公开(公告)号：US20180015447A1

公开(公告)日：2018-01-18

申请号：US15674795

申请日：2017-08-11

Applicant: BASF Corporation

Inventor： Jim Aloysius Maria Brandts ,  Lorianne Wagemaker

IPC: B01J29/89 ,  B01J37/03 ,  C11C3/10 ,  B01J37/06 ,  C01B33/20 ,  B01J37/30 ,  B01J37/08 ,  C02F1/28 ,  B01J35/10 ,  B01J35/00 ,  C02F101/30 ,  C02F1/42 ,  C02F101/00 ,  C02F101/20

CPC classification number: B01J29/89 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/18 ,  C01B33/20 ,  C02F1/281 ,  C02F1/42 ,  C02F2101/006 ,  C02F2101/20 ,  C02F2101/30 ,  C11C3/10

Abstract: The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesteritications, (ep)oxidations, hydroxylations, or in absorbance of small inorganic and organic molecules e.g. CO2 or aromatic compounds.

公开(公告)号：US08981136B2

公开(公告)日：2015-03-17

申请号：US14350688

申请日：2012-10-12

Applicant: BASF Corporation

Inventor： Jim Aloysius Maria Brandts

IPC: C11C3/00 ,  C07C67/03

CPC classification number: C07C67/03 ,  C10L1/026 ,  C10L2200/0476 ,  C10L2290/00 ,  C11C3/003 ,  Y02E50/13 ,  C07C69/24 ,  C07C69/52

Abstract: The invention relates to a process for making esters, in particular biodiesel, using heterogeneous catalysts. The invention provides a process for making biodiesel, in particular FAME, which process is versatile and robust. The process of the invention can be carried out continuously, in particular in a fixed bed reactor or a slurry reactor and may be operated in a continuous fashion. In accordance with the invention, the transesterification reaction of triglycerides is carried out using a heterogeneous catalyst that comprises a Group 4 silicate and less than 3 wt. % Na in the presence of at least one acid compound.

Abstract translation: 本发明涉及使用多相催化剂制备酯，特别是生物柴油的方法。 本发明提供了一种制备生物柴油，特别是FAME的方法，该方法是通用且鲁棒的。 本发明的方法可以连续进行，特别是在固定床反应器或淤浆反应器中，并且可以以连续的方式操作。 根据本发明，甘油三酯的酯交换反应使用包含4族硅酸盐并且小于3重量％的多相催化剂进行。 ％Na在至少一种酸化合物的存在下。

公开(公告)号：US10286390B2

公开(公告)日：2019-05-14

申请号：US15674795

申请日：2017-08-11

Applicant: BASF Corporation

Inventor： Jim Aloysius Maria Brandts ,  Lorianne Wagemaker

IPC: B01J29/89 ,  B01J35/00 ,  C02F1/28 ,  C01B33/20 ,  B01J35/10 ,  B01J37/03 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  C11C3/10 ,  C02F1/42 ,  C02F101/00 ,  C02F101/20 ,  C02F101/30

Abstract: The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesterifications, (ep)oxidations, hydroxylations, or in absorbance of small inorganic and organic molecules e.g. CO2 or aromatic compounds.

公开(公告)号：US20160067693A1

公开(公告)日：2016-03-10

申请号：US14785184

申请日：2014-04-16

Applicant: BASF CORPORATION

Inventor： Jim Aloysius Maria Brandts ,  Lorianne Wagemaker

IPC: B01J29/89 ,  B01J37/03 ,  C11C3/10 ,  B01J37/06 ,  B01J37/30 ,  C01B33/20 ,  B01J37/08

CPC classification number: B01J29/89 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/18 ,  C01B33/20 ,  C02F1/281 ,  C02F1/42 ,  C02F2101/006 ,  C02F2101/20 ,  C02F2101/30 ,  C11C3/10

Abstract: The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesterifications, (ep)oxidations, hydroxylations, or in adsorbance of small inorganic and organic molecules e.g. CO2 or aromatic compounds.

Abstract translation: 本发明提供了一种制备元素周期表第4族中至少一种金属的无定形硅酸盐的方法，其总孔体积至少为0.3mL / g。 制备方法包括使用孔成型条件，其可以使用孔隙整形器和任选地增加的沉淀温度，例如， 本发明的硅酸盐特别适用于催化反应，例如酯化，迈克尔加成，酯交换，（ep）氧化，羟基化或吸附小的无机和有机分子，例如， 二氧化碳或芳香族化合物。

公开(公告)号：US09579635B2

公开(公告)日：2017-02-28

申请号：US14651937

申请日：2013-12-12

Applicant: BASF CORPORATION

Inventor： Jacobus Hoekstra ,  Jim Aloysius Maria Brandts ,  Lorianne Wagemaker ,  John Wilhelm Geus ,  Leonardus Wijnand Jenneskens

IPC: B01J23/75 ,  C07C1/00 ,  B01J23/745 ,  B01J21/18 ,  B01J31/06 ,  B01J35/02 ,  B01J35/10 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/16 ,  H01F41/02 ,  B01J20/20 ,  H01F1/00 ,  H01F1/28 ,  B01J20/28 ,  B01J20/02 ,  B01J20/06 ,  B01J20/30 ,  B01J20/32 ,  C02F1/28 ,  C02F1/48

CPC classification number: B01J23/745 ,  B01J20/02 ,  B01J20/06 ,  B01J20/20 ,  B01J20/205 ,  B01J20/28009 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28083 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3268 ,  B01J21/18 ,  B01J21/185 ,  B01J31/06 ,  B01J35/0033 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/082 ,  B01J37/16 ,  B01J2231/62 ,  B01J2531/002 ,  B01J2531/008 ,  C02F1/281 ,  C02F1/283 ,  C02F1/288 ,  C02F1/488 ,  C02F2305/08 ,  H01F1/0063 ,  H01F1/28 ,  H01F41/0266 ,  Y10T428/2982

Abstract: The invention is in the field of modified carbon products. More in particular, the invention is in the field of graphitized activated carbon bodies. The invention is directed to carbon bodies and ferromagnetic carbon bodies, the production of these bodies from activated carbon, and the applications of the carbon bodies and ferromagnetic carbon bodies, for instance in water treatment and in electrochemical applications.

Abstract translation: 本发明是在改性碳产品领域。 更具体地，本发明在石墨化活性炭体领域。 本发明涉及碳体和铁磁性碳体，从活性炭生产这些体，以及碳体和铁磁性碳体的应用，例如在水处理和电化学应用中。

公开(公告)号：US10814310B2

公开(公告)日：2020-10-27

申请号：US14782665

申请日：2014-04-10

Applicant: BASF Corporation

Inventor： Jim Aloysius Maria Brandts

IPC: B01J23/14 ,  B01J37/03 ,  B01J35/10 ,  C01B33/20 ,  B01J37/02 ,  G21F9/12 ,  B01J39/14 ,  C02F1/28 ,  B01J21/08 ,  B01J20/10 ,  B01J21/06 ,  B01J20/28 ,  B01J20/30 ,  B01J35/02 ,  B01J37/08 ,  B01J37/30 ,  C07C67/08 ,  C02F103/06 ,  C02F101/20 ,  C02F101/00 ,  C02F101/32

Abstract: The present invention relates to an amorphous titanium stannate silicate with the general formula: Mv+wTixSiySnzO2x+2y+2z+0.5vw, wherein M is proton, ammonium, a metal or a mixture of metals, wherein v is the valence of M being a positive integer, and wherein x, y, z and w are molar ratios: x is 1, y is from 0.01 to 99, z is from 0.01 to 99, and w is from 0.01 to 50. The described titanium stannate silicates are particularly useful in catalysis and adsorption.

公开(公告)号：US09764315B2

公开(公告)日：2017-09-19

申请号：US14785184

申请日：2014-04-16

Applicant: BASF Corporation

Inventor： Jim Aloysius Maria Brandts ,  Lorianne Wagemaker

IPC: B01J29/89 ,  B01J37/30 ,  C11C3/10 ,  C01B33/20 ,  C02F1/28 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/06 ,  B01J37/08 ,  C02F1/42 ,  C02F101/00 ,  C02F101/20 ,  C02F101/30

CPC classification number: B01J29/89 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/18 ,  C01B33/20 ,  C02F1/281 ,  C02F1/42 ,  C02F2101/006 ,  C02F2101/20 ,  C02F2101/30 ,  C11C3/10

Abstract: The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesterifications, (ep)oxidations, hydroxylations, or in adsorbance of small inorganic and organic molecules e.g. CO2 or aromatic compounds.

公开(公告)号：US20160067677A1

公开(公告)日：2016-03-10

申请号：US14782665

申请日：2014-04-10

Applicant: BASF CORPORATION

Inventor： Jim Aloysius Maria Brandts

IPC: B01J23/14 ,  B01J35/02 ,  B01J37/03 ,  B01J37/30 ,  C07C67/08 ,  B01J20/10 ,  B01J20/28 ,  B01J20/30 ,  C01B33/20 ,  B01J35/10 ,  B01J37/08

Abstract: The present invention relates to an amorphous titanium stannate silicate with the general formula: Mv+wTixSiySnzO2x+2y+2z+0.5vw, wherein M is proton, ammonium, a metal or a mixture of metals, wherein v is the valence of M being a positive integer, and wherein x, y, z and w are molar ratios: x is 1, y is from 0.01 to 99, z is from 0.01 to 99, and w is from 0.01 to 50. The described titanium stannate silicates are particularly useful in catalysis and adsorption.

Abstract translation: 本发明涉及具有以下通式的无定形锡酸锡硅酸盐：Mv + wTixSiySnzO2x + 2y + 2z + 0.5vw，其中M为质子，铵，金属或金属混合物，其中v为M的化合价为 正整数，并且其中x，y，z和w是摩尔比：x为1，y为0.01至99，z为0.01至99，w为0.01至50.所述锡酸锡硅酸盐特别有用 在催化和吸附。

公开(公告)号：US20150328621A1

公开(公告)日：2015-11-19

申请号：US14651937

申请日：2013-12-12

Applicant: BASF CORPORATION

Inventor： Jacobus Hoekstra ,  Jim Aloysius Maria Brandts ,  Lorianne Wagemaker ,  John Wilhelm Geus ,  Leonardus Wijnand Jenneskens

IPC: B01J23/745 ,  B01J31/06 ,  B01J35/02 ,  H01F41/02 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/16 ,  B01J21/18 ,  B01J35/10

CPC classification number: B01J23/745 ,  B01J20/02 ,  B01J20/06 ,  B01J20/20 ,  B01J20/205 ,  B01J20/28009 ,  B01J20/28057 ,  B01J20/28069 ,  B01J20/28083 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3268 ,  B01J21/18 ,  B01J21/185 ,  B01J31/06 ,  B01J35/0033 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/082 ,  B01J37/16 ,  B01J2231/62 ,  B01J2531/002 ,  B01J2531/008 ,  C02F1/281 ,  C02F1/283 ,  C02F1/288 ,  C02F1/488 ,  C02F2305/08 ,  H01F1/0063 ,  H01F1/28 ,  H01F41/0266 ,  Y10T428/2982

Abstract: The invention is in the field of modified carbon products. More in particular, the invention is in the field of graphitized activated carbon bodies. The invention is directed to carbon bodies and ferromagnetic carbon bodies, the production of these bodies from activated carbon, and the applications of the carbon bodies and ferromagnetic carbon bodies, for instance in water treatment and in electrochemical applications.

Abstract translation: 本发明是在改性碳产品领域。 更具体地，本发明在石墨化活性炭体领域。 本发明涉及碳体和铁磁性碳体，从活性炭生产这些体，以及碳体和铁磁性碳体的应用，例如在水处理和电化学应用中。

公开(公告)号：US20140364637A1

公开(公告)日：2014-12-11

申请号：US14350688

申请日：2012-10-12

Applicant: BASF Corporation

Inventor： Jim Aloysius Maria Brandts

IPC: C07C67/03

CPC classification number: C07C67/03 ,  C10L1/026 ,  C10L2200/0476 ,  C10L2290/00 ,  C11C3/003 ,  Y02E50/13 ,  C07C69/24 ,  C07C69/52

Abstract: The invention relates to a process for making esters, in particular biodiesel, using heterogeneous catalysts. The invention provides a process for making biodiesel, in particular FAME, which process is versatile and robust. The process of the invention can be carried out continuously, in particular in a fixed bed reactor or a slurry reactor and may be operated in a continuous fashion. In accordance with the invention, the transesterification reaction of triglycerides is carried out using a heterogeneous catalyst that comprises a Group 4 silicate and less than 3 wt. % Na in the presence of at least one acid compound.

Abstract translation: 本发明涉及使用多相催化剂制备酯，特别是生物柴油的方法。 本发明提供了一种制备生物柴油，特别是FAME的方法，该方法是通用且鲁棒的。 本发明的方法可以连续进行，特别是在固定床反应器或淤浆反应器中，并且可以以连续的方式操作。 根据本发明，甘油三酯的酯交换反应使用包含4族硅酸盐并且小于3重量％的多相催化剂进行。 ％Na在至少一种酸化合物的存在下。