antioxidant function is separate from, and in addition to the metal deactivating properties of the invention. These functional properties of the invention can act either singly, or in concert, for the stabilization of hydrocarbon fluids. Further a method of deactivating iron species in hydrocarbon fluids using the described compound is disclosed.
Abstract:
A novel compound comprises a chemical compound comprising or including a cyclic ring system such as an aromatic ring system, the compound carrying at least two substituents of the general formula (I) below on the ring system--A--NR.sup.1 R.sup.2 (I)where A is an aliphatic hydrocarbyl group that is optionally interrupted by one or more hetero atoms and that is straight chain or branched, and R.sup.1 and R.sup.2 are the same or different and each is independently a hydrocarbyl group containing 9 to 40 carbon atoms, optionally interrupted by one or more hetero atoms, the substituents being the same or different and the compound optionally being in the form of a salt thereof.Such compounds may be used as additives for improving the cold flow properties of crude oil, lubricating oil or fuel oil.
Abstract:
.beta.-Aminonitriles of the following formula I ##STR1## where R.sup.1 is an aliphatic hydrocarbon radical having alkyl side groups and a number average molecular weight of from 250 to 5,000 and R.sup.2, R.sup.3 and R.sup.4, independently of one another, are each hydrogen or C.sub.1 -C.sub.8 -alkyl and R.sup.2 or R.sup.4 is also phenyl, and alkylpropylenediamines prepared from the .beta.-aminonitriles by hydrogenation are used as additives in fuels and lubricants.
Abstract translation:其中R1是具有烷基侧基和数均分子量为250至5,000的脂族烃基,R2,R3和R4彼此独立地为氢或 C 1 -C 8 - 烷基和R 2或R 4也是苯基,并且通过氢化由β-氨基腈制备的烷基丙二胺用作燃料和润滑剂中的添加剂。
Abstract:
Fuel compositions containing a major amount of hydrocarbons boiling in the gasoline or diesel range and an effective deposit-controlling amount of a poly(oxyalkylene) aromatic ether having the formula: ##STR1## where A.sub.1 is nitro, amino, N-alkylamino wherein the alkyl group contains 1 to 6 carbon atoms, or N,N-dialkylamino wherein each alkyl group independently contains 1 to 6 carbon atoms; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl, or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl and each R.sub.3 and R.sub.4 is independently selected in each --O--CHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to 100 carbon atoms, phenyl, aralkyl having 7 to 100 carbon atoms or alkaryl having 7 to 100 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10.
Abstract:
An additive composition for fuels comprising at least one constituent (A) and at least one constituent (B), the said constituent (A) comprising at least one multinitrogen-containing compound of general formula (I): ##STR1## where R.sup.1 and R.sup.2, which are the same or different each represent a hydrocarbon group or a group of formula R.sup.5 --(--O--R.sup.6 --).sub.a --(--O--R.sup.7 --).sub.b --, R.sup.3 is a hydrocarbon group or a group of formula R.sup.8 --(--X--R.sup.9 --).sub.c --(--X--R.sup.1 O--).sub.d --(--X--R.sup.1 1--).sub.e -- in which X is selected from the groups --O-- and --NR.sup.1 2--, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.1 0 and R.sup.1 1 each represent a hydrocarbon group, a, d and e are each zero or a whole number, b and c are each a whole number, R.sup.4 and R.sup.1 2 each represent a hydrogen atom or a hydrocarbon group and n is a number from 0 to 20 and the said constituent (B) comprises at least one polyglycol which is soluble in the fuel in question. The additive composition may also contain a detergent-dispersant product. These compositions are useful as multipurpose additives for fuels used in internal combustion engines, in particular in spark ignition engines.
Abstract:
A fuel additive composition comprising:(a) a poly(oxyalkylene) hydroxyaromatic ether having the formula: ##STR1## or a fuel-soluble salt thereof; where R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is hydrogen, alkyl having 1 to 30 carbon atoms, phenyl, aralkyl or alkaryl having 7 to 36 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, or aralkyl or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10; and(b) a poly(oxyalkylene) amine having at least one basic nitrogen atom and a sufficient number of oxyalkylene units to render the poly(oxyalkylene) amine soluble in hydrocarbons boiling in the gasoline or diesel fuel range.
Abstract translation:一种燃料添加剂组合物,其包含:(a)具有下式的聚(氧化烯)羟基芳族醚或其燃料可溶性盐; 其中R 1和R 2各自独立地为氢,羟基,具有1至6个碳原子的低级烷基或具有1至6个碳原子的低级烷氧基; R 3和R 4各自独立地为氢或具有1至6个碳原子的低级烷基; R 5是氢,具有1至30个碳原子的烷基,具有7至36个碳原子的苯基,芳烷基或烷芳基,或下式的酰基:其中R 6是具有1至30个碳原子的烷基,苯基或芳烷基 或具有7至36个碳原子的烷芳基; n为5〜100的整数。 x为0〜10的整数。 和(b)具有至少一个碱性氮原子和足够数量的氧化烯单元的聚(氧化烯)胺,以使聚(氧化烯)胺可溶于汽油或柴油燃料范围内沸腾的烃。
Abstract:
A diesel fuel composition comprising a major portion of a middle distillate fuel oil and a minor portion, effective to clean deposits from diesel fuel injectors, of a diesel fuel detergent comprising the reaction product of:(a) a 4-alkyl-2-morpholinone represented by the formula: ##STR1## in which R represents a monovalent aliphatic radical having from 1 to 10 carbon atoms, and(b) an alkylphenoxypolyoxyalkylene amine represented by the formula: ##STR2## in which R' represents a hydrocarbyl radical having from 4 to 30 carbon atoms, x has a value from 5 to 50, and R" represents a methyl radical or a mixture of hydrogen and methyl radicals.A method of cleaning diesel fuel injectors is also provided.