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    4.
    发明专利
    未知

    公开(公告)号：DE19756115A1

    公开(公告)日：1999-06-24

    申请号：DE19756115

    申请日：1997-12-17

    Applicant: BASF AG

    Inventor： MUELLER BERND DR ,  SAUTER HUBERT DR ,  BAYER HERBERT DR ,  GEWEHR MARKUS DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  GYPSER ANDREAS DR ,  PTOCK ARNE DR ,  ROEHL FRANZ DR ,  GOETZ NORBERT DR ,  GOETZ ROLAND DR ,  HARRIES VOLKER DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

    IPC: A01N43/48 ,  C07C243/22 ,  C07D231/22 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  A01N43/56

    Abstract: The invention relates to substituted phenylpyrazolones of formula (I) in which the substituents have the following meanings: Y represents halogen, alkyl, halogen alkyl or alkoxyl; n represents 0, 1 or 2, whereby the radical Y can be different when n = 2; E represents a group A (A), whereby # characterizes the bond with the phenyl ring; R represents halogen, cyano, alkyl or halogen alkyl; R represents hydrogen or alkyl; R represents alkyl or halogen alkyl; T represents a direct bond, oxygen or CH2O; Z represents a) when T represents oxygen or oxymethylene, a group X, N=CWR or N=C(R )-C(R )=NOR , whereby X represents optionally substituted heterocyclyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted arylmethylene or optionally substituted heteroarylmethylene; W represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkenyl, optionally substituted heterocyclyl, optionally substituted aryl or optionally substituted heteroaryl; R represents hydrogen, cyano, alkyl, halognealkyl, alkoxyl, alkoxyl alkyl, cycloalkyl; R represents hydrogen, cyano, halogen, C(R )=NOR or W, OW, SW or NR W, whereby R represents hydrogen, alkyl, alkenyl or alkinyl; R represents hydrogen or alkyl; R represents hydrogen, optionally substituted alkyl, optionally substituted alkenyl or optionally substituted alkinyl, and b) when T represents a direct bond, Z represents a group W, CH2-CH2-W, CH=CH-W, CC-W, S-W, CH2-S-W, CH=N-O-CH2-W, CH2-O-C(=O)-W or CH2-O-C(CH3)=N-N=C(CH3)-W. The invention also relates to a method and intermediate products for the production of said phenylpyrazolones used for combating parasitic fungi and animal parasites.

    New phenyl carbamate derivatives
    7.
    发明专利
    New phenyl carbamate derivatives 未知

    公开(公告)号：DE19745650A1

    公开(公告)日：1999-04-22

    申请号：DE19745650

    申请日：1997-10-16

    Applicant: BASF AG

    Inventor： BAYER HERBERT DR ,  GEWEHR MARKUS DR ,  GROTE THOMAS DR ,  MUELLER BERND DR ,  SAUTER HUBERT DR ,  GRAMMENOS WASSILIOS DR ,  GYPSER ANDREAS DR ,  PTOCK ARNE DR ,  GOETZ ROLAND DR ,  RACK MICHAEL DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR ,  ROEHL FRANZ DR

    IPC: A01N43/82 ,  A01N43/836 ,  C07C259/14 ,  C07C265/12 ,  C07D271/06 ,  C07D271/07 ,  C07D413/12 ,  C07C251/40 ,  C07D413/04 ,  C07D413/14

    Abstract: Substituted oxy- or oxymethylenephenyl-oxazolidine and -oxazolidinedione derivatives (I) are new. They are prepared from new activated phenyl-oxazolidine derivatives (IIA) and activated phenyl-oxazolidinedione derivatives (IVB), which in turn are obtained via new substituted nitrobenzene and aniline derivatives (1), phenyl isocyanates (2) and substituted anilides (3). Substituted oxy- or oxymethylenephenyl-oxazolidine and -oxazolidinedione derivatives (I) are new: Y = halo; 1-4C alkyl; 1-4C haloalkyl; or 1-4C alkoxy; n = 0-2; E = group of formula (a) or (b): Ra = halo; CN; 1-4C alkyl or 1-4C alkoxy optionally substituted by halo; 3-6C alkenyloxy, 3-6C alkynyloxy; 3-6C cycloalkyl; S(O)m-1-4C alkyl; or NRaRb; m = 0-2; Ra and Rb = H; 1-4C alkyl; 3-6C alkenyl; or 3-6C alkynyl; Rb = 1-4C alkyl; 1-4C haloalkyl; 3-6C cycloalkyl; or optionally substituted arylmethylene; T = O or oxymethylene; Z' = X; N=CWR ; or N=C(R )-C(R )=NOR ; X = optionally substituted heterocyclyl, aryl, heteroaryl, arylmethylene or heteroarylmethylene; W = optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl or heteroaryl; R = H; CN; 1-4C alkyl; 1-4C haloalkyl; 1-4C alkoxy; 1-4C alkoxy-1-4C alkyl; or 3-6C cycloalkyl; R = H; CN; halo; C(Rd)=NOR3; W; OW; SW or NRcW; Rc = H; alk yl; alkenyl; or alkynyl; Rd = H or alkyl; R = H; or optionally substituted alkyl, alkenyl or alkynyl. Independent claims are also included for: (A) activated phenyl-oxazolidine derivatives of formula (IIA); (B) activated phenyl-oxazolidinedione derivatives of formula (IVB); (C) substituted nitrobenzene and aniline derivatives of formula (1); (D) phenyl isocyanates of formula (2); and (E) Substituted anilides (3). L = OH; CH3; CH2L'; or L'; L' = nucleophilic leaving group; La = CH3; CH2L'; NO2; alkylsulphonate; or arylsulphonate; Q = NH2 or NO2; T' = OZ'; CH2O-X; or CH2O-N=C(R )-C(R )=NOR ; Z' = N=CWR or N=C(R )-C(R )=NOR ; E asterisk = NH-C(O)-NH-OH; NH-C(O)-O-NH-C(O)-OR; NH-C(S)-R'; or NH-C(NOH)-R'; R = 1-4C alkyl; R' = 1-4C alkyl; 1-4C haloalkyl; or 3-6C cycloalkyl.

    9.
    发明专利
    未知

    公开(公告)号：AT248142T

    公开(公告)日：2003-09-15

    申请号：AT01115054

    申请日：2001-06-21

    Applicant: BASF AG

    Inventor： GYPSER ANDREAS DR ,  GROTE THOMAS DR ,  RHEINHEIMER JOACHIM DR ,  ROSE INGO DR ,  CULLMANN OLIVER DR ,  GEWEHR MARKUS DR ,  GRAMMENOS WASSILIOS DR ,  TORMO I BLASCO JORDI DR ,  MUELLER BERND DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  LORENZ GISELA DR ,  STIERL REINHARD DR

    IPC: C07C251/80 ,  A01N33/26 ,  A01N37/50 ,  C07C249/16 ,  C07C251/86

    Abstract: Hydrazonomethyl-salicylic acid (I) derivatives are new. The hydrazonomethyl-salicylic acid derivatives are compounds of formula (I). X = halo, NO2, CN, 1-4C alkyl, or 1-4C alkoxy; m = 0-3; A = OH, 1-4C alkoxy, NH2, NHCH3, or N(CH3)2; R = phenyl, naphthyl, 3-10C cycloalkyl, 5- or 6-membered heteroaryl or heterocyclyl containing 1-3 N and/or 1 O or S or 1 or 2 O and/or S (each optionally substituted with 1-3 Ra); Ra = CN, NO2, NH2, H2NCO-, H2NCS-, halo, OH, 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo), 1-6C alkylcarbonyl, 1-6C alkylsulfonyl, 1-6C alkylsulfoxyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 1-6C alkyl-NH-CO-, (1-6C alkyl)2N-CO-, 1-6C alkyl-NH-CS-, (1-6C alkyl)2N-CS-, 2-6C alkenyl, 2-6C alkenyloxy, phenyl, phenoxy, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, heteroaryl or heteroaryloxy, C(=NOR alpha )-OR beta , or OC(R alpha )2-C(R beta )=NOR beta , and cyclic groups are optionally substituted with 1-3 Rb; Rb = CN, NO2, NH2, H2NCO-, H2NCS-, halo, OH, 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo), 1-6C alkylcarbonyl, 1-6C alkylsulfonyl, 1-6C alkylsulfoxyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 1-6C alkyl-NH-CO-, (1-6C alkyl)2N-CO-, 1-6C alkyl-NH-CS-, (1-6C alkyl)2N-CS-, 2-6C alkenyl, 2-6C alkenyloxy, 3-6C cycloalkenyl, phenyl, phenoxy, phenylthio, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, heteroaryl or heteroaryloxy, or C(=NOR alpha )-OR beta ; R alpha and R beta = H or 1-6C alkyl; R = H, CN, or 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C haloalkyl, 1-6C alkoxy or 1-6C alkylthio (each optionally substituted with 1 or more halo and/or 1-3 Rc); Rc = halo, CN, NO2, OH; 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo); 1-6C alkylcarbonyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 2-6C alkenyl, 3-6C alkenyloxy, 3-6C alkynyloxy, or 1-4C alkylenedioxy (optionally halogenated). An Independent claim is also included for the preparation of compounds (I).

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