公开(公告)号：DE19755926A1

公开(公告)日：1999-06-24

申请号：DE19755926

申请日：1997-12-17

Applicant: BASF AG

Inventor： REINHARD ROBERT DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  HEISTRACHER ELISABETH DR ,  OTTEN MARTINA DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR

IPC: C07D239/54 ,  A01N43/54 ,  A01N43/647 ,  A01N43/707 ,  A01N43/74 ,  A01N43/76 ,  A01N43/78 ,  C07D403/04 ,  C07D413/04 ,  C07D417/04 ,  C07F9/6558

Abstract: The invention relates to 3-(benzazol-4-yl)pyrimidine-dione-derivatives of formula (I) and the salts thereof, whereby X = O, S; R = H, NH2, C1-C6-alkyl, C1-C6-alkyl halide; R = H, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl; R = H, halogen, C1-C6-alkyl; R = H, halogen; R = CN, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkoxyl, C1-C6-alkoxyl halide; =Y- = a group =N-N(R )-, =C(ZR )-N(R )-, =C(ZR )-O-, =C(ZR )-S-; R = C1-C6-alkyl, C1-C4-alkyl halide, C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkyl-SO2, C1-C6-alkyl-CO, C1-C6-alkyl halide-CO, C1-C6-alkyl-CS, C1-C6-alkoxyl-CO, C1-C6-alkoxyl-CS or optionally substituted C1-C6-alkyl; Z = chemical bond, O, S, -S(O)-, -SO2-, -NH-, -N(R )-; R , R = C1-C6-alkyl, C1-C6-alkyl halide, hydroxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4-alkoxyl-C1-C4-alkyl, C1-C4-alkoxyl halide-C1-C4-alkyl, C3-C4-alkenyloxyl-C1-C4-alkyl, C3-C4-alkynyloxyl-C1-C4-alkyl, C3-C8-cycloalkoxyl-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio halide-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkynylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfinyl halide-C1-C4-alkyl, C3-C4-alkenylsulfinyl-C1-C4-alkyl, C3-C4-alkynylsulfinyl-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-alkenyl halide, C3-C6-alkynyl, cyano-C3-C6-alkynyl, C3-C6-alkynyl halide, HO-CO-C1-C4-alkyl, (C1-C4-alkoxyl)CO-C1-C4-alkyl, (C1-C4-alkyl)CS-C1-C4-alkyl, H2N-CO-C1-C4-alkyl, C1-C4-alkyl-NHCO-C1-C4-alkyl, di(C1-C4-alkyl)NCO-C1-C4-alkyl, di(C1-C4-alkyl)phosphonyl-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-linked heterocyclyl or heterocyclyl-C1-C4-alkyl, whereby each heterocyclyl ring can contain a CO-ring link or CS-ring link, or provided that Z = chemical bond, R also H, OH, CN, SH, NH2, halogen, -CH(OH)-CH2-R , -CH(halogen)-CH2-R , -CH2-CH(halogen)-R , -CH=CH-R or -CH=C(halogen)-R , whereby R = COOH, (C1-C4-alkoxyl)carbonyl, (C1-C4-alkylthio)carbonyl, CONH2, C1-C4-alkyl-NHCO or di(C1-C4-alkyl)NCO, or R + R = an optionally substituted 1,3-propylene-, tetramethylene-, pentamethylene- or ethylene oxyethylene-chain.

公开(公告)号：DE19645313A1

公开(公告)日：1998-05-07

申请号：DE19645313

申请日：1996-11-04

Applicant: BASF AG

Inventor： ZAGAR CYRILL DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

IPC: A01N43/56 ,  A61K31/415 ,  A61K31/4152 ,  A61K31/4155 ,  A61K31/454 ,  A61K31/5377 ,  A61P3/10 ,  C07D231/20 ,  C07D401/10 ,  C07D401/12 ,  C07D403/10 ,  C07D403/12 ,  C07D405/12 ,  C07D231/14 ,  C07D231/16 ,  C07D231/18

Abstract: The invention relates to substituted 3-benzylpyrazoles of formula (I), their precursors of formulas (IIa), (IIb), (IIc), their byproducts of formula (III) as well as their salts, wherein R stands for H, C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkyl thio, C1-C4 halogen alkyl thio, C1-C4 alkyl sulfinyl, C1-C4 halogen alkyl sulfinyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for H, CN, NO2, halogen, C1-C4 alkyl, C1-C4 halogen alkyl; X -X stands for chemical bond, optionally substituted methylene-, ethylene-, ethene-1,2-diyl or oxymethylene or thiamethylene chain linked through the heteroatom to the phenyl ring; R -R stands for H, CN, NO2, halogen -O-Y -R , -O-CO-Y -R , -N(Y -R ) (Y -R ), -N(Y -R )-SO2-Y -R , -N(SO2-Y -R ) (SO2-Y -R ), -N(Y -R )-CO-Y -R , -N(Y -R ) (O-Y -R ), -S-Y -R , -SO-Y -R , -SO2-Y -R , -SO2-O-Y -R , -SO2-N(Y -R ) (Y -R ), -CO-Y -R , -C(=NOR )-Y -R , -C(=NOR )-O-Y -R , -C(=NOR )-CO-O-Y -R , -CO-O-Y -R , -CO-S-Y -R , -CO-N(Y -R ) (Y -R ), -CO-N(Y -R ) (O-Y -R ); R stands C1-C4 alkyl, C1-C4 halogen alkyl. The invention further relates to the use of (I) as herbicide, for the desiccation/defoliation of plants, and of (I), (IIa), (IIb), (IIc) and (III) for lowering the sugar content in blood.

公开(公告)号：DE19616719A1

公开(公告)日：1997-10-30

申请号：DE19616719

申请日：1996-04-26

Applicant: BASF AG

Inventor： MENKE OLAF DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  MENGES MARKUS DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

IPC: A01N43/54 ,  A01N47/12 ,  A01N47/30 ,  A01N53/00 ,  C07D239/46 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/06 ,  C07C275/40

Abstract: N- or O-(3-(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)benzyl)-hydroxylamine derivs. of formula (I) and salts of (I; R , R and/or R = H) are new. X = -N(R )-O-, with R bonded to O or N; Y = O or S ; R = halo, CN, NO2 or CF3; R = H or halo; R = H, NH2 or Me; R = H, halo, alkyl, haloalkyl, alkylthio, alkylsulphinyl or alkylsulphonyl; R = H, halo or alkyl; R = H, alkyl, haloalkyl, 3-6C cycloalkyl or 2-6C alkenyl; R = (i) H; (ii) alkyl, cycloalkyl, haloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl, alkoxycarbonyl, (2-6C)alkenyloxycarbonyl, (2-6C)alkynyloxycarbonyl, alkylthiocarbonyl, alkylsulphonyl or alkylcarbamoyl (all opt. substd. by 1-3 of NO2, CN, cycloalkyl, OH, alkoxy, cycloalkoxy, alkenyloxy, alkynyloxy, alkoxyalkoxy, alkylthio, alkylcarbonyl, alkylcarbonyloxy, alkylsulphinyl, alkylsulphonyl, 1-6C alkylideneaminoxy, alkylcarbamoyl, Ar, OAr, SO2Ar, Het, OHet, COZ R , OCOZ R and NR R ); or (iii) cycloa lkylcarbonyl, benzoyl, phenylsulphonyl or phenylcarbamoyl (all opt. substd. by 1-3 of halo, NO2, CN, alkyl, alkoxy and haloalkyl); R = H ; or alkyl, cycloalkyl, haloalkyl, alkenyl or alkynyl (all opt. substd. by 1-3 of NO2, CN, halo, cycloalkyl, OH, alkoxy, cycloalkoxy, alkenyloxy, alkynyloxy, alkoxyalkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, 1-6C alkylideneaminoxy, Ar, OAr, SO2Ar, Het, OHet, COZ R , OCOZ R and NR R ); Z = a bond, O, S or NR ; Z = a bond, O, S or NR ; Ar = phenyl (opt. substd. by 1-3 of halo, NO2, CN, alkyl, haloalkyl and alkoxy); Het = 3-7 membered satd., partially or completely unsatd. or aromatic heterocycle contg. 1-3 heteroatoms selected from 2 O, 2 S and 3 N (opt. substd. by 1-3 of halo, NO2, CN, alkyl, alkoxy, haloalkyl and alkylcarbonyl); R , R = H, alkyl, haloalkyl, cycloalkyl, alkenyl, alkynyl, alkoxyalkyl or alkoxycarbonylalkyl, or phenyl or phenylalkyl (both opt. ring-substd. by 1-3 of NO2, CN, halo, alkyl, haloalkyl, alkoxy or alkylcarbonyl); or Z + R and/or Z + R may complete an N-bonded heterocycle as defined for Het (except that the optional substituents do not include alkylcarbonyl); R , R = H, OH, alkyl, cycloalkyl or alkoxy; unless specified otherwise, alkyl moieties have 1-6C, alkenyl or alkynyl moieties 3-6C and cycloalkyl moieties 3-8C.

公开(公告)号：CZ20013469A3

公开(公告)日：2002-04-17

申请号：CZ20013469

申请日：2000-03-31

Applicant: BASF AG

Inventor： HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  REINHARD ROBERT DR ,  SAGASSER INGO DR ,  ZAGAZ CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  OTTEN MARTINA DR ,  WALTER HELMUT DR

IPC: C07D213/81 ,  A01N43/40 ,  A01N43/42 ,  A01N43/76 ,  A01N43/78 ,  C07C229/56 ,  C07C237/30 ,  C07C251/48 ,  C07C253/20 ,  C07C255/58 ,  C07D209/38 ,  C07D213/82 ,  C07D213/89 ,  C07D265/26 ,  C07D317/58 ,  C07D401/12 ,  C07D405/12 ,  C07D413/12 ,  C07D413/14 ,  C07D417/14

Abstract: The present invention relates to substituted aniline compounds of the formula 1in which R , R and R have the meanings indicated in the description. The compounds according to the invention are intermediates for the preparation of herbicidally active pyridinedicarboxamide compounds.

公开(公告)号：DE19610701A1

公开(公告)日：1997-09-25

申请号：DE19610701

申请日：1996-03-19

Applicant: BASF AG

Inventor： HEISTRACHER ELISABETH DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

IPC: A01N37/46 ,  C07D209/48 ,  A01N43/38 ,  C07C205/07 ,  C07C211/46

Abstract: Tetrahydrophthalimido-cinnamic acid derivatives of formula (I) and their salts are new. R1 = H or 1-6C alkyl; R2 = CN, halo, 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy or 1-6C haloalkoxy; R3 = NO2, CN or halo; R4 = OR5, SR5, NR6R7 or NR6OR7; R5 = H, 1-6C alkyl (optionally substituted by halo, cyano, 1-6C alkoxy, 1-6C alkylthio,(1-6C alkyl)carbonyl, (1-6C alkyl)aminocarbonyl, di(1-6C alkyl)aminocarbonyl or 1-6C alkyloxyimino), 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, di(1-6C alkoxy)-2-6C alkyl, di(1-6C alkylthio)-2-6C alkyl, 3-6C haloalkenyl, or phenyl or benzyl (both optionally ring-substituted by 1-3 of CN, NO2, halo, 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, 1-6C haloalkylthio and (1-6C alkyl)carbonyl); R6-R8 = (1-6C alkyl)carbonyl, (1-6C haloalkyl)carbonyl or as for R5; or R6+R7 = 4-6-membered hydrocarbon chain, optionally with a non-terminal CH2 replaced by O or 1-4C alkylimino. Also claimed are (1) the preparation of substituted anilines (amino-cinnamic acid derivatives) of formula (X) by reduction of the corresponding nitro compound of formula (XI); and (2) the preparation of the nitro compounds (XI) (a) from 4-chloro-5-nitro-2-R2-aniline by the Meerwein reaction, using an alkyne of formula H-C?=C-COR4 (III), or (b) from 4-chloro-5-nitro-2-R2-benzaldehyde by reaction with an ylide of formula (Ar)3P=CX-COR4 (V), or an acidic CH compound of formula CH2Y-COR4 (VI). X = F, Cl or Br; Y = NO2 or CN; Ar = optionally substituted aromatic residue.

公开(公告)号：CZ20004270A3

公开(公告)日：2001-06-13

申请号：CZ20004270

申请日：1999-05-19

Applicant: BASF AG

Inventor： SCHAFER PETER DR ,  RACK MICHAEL DR ,  GOETZ ROLAND DR ,  HAMPRECHT GERHARD DR ,  MENKE OLAF DR ,  MENGES MARKUS DR ,  REINHARD ROBERT DR ,  ZAGAR CYRILL DR ,  OTTEN MARTINA DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

IPC: A01N43/707 ,  A01N43/76 ,  A01N43/84 ,  C07C59/84 ,  C07C59/90 ,  C07C69/738 ,  C07D253/075 ,  C07D403/10 ,  C07D405/04 ,  C07D413/10 ,  C07D417/10

公开(公告)号：CZ9800026A3

公开(公告)日：1998-07-15

申请号：CZ2698

申请日：1996-06-27

Applicant: BASF AG

Inventor： KLINTZ RALF DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  SCHAFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISSLITZ ULF DR ,  MENKE OLAF DR ,  MENGES MARKUS DR

IPC: A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/32 ,  C07C275/40 ,  C07D239/54 ,  C07D405/12

CPC classification number: C07D239/54 ,  A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/40

公开(公告)号：CZ2698A3

公开(公告)日：1998-07-15

申请号：CZ2698

申请日：1996-06-27

Applicant: BASF AG

Inventor： KLINTZ RALF DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  SCHAFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISSLITZ ULF DR ,  MENKE OLAF DR ,  MENGES MARKUS DR

IPC: A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/32 ,  C07C275/40 ,  C07D239/54 ,  C07D405/12

Abstract: PCT No. PCT/EP96/02805 Sec. 371 Date Jan. 5, 1998 Sec. 102(e) Date Jan. 5, 1998 PCT Filed Jun. 27, 1996 PCT Pub. No. WO97/02253 PCT Pub. Date Jan. 23, 1997Benzylhydroxylamines I (X=-N(R7)-O-; Y=O, S; R1=halogen, CN, NO2, CF3; R2=H, halogen; R3=H, NH2, CH3; R4=H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl or C1-C6-alkylsulfonyl; R5=H, halogen, C1-C6-alkyl; R6=H, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C2-C6-alkenyl; R7=H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkylcarbonyl, C3-C6-alkenylcarbonyl, C3-C6-alkynylcarbonyl, C1-C6-alkoxycarbonyl, C2-C8-alkenyloxycarbonyl, C2-C6-alkynyloxycarbonyl, C1-C6-alkylthiocarbonyl, C1-C6-alkylsulfonyl, C1-C6-alkylcarbamoyl, it being possible for the 14 last-mentioned radicals to have attached to them 1-3 substituents: NO2, CN, halogen, C3-C8-cycloalkyl, OH, C1-C6-alkoxy, C3-C8-cycloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C1-C6-alkoxy-C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylcarbonyl, C1-C6-alkylcarbonyloxy, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-alkylideneaminoxy, C1-C6-alkylcarbamoyl, unsubstituted or substituted phenyl, phenoxy or phenylsulfonyl, a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents, -CO-Z1R9, -OCO-Z1R9, -N(R9)R10 or R7=unsubstituted or substituted cycloalkylcarbonyl, phenylcarbonyl, phenylsulfonyl, phenylcarbamoyl; R8=H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C6-alkenyl or C3-C6-alkynyl, it being possible for each of the 5 last-mentioned radicals to have attached to it 1-3 substituents: NO2, CN, halogen, C3-C8-cycloalkyl, OH, C1-C6-alkoxy, C3-C8-cycloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C1-C6-alkoxy-C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-alkylideneaminoxy, unsubstituted or substituted phenyl- [sic], phenoxy-[sic] or phenylsulfonyl, a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents, -CO-Z2R11, -OCO-Z2R11, -N(R11)R12; Z1 a chemical bond, oxygen, sulfur or -N(R10)-; Z2=a chemical bond, oxygen, sulfur or -N(R12)-; R9, R11=H, C1-C6-alkyl, C1-C6-haloalkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkoxy-C1-C6-alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, unsubstituted or sub

公开(公告)号：DE19633746A1

公开(公告)日：1998-02-26

申请号：DE19633746

申请日：1996-08-22

Applicant: BASF AG

Inventor： SCHAEFER PETER DR ,  RACK MICHAEL DR ,  HAMPRECHT GERHARD DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  MENGES MARKUS DR ,  ZAGAR CYRILL DR ,  MENKE OLAF DR

IPC: C07D213/70 ,  A01N43/40 ,  C07D213/71 ,  C07D213/89 ,  C07D405/10 ,  C07D405/12 ,  C07D409/10 ,  C07D411/10 ,  C07D401/10 ,  C07D407/10

Abstract: The present invention pertains to substituted 2-phenylpyridine I and the salts thereof of formula (I), where R = SH, SO2NH2, C1-C2-alkylthio, C1-C6-alkyl-sulfinyl, C1-C6-akylsulfonyl, C1-C6alkylaminosulfonyl, Di-(C1-C6alkyl)aminosulfonyl; R , R = H, halogen; R = CN, OH, halogen, C1-C6-alkoxy, possibly substituted OCH2-phenyl and R have the meanings given in the description. The invention also relates to: the use of compounds (I) as herbicides or as plant dessicating/defoliating agents, the herbicides and the plant dessicating/defoliating agents containing compounds (I) as actives substances, the processes for controlling undesirable plant growth and for dessicating/defoliating plants using compounds (I), the processes for producing compounds (I), herbicides and plant dessicating/defoliating agents by compounds (I), as well as the intermerdiate products of formulae (IIa, V and VI).

公开(公告)号：DE19738084A1

公开(公告)日：1999-03-04

申请号：DE19738084

申请日：1997-09-01

Applicant: BASF AG

Inventor： MENKE OLAF DR ,  GOETZ ROLAND DR ,  RACK MICHAEL DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  REINHARD ROBERT DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISLITZ ULF DR

IPC: A01N43/80 ,  C07D405/06 ,  C07D413/06 ,  C07D417/06 ,  C07F9/6584 ,  C07D239/54 ,  A01N43/54 ,  A01N43/84 ,  A01N57/02 ,  C07D403/06 ,  C07F9/6564 ,  C07F9/6571

Abstract: 3-Arylmethyluracil derivatives (I.1)-(I.4) are new, where A = H, 1-4C alkyl, NH2, 1-4C alkylamino or di-(1-4C alkyl)amino; X = O or S; n = not defined; R1 = 1-4C haloalkyl; R2 = H, halo or 1-3C alkyl; R3-R5 = H, CN, thiocyanato, halo, 1-4C haloalkyl, 1-4C haloalkoxy, 1-4C haloalkylthio, 1-4C alkyl or 1-4C alkoxy; R6, R7 = 1-4C alkyl, NH2, 1-4C alkylamino or di(1-4C alkyl)amino, or R6 and R7 together form =O; R8 may be in position alpha or beta and R3 is in the other position; R8 = (1) H, halo, amino, 1-4C alkylsulphonylamino or di(1-4C alkyl)amino; (2) 1-6C alkoxy, 1-6C alkylthio, 3-6C cycloalkoxy, 3-6C cycloalkylthio, 2-6C alkenyloxy, 5-7C cycloalkenyloxy, 2-6C alkenylthio, 2-6C alkynyloxy, 2-6C alkynylthio, (1-6C alkyl)carbonyloxy, (1-6C alkyl)carbonylthio, (1-6C alkoxy)carbonyloxy, (2-6C alkenyl)carbonyloxy, (2-6C alkenyl)carbonylthio, (2-6C alkynyl)carbonyloxy, (2-6C alkynyl)carbonylthio, 1-6C alkylsulphonyloxy or 1-6C alkylsulphonyl, where the last 18 groups may contain 1-4 substituents; (3) CT-R11, C(R11)(Y1R12)(Y2R13), C(R11)=C(R14)CN, C(R11)=C(R14)CO-R15, CH(R11)-CH(R14)CO-R15, C(R11)=C(R14)-CH2-CO-R15, C(R11)=C(R14)-C(R16)=C(R17)-CO-R15, C(R11)=C(R14)-CH2-CH(R18)CO-R15, CO-OR19, CO-SR19, CO-N(R19)-OR20, C?=C-CO-NH-OR20, C?=C-CO-N(R19)-OR20, , C?=C-CS-NH-OR20, C?=C-CS-N(R19)-OR20, C(R11)=C(R14)-CO-NH-OR20, C(R11)=C(R14)-CO-N(R19)-OR20, C(R11)=C(R14)-CS-NH-OR20, C(R11)=C(R14)-CS-N(R19)-OR20, C(R11)=C(R14)-C(R21)=N-OR20, C(R21)=N-OR20, C?=C-C(R21)=N-OR20, C(Y1R12)(Y2R13)-OR19, C(Y1R12)(Y2R13)-SR19, C(Y1R12)(Y2R13)-N(R23)(R24), N(R23)(R24), CO-N(R23)(R24), or groups of formula (i), (ii), -C?=C-(i), -C?=C-(ii), -C(R11)=C(R14)-(i) or -C(R11)=C(R14 )-(ii); Y1, Y2 = S or O; theta = 1-3C alkylene optionally substituted by 1-6C alkyl; R11 = H, CN, 1-6C alkyl, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 3-6C cycloalkyl, 1-6C alkoxy-(1-6C alkyl) or (1-6C alkoxy)carbonyl; R12, R13 = 1-6C alkyl, 1-6C haloalkyl, 3-6C alkenyl, 3-6C alkynyl or 1-6C alkoxy-(1-6C alkyl) or R12 and R13 together form a 2-4 membered carbon chain which is optionally substituted and can contain non-adjacent O, S or N atoms instead of C atoms or be condensed or form a spiro attachment with a 3-7 membered ring; R14 = H, CN, halo, 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy, (1-6C alkyl)carbonyl or (1-6C alkoxy)carbonyl; R15 = H, OR22, SR22, 1-6C alkyl (optionally substituted by one or two 1-6C alkoxy groups), 2-6C alkenyl, 2-6C alkynyl, 1-6C haloalkyl, 3-6C cycloalkyl, 1-6C alkylthio-(1-6C alkyl), 1-6C alkyliminooxy, N(R23)(R24) or optionally substituted phenyl; R22 has the same meanings as R19; R16 = H, CN, halo, 1-6C alkyl, 3-6C alkenyl, 3-6C alkynyl, 1-6C alkoxy-(1-6C alkyl), (1-6C alkyl)carbonyl, (1-6C alkoxy)carbonyl, N(R25)(R26) or optionally substituted phenyl; R25, R26 have the same meanings as R23 and R24; R17 = H, halo, CN, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl, (1-6C alkyl)carbonyl or (1-6C alkoxy)carbonyl; R18 = H, CN, 1-6C alkyl or (1-6C alkoxy)carbonyl; R19 = H, 1-6C alkyl, 1-6C haloalkyl, 2-6C alkenyl or 2-6C alkynyl (where the latter four groups are optionally substituted), (1-6C alkyl)carbonyl, (1-6C haloalkyl)carbonyl, (1-6C alkoxy)carbonyl, 1-6C alkylaminocarbonyl, di-(1-6C alkyl)aminocarbonyl, 1-6C alkoxyimino-(1-6C alkyl), 3-6C cycloalkyl, phenyl or phenyl-(1-6C alkyl), where the phenyl ring is optionally substituted; R20 = H, 1-6C alkyl, 1-6C haloalkyl, 3-6C cycloalkyl, 3-6C alkenyl, 3-6C alkynyl, hydroxy-(1-6C alkyl), 1-6C alkoxy-(1-6C alkyl), 1-6C alkylthio-(1-6C alkyl), cyano-(1-6C alkyl), (1-6C alkyl)carbonyl-(1-6C alkyl), (1-6C alkoxy)carbonyl-(1-6C alkyl), (1-6C alkoxy)carbonyl-(2-6C alkenyl), (1-6C alkyl)carbonyloxy-(1-6C alkyl) or phenyl-(1-6C alkyl), where the phenyl ring may contain 1-3 substituents; R