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    CATALIZADOR Y PROCEDIMIENTO PARA EL HIDROGENADO DE COMPUESTOS CARBONICOS.
    2.
    发明专利
    CATALIZADOR Y PROCEDIMIENTO PARA EL HIDROGENADO DE COMPUESTOS CARBONICOS. 未知

    公开(公告)号：ES2231253T3

    公开(公告)日：2005-05-16

    申请号：ES00960507

    申请日：2000-08-22

    Applicant: BASF AG

    Inventor： HUBER SYLVIA ,  SPRAGUE MICHAEL JOLYON ,  BREITSCHEIDEL BORIS ,  WULFF-DORING JOACHIM ,  HESSE MICHAEL ,  PINKOS ROLF

    IPC: B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C31/04 ,  C07C31/20

    Abstract: Procedimiento para el hidrogenado de un compuesto orgánico que presenta al menos un grupo carbonilo, en el que se pone en contacto el compuesto orgánico, en presencia de hidrógeno, con un cuerpo moldeado que es obtenible según un procedimiento en el que (i) se pone a disposición un material oxídico desecado y calcinado, que presenta material soporte y componente activo, que comprende óxido de cobre, óxido de cinc y óxido de aluminio, (ii) se añade al material oxídico polvo metálico pulverulento o cemento pulverulento, o una mezcla de los mismos, empleándose polvo de cobre y polvo de cemento con una distribución de tamaños de grano en la que al menos un 45 % de partículas de cobre o cemento poseen tamaños de grano en el intervalo de 10 a 100 m, y (iii) se moldea la mezcla resultante de (ii) para dar un cuerpo moldeado.

    5.
    发明专利
    未知

    公开(公告)号：ES2180183T3

    公开(公告)日：2003-02-01

    申请号：ES98929301

    申请日：1998-05-12

    Applicant: BASF AG

    Inventor： FISCHER ROLF ,  PINKOS ROLF ,  WULFF-DORING JOACHIM

    IPC: C07C29/149 ,  C07B61/00 ,  C07C29/19 ,  C07C31/135 ,  C07C31/27

    Abstract: In a process for preparing alcohols containing cycloaliphatic groups by hydrogenation of carboxylic acids containing aromatic nuclei, or anhydrides or esters thereof, in the presence of a catalyst, the hydrogenation is carried out in one stage, and the catalyst contains at least one element from groups 8 to 10 and at least one element from group 7 of the Periodic Table of the Elements, in the form of the metal or an oxide in each case.

    6.
    发明专利
    未知

    公开(公告)号：ES2128799T3

    公开(公告)日：1999-05-16

    申请号：ES95942679

    申请日：1995-12-16

    Applicant: BASF AG

    Inventor： VICARI MAXIMILIAN ,  FLICK KLEMENS ,  MELDER JOHANN-PETER ,  SCHNURR WERNER ,  WULFF-DORING JOACHIM

    IPC: B01J25/00 ,  B01J25/02 ,  B01J37/00 ,  C07B31/00 ,  C07C253/30

    Abstract: A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.

    7.
    发明专利
    未知

    公开(公告)号：ES2126901T3

    公开(公告)日：1999-04-01

    申请号：ES95921795

    申请日：1995-05-31

    Applicant: BASF AG

    Inventor： SCHNURR WERNER ,  FISCHER ROLF ,  WULFF-DORING JOACHIM ,  IRGANG MATTHIAS ,  NEUHAUSER HORST

    IPC: C07D307/12 ,  B01J23/34 ,  C07D309/04 ,  C07D309/06

    Abstract: PCT No. PCT/EP95/02071 Sec. 371 Date Feb. 20, 1997 Sec. 102(e) Date Feb. 20, 1997 PCT Filed May 31, 1995 PCT Pub. No. WO95/33741 PCT Pub. Date Dec. 14, 1995Preparation of heterocyclic aldehydes I (I) (A, B=optionally substituted methylene groups; +E,uns m+EE , +E,uns n+EE =1 to 5; +E,uns m+EE ++E,uns n+EE >2), by hydrogenation of carboxylic acids IIa (IIa) or one of their esters IIb derived from a C1-C10 alcohol, at a temperature of from 200 DEG to 450 DEG C. over a catalyst. The end products are suitable as intermediates for herbicides of the cyclohexanone class.

    PROCESS FOR PREPARING 1,4-BUTANEDIOL BY CATALYTIC HYDROGENATION OF 1,4-BUTINEDIOL
    10.
    发明专利
    PROCESS FOR PREPARING 1,4-BUTANEDIOL BY CATALYTIC HYDROGENATION OF 1,4-BUTINEDIOL 未知

    公开(公告)号：CA2260810C

    公开(公告)日：2005-05-10

    申请号：CA2260810

    申请日：1997-09-23

    Applicant: BASF AG

    Inventor： KAIBEL GERD ,  PINKOS ROLF ,  WULFF-DORING JOACHIM ,  BROCKER FRANZ JOSEF ,  BECKER RAINER

    IPC: B01J25/02 ,  B01J8/02 ,  B01J8/06 ,  B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  B01J19/26 ,  C07B61/00 ,  C07C29/17 ,  C07C31/20

    Abstract: The invention concerns a process for preparing 1,4-butanediol by continuous catalytic hydrogenation of 1,4-butinediol in that 1,4-butinediol is reacted with hydrogen in the liquid continuous phase in th e presence of a heterogeneous hydrogenation catalyst at temperatures of between 20 and 300 .degree.C, a pressure of between 1 and 20 0 bar and values of the liquid-side mass transfer coefficients k L a, relative to the volume, of between 0.1 s-1 and 1s-1, a) with a catalyst suspended in the reaction medium, wherein, when a packed bubble column is used, it is operated in the upwards mode and at a ratio of the amount of gas leaving the reaction vessel to the amount fed thereto of between 0.99:1 and 0.4:1, or b) is guided upwards in parallel flow throug h a fixed bed reactor operated in the circulating gas mode, the ratio between the amount of gas fed to the reaction vessel and the amount of gas leaving the latter being maintained between 0.99:1 and 0.4:1.

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