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公开(公告)号:AU3735201A
公开(公告)日:2001-08-07
申请号:AU3735201
申请日:2001-01-26
Applicant: BASF AG
Inventor: KEE GRAHAM EDMUND MC , GAUSEPOHL HERMANN , NIESSNER NORBERT
IPC: C08F285/00 , C08L51/04
Abstract: The invention relates to a process for preparing an impact-modified plastic based on grafted crosslinked rubber particles, and also to an impact-modified plastic obtainable by the process. To prepare the impact-modified plastic, (a) particles of a crosslinked rubber are produced from a first monomer mixture which has a content of
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公开(公告)号:AU2850501A
公开(公告)日:2001-08-07
申请号:AU2850501
申请日:2001-01-26
Applicant: BASF AG
Inventor: KEE GRAHAM EDMUND MC , GAUSEPOHL HERMANN , NIESSNER NORBERT
IPC: C08F279/02 , C08F279/04 , C08F285/00 , C08L51/04 , C08L55/02
Abstract: The invention relates to a process for preparing an impact-modified plastic based on grafted crosslinked rubber particles, and also to an impact-modified plastic obtainable by the process. To prepare the impact-modified plastic, (a) particles of a crosslinked rubber are produced from a first monomer mixture which has a content of at least 50% by weight, preferably at least 90% by weight, particularly preferably at least 98% by weight, of diene compounds. The particles of the crosslinked rubber are (b) grafted with a second monomer or monomer mixture, with formation of a graft shell. Particles of the grafted crosslinked rubber are (c) added to a third monomer mixture, and the monomers of the third monomer mixture (d) are polymerized, with formation of a matrix. The process of the invention is simple to carry out and gives impact-modified plastics with very good mechanical properties.
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公开(公告)号:AU4913200A
公开(公告)日:2000-11-02
申请号:AU4913200
申请日:2000-04-18
Applicant: BASF AG
Inventor: BRINKMANN-RENGEL SUZANNE , NIESSNER NORBERT , SUTORIS HEINZ FRIEDRICH , KEE GRAHAM EDMUND MC , KNOLL KONRAD , CHRISTIE DAVID
IPC: C08F293/00 , C08F297/04 , C08L53/02 , C09D153/02
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公开(公告)号:ZA9805868B
公开(公告)日:2000-01-10
申请号:ZA9805868
申请日:1998-07-03
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , KOCH JUERGEN , ITTEMANN PETER , SEIBRING JOACHIM , GRABOWSKI SVEN , KEE GRAHAM EDMUND MC , MOSBACH NORBERT , CZAUDERNA BERNHARD , NIEBNER NORBERT , HEINEN HARTMUT
CPC classification number: C08L25/12 , C08F279/04 , C08L25/14 , C08L51/04 , C08L2205/02 , C08L2666/02
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公开(公告)号:AU5285499A
公开(公告)日:2000-03-06
申请号:AU5285499
申请日:1999-07-20
Applicant: BASF AG
Inventor: KEE GRAHAM EDMUND MC , WUNSCH JOSEF , RAMSTEINER FALKO
IPC: C08J5/00 , C08F2/18 , C08F265/00 , C08L25/04 , C08L25/06 , C08L51/00 , C08L53/02 , D01F6/56 , B29C45/00 , D01F6/44 , C08J5/18
Abstract: Thermoplastic moulding materials containing (A) 30 - 99. 9 wt. % vinyl aromatic polymers with a syndiotactic structure, (B) 0.1 - 70 wt. % rubber elastic particle-shaped graft polymers with (C) 0 - 69.9 wt. % rubber elastic particle-shaped styrene/diene block copolymers, whereby the proportion of diene can be fully or partially hydrogenated and the particles of constituent (B) have a D (50) value ranging from 0.1-10 mu m and constituent (B) is different from constituent (C).
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公开(公告)号:ZA985868B
公开(公告)日:2000-01-10
申请号:ZA985868
申请日:1998-07-03
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , KOCH JUERGEN , ITTEMANN PETER , SEIBRING JOACHIM , GRABOWSKI SVEN , KEE GRAHAM EDMUND MC , MOSBACH NORBERT , CZAUDERNA BERNHARD , NIEBNER NORBERT , HEINEN HARTMUT
Abstract: A thermoplastic molding composition having little intrinsic color is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer, upon which is grafted a vinylaromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer. The thermoplastic polymer is a copolymer of a vinylaromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of intrinsic color coupled with good mechanical properties and can be processed by, for example, extrusion, injection molding, calendaring, blow molding, compression molding, or sintering.
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公开(公告)号:AU4013997A
公开(公告)日:1998-03-06
申请号:AU4013997
申请日:1997-08-05
Applicant: BASF AG
Inventor: KEE GRAHAM EDMUND MC , RENZ GUNTER , JAHNS EKKEHARD , KASTENHUBER WALTER
IPC: C08F2/22 , C08F2/24 , C08F2/44 , C08F20/00 , C08F265/00 , C08F291/00 , G03G9/08
Abstract: A particulate polymer P having an average particle diameter d50 of from 0.1 to 50 mum is prepared by a process in which an emulsion E is prepared fromone or more monomers M, which are polymerizable by free radical polymerization to give the polymer P,water, andat least one protective colloid PCby the action of high shear forces, and the emulsion E is subjected to polymerization in a reactor with the use of a free radical polymerization initiator RI wherein, based on the emulsion E, not more than 75% by weight of the emulsion E (initially taken portion of E) are initially taken in the reactor at the beginning of the polymerization and at least 25% by weight of the emulsion E (feed portion of E) are not fed to the reactor until after the beginning of the polymerization.
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公开(公告)号:AU2003245960A1
公开(公告)日:2004-01-06
申请号:AU2003245960
申请日:2003-06-18
Applicant: BASF AG
Inventor: KEE GRAHAM EDMUND MC , LUINSTRA GERRIT , QUEISSER JOACHIM , SCHMID MARKUS
IPC: C08F255/00 , C08F255/02 , C08F265/04 , C08F279/02 , C08F279/04 , C08F285/00 , C08F291/00 , C08F297/00 , C08J3/03 , C08J3/07 , C08L23/04 , C08L23/08 , C08L51/00 , C08L51/04 , C08L51/06 , C08L53/00 , C08L55/02 , C09D123/16 , C09D151/00 , C09J123/16 , C09J151/00
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公开(公告)号:AU5474801A
公开(公告)日:2001-10-15
申请号:AU5474801
申请日:2001-03-28
Applicant: BASF AG
Inventor: GEPRAGS MICHAEL , KEE GRAHAM EDMUND MC , KNOLL KONRAD
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公开(公告)号:BR9810666A
公开(公告)日:2000-09-26
申请号:BR9810666
申请日:1998-06-23
Applicant: BASF AG
Inventor: GUENTHERBERG NORBERT , KOCH JUERGEN , ITTEMAN PETER , SEIBRING JOACHIM , GRABOWSKI SVEN , KEE GRAHAM EDMUND MC , MOSBACH NORBERT , CZAUDERNA BERBHARD , NIESSNER NORBERT , HEINEN HARTMUT
Abstract: A thermoplastic molding composition having little intrinsic color is produced from a graft copolymer and a thermoplastic polymer. The graft copolymer is produced from a soft elastomeric particulate graft base obtained by polymerization of a conjugated diene alone or with a small amount of a monoethylenically unsaturated monomer, upon which is grafted a vinylaromatic monomer and acrylonitrile and optionally another monoethylenically unsaturated monomer. The thermoplastic polymer is a copolymer of a vinylaromatic monomer and acrylonitrile and optionally an additional monoethylenically unsaturated monomer. The thermoplastic molding composition has a low level of intrinsic color coupled with good mechanical properties and can be processed by, for example, extrusion, injection molding, calendaring, blow molding, compression molding, or sintering.
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