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公开(公告)号：US3669825A
公开(公告)日：1972-06-13
申请号：US3669825D
申请日：1968-10-03
Applicant: SCM CORP
Inventor： HALL ROGER P
CPC classification number: B05D3/068 , B05D3/029 , B29C35/0805 , B29C35/0866 , B29C35/10 , B29C2035/0827 , B29C2035/0855 , B29C2035/0877 , B32B15/08 , C08F283/01 , Y10S428/913 , Y10T428/31536 , Y10T428/31681 , Y10T428/31699 , Y10T428/31801 , Y10T428/3192 , C08F2/46
Abstract: A PROCESS FOR BONDING BY RADIATION A SUBSTRATE, AND ESPECIALLY ONE HAVING A METALLIC SURFACE, WITH A SUBSTANTIALLY CATALYST-FREE SYSTEM CONTAINING A POLYMERIZABLE ORGANIC UNSATURATED RESIN SUSCEPTIBLE TO FREE-RADICAL CATALYSIS; AND THE RESULTING PRODUCT. IN ONE FORM, A FILM OF THE RESIN IS SUPERIMPOSED UPON THE SUBSTRATE WHILE A FACING SIDE OF EITHER THE RESINOUS FILM OR SUBSTRATE IS CONTACTED AT ANY TIME PRIOR TO SUCH RADIATION WITH AN ORGANIC SUBSTITUTED, RADIATION-RESPONSIVE ESTER OF A METAL ACID, SUCH AS TITANIC ACID OR ZIRCONIC ACID. THEREAFTER, THE FILM AND SUBSTRATE ARE SUBJECTED TO THE HIGH ENERGY RADIATION TO ADHERE ONE TO THE OTHER. IN ANOTHER FORM, NORMALLY AIRINHIBITED, THERMOSETTING RESINS ARE BONDED TO SUBSTRATES BY A TWO-STEP PROCESS, WHEREIN THE RESIN FILM IS FIRST PASSED THROUGH ONE TREATING ZONE EFFECTIVE TO IMPART MASS INTEGRITY AND THEREBY DEFINE A SHEET, AND THE SHEET TOGETHER WITH THE METAL ESTER AND THE SUBSTRATE IS THEN PASSED THROUGH ANOTHER TREATING ZONE EFFECTIVE SUBSTANTIALLY TO COMPLETE THE CURE OF THE RESIN AND SIMULTANEOUSLY ADHERE THE SHEET TO THE SUBSTRATE, AT LEAST ONE OF THE TREATING ZONES COMPRISING EXPOSURE TO HIGH ENERGY RADIATION.
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公开(公告)号：US3655481A
公开(公告)日：1972-04-11
申请号：US3655481D
申请日：1968-10-03
Applicant: SCM CORP
Inventor： HALL ROGER P
IPC: B05D3/02 , B05D3/06 , B29C35/08 , B29C35/10 , B29C63/00 , B29C63/48 , B32B15/08 , C08F283/01 , B29C27/04
CPC classification number: B32B15/09 , B05D3/029 , B05D3/068 , B29C35/0805 , B29C35/0866 , B29C35/10 , B29C63/00 , B29C63/48 , B29C2035/0827 , B29C2035/0855 , B29C2035/0877 , B32B15/08 , B32B2038/0076 , B32B2310/0806 , C08F283/01 , C08F2/46
Abstract: A process for coating by radiation a substrate, and especially one having a metallic surface, with a substantially catalyst-free system containing a polymerizable organic unsaturated resin susceptible to free-radical catalysis; and the resulting product. In one form, a film of the resin is superimposed upon the substrate while a facing side of either the resinous film or substrate is contacted at any time prior to such radiation with a selected chromium Werner complex. The Werner complex has a polar moiety attractive to the substrate and an organic unsaturated moiety which is sufficiently responsive to high energy radiation to react chemically with the resin. Thereafter, the film and substrate are subjected to the high energy radiation to adhere one to the other. The process is also adapted for coating articles with normally air-inhibited, thermosetting resins by a two-step process, wherein the resin film is first passed through one treating zone effective to impart mass integrity and thereby define a sheet, and the sheet together with the Werner complex and the substrate is then passed through another treating zone effective substantially to complete the cure of the resin and simultaneously adhere the sheet to the substrate, at least one of the treating zones comprising exposure to high energy radiation.
Abstract translation: 一种通过辐射基底，特别是具有金属表面的基体，用基本上不含催化剂的体系进行涂覆的方法，所述系统含有易受自由基催化影响的可聚合有机不饱和树脂; 和产生的产品。 在一种形式中，将树脂膜叠加在基材上，同时在用所选的铬维纳复合物进行这种辐射之前的任何时间使树脂膜或基材的面对侧接触。 维纳络合物具有对底物有吸引力的极性部分和有机不饱和部分，该有机不饱和部分对高能量辐射具有足够的响应，与树脂发生化学反应。 此后，对薄膜和基板进行高能量辐射以彼此粘合。
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公开(公告)号：US3669796A
公开(公告)日：1972-06-13
申请号：US3669796D
申请日：1968-10-03
Applicant: SCM CORP
Inventor： HALL ROGER P , PRATT IVOR , YOUNG RICHARD A
IPC: B29C63/48 , C08F283/01 , B29C27/04
CPC classification number: B29C63/48 , C08F283/01 , C08F230/08
Abstract: A PROCESS FOR COATING BY RADIATION A SUBSTRATE, AND ESPECIALLY ONE HAVING A METALLIC SURFACE, WITH A SUBSTANTIALLY CATALYST-FREE SYSTEM CONTAINING A POLYMERIZABLE ORGANIC UNSATURATED RESIN SUSCEPTIBLE TO FREE-RADICAL CATALYSIS; AND THE RESULTING PRODUCT. IN ONE FORM, A FILM OF THE RESIN IS SUPERIMPOSED UPON THE SUBSTRATE WHILE A FACING SIDE OF EITHER THE RESINOUS FILM OR SUBSTRATE IS CONTACTED AT ANY TIME PRIOR TO SUCH RADIATION WITH AN ORGANIC SUBSTITUTED, RADIATION-RESPONSIVE SILANE, OR DERIVATIVE THEREOF SUCH AS A SILOXANE OR POLYSILOXANE OF THE SILANE. THEREAFTER, THE FILM AND SUBSTRATE ARE SUBJECTED TO THE HIGH ENERGY RADIATION TO ADHERE TO THE OTHER. THE PROCESS IS ALSO ADAPTED FOR COATING ARTICLES WITH NORMALLY AIR-INHIBITED, THERMOSETTING RESINS BY A TWO-STEP PROCESS, WHEREIN THE RESIN FILM IS FIRST PASSED THROUGH ONE TREATING ZONE EFFECTIVE TO IMPART MASS INTEGRITY AND THEREBY DEFINE A SHEET, AND THE SHEET TOGETHER WITH THE SILANE AND THE SUBSTRATE IS THEN PASSED THROUGH ANOTHER TREATING ZONE EFFECTIVE SUBSTANTIALLY TO COMPLETE THE CURE OF THE RESIN AND SIMULTANEOUSLY ADHERE THE SHEET TO THE SUBSTRATE, AT LEAST ONE OF THE TREATING ZONES COMPRISING EXPOSURE TO HIGH ENERGY RADIATION.
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Patent Agency Ranking4.发明授权
公开(公告)号：US3666591A
公开(公告)日：1972-05-30
申请号：US3666591D
申请日：1968-10-03
Applicant: SCM CORP
Inventor： HALL ROGER P
CPC classification number: B29C66/45 , B29C63/48 , B29C65/14 , B29C65/1403 , B29C65/1406 , B29C65/1412 , B29C65/1425 , B29C65/1435 , B29C65/1483 , B29C66/1122 , B29C66/71 , B29C66/7392 , B29C66/7394 , B29C66/964 , B29K2067/06
Abstract: A PROCESS FOR COATING BY RADIATION A SUBSTRATE, AND ESPECIALLY ONE HAVING A METALLIC SURFACE, WITH A SUBSTANTIALLY CATALYST-FREE SYSTEM CONTAINING A POLYMERIZABLE ORGANIC UNSATURATED RESIN SUSCEPTIBLE TO FREE-RADICAL CATALYSIS; AND THE RESULTING PRODUCT. IN ONE FORM, A FILM OF THE RESIN IS SUPERIMPOSED UPON THE SUBSTRATE WHILE A FACING SIDE OF EITHER THE RESINOUS FILM OR SUBSTRATE IS CONTACTED AT ANY TIME PRIOR TO SUCH RADIATION WITH AN ACID POLYMER-FORMING MATERIAL HAVING A MINERAL ACID GROUP SELECTED FROM THE CLASS CONSISTING OF OXYGENATED SULFURCONTAINING AND OXYGENATED PHOSPHORUS-CONTAINING GROUPS WHICH ARE ATTRACTIVE TO THE SUBSTRATE, AND AN ORGANIC UNSATURATED MOIETY WHICH IS SUFFICIENTLY RESPONSIVE TO HIGH ENERGY RADIATION TO REACT CHEMICALLY WITH THE FILM OF THE COATING RESIN. THEREAFTER, THE FILM AND SUBSTRATE ARE SUBJECTED TO THE HIGH ENERGY RADIATION TO ADHERE ONE TO THE OTHER. THE PROCESS IS ALSO ADAPTED FOR COATING ARTICLES WITH NORMALLY AIR-INHIBITED, THERMOSETTING RESINS BY A TWO-STEP PROCESS, WHEREIN THE RESIN FILM IS FIRST PASSED THROUGH ONE TREATING ZONE EFFECTIVE TO IMPART MASS INTERGRITY AND THEREBY DEFINE A SHEET, AND THE SHEET TOGERTHER WITH THE ACID POLYMER-FORMING MATERIAL AND THE SUBSTRATE IS THEN PASSED THROUGH ANOTHER TREATING ZONE EFFECTIVE SUBSTANTIALLY TO COMPLETE THE CURE OF THE RESIN AND SIMULTANEOUSLY ADHERE THE SHEET TO THE SUBSTRATE, AT LEAST ONE OF THE TREATING ZONES COMPRISING EXPOSURE TO HIGH ENERGY RADIATION.
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公开(公告)号：US3658670A
公开(公告)日：1972-04-25
申请号：US3658670D
申请日：1969-02-11
Applicant: SCM CORP
Inventor： HOLICKY DONALD F , HALL ROGER P
CPC classification number: C08L67/06 , C08F283/01 , Y10S525/904 , C08L2666/12 , C08F2/46
Abstract: An improved process for curing an unsaturated air-inhibited thermosetting resin with a vinyl compound copolymerizable therewith suitably by means of radiation with a beam from electron emitting means wherein curling occurs by the addition of unsaturated molecules one to another is described. The improvement is for reducing inhibition of the resin to surface cure and comprises: substituting for at least a fraction of the unsaturated inhibited resin a copolymer comprising a linear saturated backbone having pendant therefrom through linkage selected from the group consisting of ester, ether, urethane, amine, and amide, a plurality of ethylenically unsaturated groups capable of the addition. The copolymer is characterized in having an average molecular weight of between about 5,000 and about 225,000.
Abstract translation: 描述了一种改进的用不饱和空气抑制热固性树脂固化的乙烯基化合物，其可以通过辐射与适当的共聚合的乙烯基化合物进行固化，所述辐射具有来自电子发射装置的束，其中通过不相容地分别加入发生卷曲。 改进之处在于减少树脂对表面固化的抑制，并且包括：用至少一部分不饱和抑制树脂代替含有直链饱和骨架的共聚物，该共聚物通过选自酯，醚，氨基甲酸酯， 胺和酰胺，能够加成的多个烯属不饱和基团。 共聚物的特征在于其平均分子量在约5,000和约225,000之间。
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公开(公告)号：US3899611A
公开(公告)日：1975-08-12
申请号：US40824473
申请日：1973-10-19
Applicant: SCM CORP
Inventor： HALL ROGER P
IPC: C08F290/06 , C08F299/06 , C09D4/06 , C08F8/00 , B05C5/00
CPC classification number: C09D4/06 , C08F290/06 , C08F299/06 , Y10T428/31652 , Y10T428/31862 , Y10T428/31942 , Y10T428/31957 , C08F283/00 , C08F220/36 , C08F290/14
Abstract: Methods are disclosed for rapidly curing compositions containing acrylyl terminated prepolymers and unsaturated diluents with melamine acrylate cross-linking agents by exposure to actinic radiation. The compositions also contain a polymerization initiator which is sensitive to the radiation employed.
Abstract translation: 公开了用于通过暴露于光化辐射快速固化含有丙烯酰端基预聚物和不饱和稀释剂与三聚氰胺丙烯酸酯交联剂的组合物的方法。 组合物还含有对所用辐射敏感的聚合引发剂。
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公开(公告)号：US3658620A
公开(公告)日：1972-04-25
申请号：US3658620D
申请日：1968-06-17
Applicant: SCM CORP
Inventor： HALL ROGER P
CPC classification number: B32B21/08 , B29C35/0805 , B29C35/0866 , B29C35/10 , B32B7/12 , B32B27/00 , B32B27/18 , B32B27/36 , B32B2038/0076 , B32B2260/028 , B32B2310/0806 , B32B2451/00 , Y10T428/31794
Abstract: A process for preparing a laminable sheet from a substantially catalyst-free system containing a polymerizable organic unsaturated resin susceptible to free-radical one comprising assembling a film or the like of the resin in contacting substantially coplanar relation with a membrane, and then exposing the resulting assembly while overlying a substrate to high energy radiation. This action cures a depthwise segment of the assembly contiguous to the substrate and provides a nontacky, mar-resistant undersurface to the film while leaving at least the upper exposed surface of the assembly in a relatively tacky, mar-susceptible condition. The latter surface thereby defines an interface of a resulting laminable sheet adapted for subsequent adherence to another lamina. Preferably, the process includes the ultimate step of lamination as well. In this embodiment, the described assembly is first passed through onm treating zone effective to impart mass integrity and thereby define a sheet, and is then passed in juxtaposition with a cooperating lamina through another treating zone effective substantially to complete the cure of the resin and simultaneously laminate the sheet to the cooperating lamina, one of the treating zones comprising exposure to high energy radiation.
Abstract translation: 一种从基本上不含催化剂的体系制备层压片材的方法，该系统含有易受自由基影响的可聚合有机不饱和树脂，其包括将膜的膜或类似物与膜基本上共面的关系相组合， 同时将基板覆盖到高能辐射。 这种作用固化了与基底相邻的组件的深度方面的部分，并向薄膜提供了一种非粘性的，抗磨损的下表面，同时至少使组件的上部暴露表面处于相对发粘的，易受感染的状况。 后者的表面由此限定了适于随后粘附到另一层的所得到的层压板的界面。
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公开(公告)号：US3644161A
公开(公告)日：1972-02-22
申请号：US3644161D
申请日：1967-11-13
Applicant: SCM CORP
Inventor： HALL ROGER P
CPC classification number: B32B37/00 , B05D3/029 , B05D3/068 , B29C35/10 , B29C63/00 , B29C2035/0827 , B29C2035/0855 , B29C2035/0877
Abstract: A process for curing a normally air-inhibited, thermosetting resinous reaction product comprising exposing a film or coat of the resin while overlying a substrate to high-energy radiation to cure at least a depthwise segment of the film that is contiguous to the substrate to provide a nontacky, mar-resistant undersurface to the film, then inverting the film on a substrate, and again exposing the inverted film to high energy radiation or to heat. Electron emission, microwaves, ultraviolet light, and the like may be used as the high-energy radiation. As a modification, the resin film or coat may be stretched prior to completing the second exposure. As a further modification, the resin film may be laminated to a substrate during the second exposure, preferably with an adhesive curable by exposure to such high energy radiation.
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