公开(公告)号：US20240002223A1

公开(公告)日：2024-01-04

申请号：US18250289

申请日：2021-11-24

Applicant: TOPSOE A/S

Inventor： Jens SEHESTED ,  Raul MONTESANO LOPEZ ,  Susanne Lægsgaard JØRGENSEN ,  Jeremy Neil BURN ,  Niels Christian SCHJØDT

IPC: C01B3/16 ,  B01J35/10 ,  B01J23/80

CPC classification number: C01B3/16 ,  B01J35/1047 ,  B01J23/80 ,  C01B2203/0283 ,  C01B2203/1076

Abstract: The invention comprises a method of operating a water gas shift reactor in a transient state such as during reactor start-up, the method comprising: providing a water gas shift catalyst comprising an alkali metal or alkali metal compound; heating the water gas shift catalyst up to the reaction temperature of the water gas shift reaction under steam condensing conditions, by applying steam as a heat transfer medium for the water gas shift catalyst, and where the water gas shift catalyst has a total pore volume larger than the volume of liquid water that forms during the heating.

公开(公告)号：US20230398522A1

公开(公告)日：2023-12-14

申请号：US18250277

申请日：2021-11-24

Applicant: TOPSOE A/S

Inventor： Poul Erik HØJLUND NIELSEN ,  Niels Christian SCHJØDT ,  Susanne Lægsgaard JØRGENSEN ,  Uffe Vie MENTZEL ,  Matthias Josef BEIER ,  Henrik Junge MORTENSEN

IPC: B01J23/80 ,  B01J21/02 ,  B01J37/08 ,  B01J35/10 ,  B01J35/00 ,  B01J6/00 ,  B01J37/03 ,  B01J21/00 ,  C07C29/145

CPC classification number: B01J23/80 ,  B01J21/02 ,  B01J37/08 ,  B01J35/1033 ,  B01J35/1004 ,  B01J35/006 ,  B01J6/001 ,  B01J37/03 ,  B01J35/0026 ,  B01J21/005 ,  C07C29/145

Abstract: Process for the catalytic hydrogenation of organic carbonyl compounds containing at least one functional group belonging to the group of aldehydes, ketones, esters and carboxylic acids, whereby said at least one functional group is converted to an alcohol by contacting said carbonyl compound with hydrogen and a hydrogenation catalyst at elevated temperature and pressure as well as a catalyst therefore and a process for producing said catalyst.

公开(公告)号：US20250084315A1

公开(公告)日：2025-03-13

申请号：US18727130

申请日：2022-12-22

Applicant: Topsoe A/S

Inventor： Niels Christian SCHJØDT ,  Pablo BEATO ,  Finn JOENSEN ,  Rasmus Yding BROGAARD ,  Linn Edda SOMMER

IPC: C10G3/00 ,  B01D3/06 ,  B01J23/72 ,  B01J23/755 ,  B01J29/40 ,  B01J29/70

Abstract: A process for producing a C3 olefin product stream and a hydrocarbon stream comprising hydrocarbons boiling in the jet fuel range, the process comprising: passing a feedstock stream comprising oxygenates over a catalyst active in the conversion of oxygenates for producing a first olefin stream; conducting the first olefin stream to a first separation step and withdrawing thereof a liquid hydrocarbon fraction comprising at least 50 wt % of the C3-olefins contained in the first olefin stream; conducting the liquid hydrocarbon fraction to a fractionation step and separating therefrom said C3 olefin product stream and the olefin product stream; and converting the olefin product stream into the hydrocarbon stream comprising hydrocarbons boiling in the jet fuel range, particularly sustainable aviation fuel (SAF), by subsequent oligomerization and hydrogenation. The invention provides also a plant for conducting the process.

公开(公告)号：US20240002224A1

公开(公告)日：2024-01-04

申请号：US18250322

申请日：2021-11-24

Applicant: TOPSOE A/S

Inventor： Jeremy Neil BURN ,  Raul MONTESANO LOPEZ ,  Jens SEHESTED ,  Susanne Lægsgaard JØRGENSEN ,  Niels Christian SCHJØDT

IPC: C01B3/16 ,  C01B3/48 ,  B01J23/00 ,  B01J23/80 ,  B01J21/04 ,  B01J35/10 ,  B01J35/00 ,  B01J35/02

CPC classification number: C01B3/16 ,  C01B3/48 ,  B01J23/005 ,  B01J23/80 ,  B01J21/04 ,  B01J35/1038 ,  B01J35/0026 ,  B01J35/026 ,  B01J35/0066 ,  C01B2203/0244 ,  C01B2203/025 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  C01B2203/0283

Abstract: The disclosure relates to a process for enriching a synthesis gas in hydrogen by contacting said synthesis gas with a water gas shift catalyst, the synthesis gas being a CO-rich synthesis gas including at least 15 vol % CO and at least 1 ppmv sulfur, and the water gas shift catalyst including Zn, Al, optionally Cu, and an alkali metal or alkali metal compound; the water gas shift catalyst is free of chromium (Cr) and iron (Fe), and has a pore volume, as determined by mercury intrusion, of 240 ml/kg or higher.

公开(公告)号：US20240001341A1

公开(公告)日：2024-01-04

申请号：US18250311

申请日：2021-11-24

Applicant: TOPSOE A/S

Inventor： Jens SEHESTED ,  Susanne Lægsgaard JØRGENSEN ,  Raul MONTESANO LOPEZ ,  Jeremy Neil BURN ,  Niels Christian SCHJØDT

IPC: B01J23/00 ,  B01J35/10 ,  B01J35/00 ,  C01B3/16 ,  B01J23/80

CPC classification number: B01J23/005 ,  B01J35/1033 ,  B01J35/0026 ,  C01B3/16 ,  B01J23/80 ,  C01B2203/0283 ,  C01B2203/1076

Abstract: The present disclosure relates to an improved water gas shift catalyst, in particular an improved high temperature shift catalyst and process using the catalyst. The water gas shift catalyst includes Zn, Al, optionally Cu, and an alkali metal or alkali metal compound, wherein the content of alkali metal, preferably K, is in the range 1-6 wt %, such as 1-5 wt % or 2.5-5 wt % based on the weight of oxidized catalyst, and wherein the water gas shift catalyst has a pore volume, as determined by mercury intrusion, of 240 ml/kg or higher, such as 250 ml/kg or higher. A process for enriching a synthesis gas in hydrogen by contacting the synthesis gas in a water gas shift reactor with the water gas shift catalyst.