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公开(公告)号:DE3681001D1
公开(公告)日:1991-09-26
申请号:DE3681001
申请日:1986-12-19
Applicant: BASF AG
Inventor: BOTT KASPAR , HOFFMANN HERWIG , SCHEIDMEIR WALTER , TRAPP HORST
IPC: C07C29/34 , C07C33/20 , C07D213/30
Abstract: Alkanols of formula R1-CH(OH)-CH(R3)-R2 (I) are prepd. by reacting a sec. alcohol of formula R1-CH(OH)-CH2(R3) (II) with a prim. alcohol of formula R2OH, in presence of an alkali hydroxide at 150-300 deg.C; R1 = aromatic or heterocyclic gp.; R2 = 1-20C alkyl; R3 = H, Me or Et. Pref. reaction is at 200-300 deg.C, using KOH; R1 is pref. phenyl, opt. carrying 1-4C alkyl gp(s). The sec. alcohol may contain a pyridyl gp. as heterocyclic gp.
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公开(公告)号:AU607861B2
公开(公告)日:1991-03-14
申请号:AU3676389
申请日:1989-06-23
Applicant: BASF AG
Inventor: DENZINGER WALTER , BAUR RICHARD , HARTMANN HEINRICH , PERNER JOHANNES , TRIESELT WOLFGANG , TRAPP HORST , RAUBENHEIMER HANS-JUERGEN
Abstract: Oxyalkylated, carboxyl-containing polymers are prepared by reacting (A) a polymer which contains one or more monoethylenically unsaturated C3-C6-carboxylic acids as copolymerized units with (B) an alkylene oxide in an aqueous medium at not more than 120 DEG C. by a process in which the reaction is started at a pH of from 5.0 to 5.9 and is ended after a pH of from 5.5 to 8.5 has been reached. As a result of monitoring of the pH, the selectivity of the addition reaction of alkylene oxides with the polymers (A) is substantially improved compared with known processes.
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公开(公告)号:AU2671295A
公开(公告)日:1996-01-05
申请号:AU2671295
申请日:1995-05-27
Applicant: BASF AG
Inventor: OPPENLANDER KNUT , DRALLE-VOSS GABRIELE , SCHUHMACHER RUDOLF , TRAPP HORST
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公开(公告)号:AT127150T
公开(公告)日:1995-09-15
申请号:AT92904485
申请日:1992-02-11
Applicant: BASF AG
Inventor: STOECKIGT DIETER , BAUR RICHARD , TRAPP HORST , PERNER JOHANNES
Abstract: PCT No. PCT/EP92/00289 Sec. 371 Date Aug. 23, 1993 Sec. 102(e) Date Aug. 23, 1993 PCT Filed Feb. 11, 1992 PCT Pub. No. WO92/14808 PCT Pub. Date Sep. 3, 1992.A mixture suitable for use as a foam-suppressing surfactant additament in cleaning compositions for mechanized cleaning processes comprises at least two mixtures of alkoxylated alcohols I R-O-(C2H4O)x-(C3H6O)y-H (I) where x is an average degree of ethoxylation between 1 and 12, y is an average degree of propoxylation between 1 and 15, one alkoxylated alcohol mixture carries straight-chain or branched C8-C18-alkyl groups as the radical R and one other alkoxylated alcohol mixture carries straight-chain or branched C10-C20-alkyl groups as the radical R, subject to the proviso that the two radicals R differ by at least 0.5 in the average number of carbon atoms, and the two alkoxylated alcohol mixtures present in a ratio of from 10:90 to 90:10.
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公开(公告)号:ES2123151T3
公开(公告)日:1999-01-01
申请号:ES94924233
申请日:1994-07-05
Applicant: BASF AG
Inventor: WOLF GERHARD , BURKHART BERND , LAUTH GUENTER , TRAPP HORST , OFTRING ALFRED
IPC: B01J27/232 , C01F7/00 , C01F7/04 , C01F7/16 , C01B13/14 , C01F7/76 , C01G9/00 , C07B61/00 , C07C41/02 , C07C41/03 , C07C43/11
Abstract: PCT No. PCT/EP94/02195 Sec. 371 Date Jan. 29, 1996 Sec. 102(e) Date Jan. 29, 1996 PCT Filed Jul. 5, 1994 PCT Pub. No. WO95/04024 PCT Pub. Date Feb. 9, 1995Alkoxylation products are prepared by reacting compounds having active hydrogen atoms with C2-C4-alkylene oxides in the presence of a mixed hydroxide built up of polycations and modified with additives and having the general formula I or II[M(II)1-xM(III)x(OH)2]Ax/nxm L(I)[LiAl2(OH)6]A1/nxm L(II)where M(II) is at least one divalent metal ion, M(III) is at least one trivalent metal ion, A is at least one inorganic anion and L is an organic solvent or water, n is the valence of the inorganic anion A or in the case of a plurality of anions A is their mean valence and x can assume a value of from 0.1 to 0.5 and m can assume a value of from 0 to 10, as alkoxylation catalyst, wherein the mixed hydroxide contains additives.
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公开(公告)号:DE59203477D1
公开(公告)日:1995-10-05
申请号:DE59203477
申请日:1992-02-11
Applicant: BASF AG
Inventor: STOECKIGT DIETER , BAUR RICHARD , TRAPP HORST , PERNER JOHANNES
Abstract: PCT No. PCT/EP92/00289 Sec. 371 Date Aug. 23, 1993 Sec. 102(e) Date Aug. 23, 1993 PCT Filed Feb. 11, 1992 PCT Pub. No. WO92/14808 PCT Pub. Date Sep. 3, 1992.A mixture suitable for use as a foam-suppressing surfactant additament in cleaning compositions for mechanized cleaning processes comprises at least two mixtures of alkoxylated alcohols I R-O-(C2H4O)x-(C3H6O)y-H (I) where x is an average degree of ethoxylation between 1 and 12, y is an average degree of propoxylation between 1 and 15, one alkoxylated alcohol mixture carries straight-chain or branched C8-C18-alkyl groups as the radical R and one other alkoxylated alcohol mixture carries straight-chain or branched C10-C20-alkyl groups as the radical R, subject to the proviso that the two radicals R differ by at least 0.5 in the average number of carbon atoms, and the two alkoxylated alcohol mixtures present in a ratio of from 10:90 to 90:10.
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公开(公告)号:DE3546016A1
公开(公告)日:1987-06-25
申请号:DE3546016
申请日:1985-12-24
Applicant: BASF AG
Inventor: BOTT KASPAR , HOFFMANN HERWIG , SCHEIDMEIR WALTER , TRAPP HORST
IPC: C07C29/34 , C07C33/20 , C07D213/30 , C07C29/32
Abstract: Alkanols of the formula in which R denotes an aromatic or heterocyclic radical, R denotes a linear or branched alkyl radical and R denotes a hydrogen atom, the methyl radical or the ethyl radical are prepared by reacting a secondary alcohol of the formula with a primary alcohol of the formula R OH(III) in the presence of an alkali metal hydroxide at temperatures of 150 to 300 DEG C.
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8.
公开(公告)号:CA1141251A
公开(公告)日:1983-02-15
申请号:CA350742
申请日:1980-04-25
Applicant: BASF AG
Inventor: STOECKIGT DIETER , KIESSLING DIETER , PERNER JOHANNES , TRIESELT WOLFGANG , TRAPP HORST
Abstract: O.Z. 0050/033852 A detergent and cleanser which contains an oxyalkylated alcohol of the formula where R is C8-C18-alkyl, x is from 2 to 4.5 and y is from 2 to 5, as a low-foam, biodegradable surfactant additive.
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公开(公告)号:DE59407185D1
公开(公告)日:1998-12-03
申请号:DE59407185
申请日:1994-07-05
Applicant: BASF AG
Inventor: WOLF GERHARD , BURKHART BERND , LAUTH GUENTER , TRAPP HORST , OFTRING ALFRED
IPC: C01B13/14 , B01J27/232 , C01F7/00 , C01F7/04 , C01F7/16 , C01F7/76 , C01G9/00 , C07B61/00 , C07C41/02 , C07C41/03 , C07C43/11
Abstract: PCT No. PCT/EP94/02195 Sec. 371 Date Jan. 29, 1996 Sec. 102(e) Date Jan. 29, 1996 PCT Filed Jul. 5, 1994 PCT Pub. No. WO95/04024 PCT Pub. Date Feb. 9, 1995Alkoxylation products are prepared by reacting compounds having active hydrogen atoms with C2-C4-alkylene oxides in the presence of a mixed hydroxide built up of polycations and modified with additives and having the general formula I or II[M(II)1-xM(III)x(OH)2]Ax/nxm L(I)[LiAl2(OH)6]A1/nxm L(II)where M(II) is at least one divalent metal ion, M(III) is at least one trivalent metal ion, A is at least one inorganic anion and L is an organic solvent or water, n is the valence of the inorganic anion A or in the case of a plurality of anions A is their mean valence and x can assume a value of from 0.1 to 0.5 and m can assume a value of from 0 to 10, as alkoxylation catalyst, wherein the mixed hydroxide contains additives.
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公开(公告)号:CA1330611C
公开(公告)日:1994-07-05
申请号:CA602774
申请日:1989-06-14
Applicant: BASF AG
Inventor: DENZINGER WALTER , HARTMANN HEINRICH , BAUR RICHARD , PERNER JOHANNES , TRIESELT WOLFGANG , TRAPP HORST , RAUBENHEIMER HANS-JUERGEN
Abstract: Oxyalkylated, carboxylcontaining polymers are prepared by reacting (A) a polymer which contains one or more monoethyleni cally unsaturated C3-C8-carboxylic acids as copolymerized units with (B) an alkylene oxide in an aqueous medium at not more than 120.degree.C by a process in which the reaction is started at a pH of from 5.0 to 5.9 and is ended after a pH of from 5.5 to 8.5 has been reached. As a result of monitoring of the pH, the selectivity of the addition reaction of alkylene oxides with the polymers (A) is substantially improved compared with known processes.
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