公开(公告)号：NO318052B1

公开(公告)日：2005-01-24

申请号：NO20012470

申请日：2001-05-18

Applicant: BASF AG

Inventor： GOTZ NORBERT ,  RACK MICHAEL ,  GOTZ ROLAND ,  MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  HENKELMANN JOCHEM ,  BECKER HEIKE ,  BAYETO JUAN JOSE AISCAR

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：DE59910761D1

公开(公告)日：2004-11-11

申请号：DE59910761

申请日：1999-07-20

Applicant: BASF AG

Inventor： BOETTCHER ARND ,  BRUNNER MELANIE ,  HENKELMANN JOCHEM ,  RUETTER HEINZ ,  BREITSCHEIDEL BORIS

IPC: C07D295/00 ,  C07B35/02 ,  C07B61/00 ,  C07D209/08 ,  C07D209/44 ,  C07D211/60 ,  C07D211/62 ,  C07D215/04 ,  C07D217/02 ,  C07D219/02 ,  C07D295/02 ,  C07D307/06 ,  C07D307/08

Abstract: A process for hydrogenating an unsaturated heterocyclic compound or a mixture of two or more thereof by contacting the unsaturated heterocyclic compounder the mixture of two or more thereof with a hydrogen-containing gas in the presence of a catalyst comprising as active metal at least one metal from transition group VIII of the Periodic Table, applied to a support, wherein the support has macropores.

公开(公告)号：AT278649T

公开(公告)日：2004-10-15

申请号：AT99934714

申请日：1999-07-20

Applicant: BASF AG

Inventor： BOETTCHER ARND ,  BRUNNER MELANIE ,  HENKELMANN JOCHEM ,  RUETTER HEINZ ,  BREITSCHEIDEL BORIS

IPC: C07D295/00 ,  C07B35/02 ,  C07B61/00 ,  C07D209/08 ,  C07D209/44 ,  C07D211/60 ,  C07D211/62 ,  C07D215/04 ,  C07D217/02 ,  C07D219/02 ,  C07D295/02 ,  C07D307/06 ,  C07D307/08

Abstract: A process for hydrogenating an unsaturated heterocyclic compound or a mixture of two or more thereof by contacting the unsaturated heterocyclic compounder the mixture of two or more thereof with a hydrogen-containing gas in the presence of a catalyst comprising as active metal at least one metal from transition group VIII of the Periodic Table, applied to a support, wherein the support has macropores.

公开(公告)号：DE50007400D1

公开(公告)日：2004-09-16

申请号：DE50007400

申请日：2000-08-31

Applicant: BASF AG

Inventor： BUSCH RALPH ,  KNEUPER HEINZ-JOSEF ,  WEBER THEODOR ,  MUELLER WINFRIED ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07B61/00 ,  C07C51/60 ,  C07C51/64 ,  C07C53/42 ,  C07C57/66

Abstract: The invention relates to a method for producing acid chlorides by converting carboxylic acids with carbon oxychlorides or thionyl chloride in the presence of a catalyst adduct of an N,N-disubstituted formamide of general formula (I) and carbon oxychloride or thionyl chloride. In the formula, R and R , independently from one another, mean C1- to C4-alkyl or R and R together mean a C4- or C5-alkylene chain. According to the inventive method, hydrogen chloride is added during and/or after the conversion.

公开(公告)号：UA67815C2

公开(公告)日：2004-07-15

申请号：UA01064275

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  RACK MICHAEL ,  GOTZ NORBERT ,  GOETZ ROLAND ,  HENKELMANN JOCHEM

IPC: C07D231/20

Abstract: Винахідвідноситьсядоспособуодержання 1-заміщених 5- та/або 3-гідроксипіразолівформулІ і II, відповідноде R1 означаєС1-С6алкіл, С2-С6алкеніл, С2-С6алкініл, С3-С6циклоалкілабоС1-С4алкокси, причомуцігрупиможутьбутизаміщенігалогеном, С1-С4алкокси, фенокси, С1-С6алкоксикарбонілом, С1-С6алкілтіокарбоніломабоциклічноюсистемоюз 3-14 циклічнимиатомами, причомускладнийалкіловийефір 3-алкоксіакриловоїкислотиформули III, де R2, R3 незалежноодневідодногоозначаютьС1-С6алкілабоС3-С6циклоалкіл, піддаютьвзаємодіїз гідразиномформули IV де R1 приймаєвищенаведенізначення, а) зодержаннямпризначеннірН, рівному 6-11, 5-гідроксипіразолівформулиІ, абоб) зодержаннямпризначеннірН, щодорівнює 11-14, 3-гідроксипіразолівформулиІІ.

公开(公告)号：AU2003288219A1

公开(公告)日：2004-06-30

申请号：AU2003288219

申请日：2003-12-03

Applicant: BASF AG

Inventor： ARNDT JAN-DIRK ,  KLASS KATRIN ,  LAAR FREDERIK VAN ,  HERWIG STEPHAN ,  HENKELMANN JOCHEM

IPC: B01J21/08 ,  B01J23/46 ,  B01J33/00 ,  B01J37/18 ,  C07C29/141 ,  C07C31/26 ,  C07C31/18

Abstract: A continuous process for preparing sugar alcohols by catalytic hydrogenation of an aqueous solution of a saccharide, which forms the corresponding sugar alcohol on hydrogenation, in the presence of a ruthenium catalyst which is obtainable by: i) single or multiple treatment of an amorphous silicon-dioxide-based support material with a halogen-free aqueous solution of a low-molecular-weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reducing the solid obtained in i) with hydrogen at from 100 to 350° C., step ii) being carried out immediately after step i), which comprises, before the hydrogenation, bringing the aqueous saccharide solution to be hydrogenated into contact with the support material.

公开(公告)号：ES2209544T3

公开(公告)日：2004-06-16

申请号：ES99964476

申请日：1999-06-14

Applicant: BASF AG

Inventor： STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07D233/56 ,  C07D233/60 ,  C07D233/95 ,  C07D521/00

Abstract: In a process for preparing carbonyldiimidazole from imidazole and phosgene in an inert solvent, the imidazole hydrochloride which results as coupled product is removed as melt from the resulting reaction mixture by phase separation.

公开(公告)号：ES2207988T3

公开(公告)日：2004-06-01

申请号：ES99972625

申请日：1999-11-06

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  STEINMETZ ADRIAN ,  RACK MICHAEL ,  GOTZ NORBERT ,  GOTZ ROLAND ,  HENKELMANN JOCHEM

IPC: C07D231/20

Abstract: The invention relates to a process for preparing 1-substituted 5- and/or 3-hydroxypyrazoles of the formulae I and IIin which R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy, where these groups may be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms, which comprises reactingan alkyl 3-alkoxyacrylate of the formula IIIin which R2, R3 independently of one another are C1-C6-alkyl or C3-C6-cycloalkyl with a hydrazine of the formula IVin which R1 is as defined abovea) at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I orb) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II.

公开(公告)号：DE50006006D1

公开(公告)日：2004-05-13

申请号：DE50006006

申请日：2000-08-23

Applicant: BASF AG

Inventor： STAMM ARMIN ,  KNEUPER HEINZ-JOSEF ,  THIL LUCIEN ,  HENKELMANN JOCHEM

IPC: C07C263/10 ,  C07C265/08 ,  C07C265/10 ,  C07C265/12

Abstract: The present invention relates to a process for the preparation of aliphatic, cycloaliphatic, araliphatic and aromatic mono- and oligoisocyanates by phosgenation of the corresponding primary amines at atmospheric pressure, which comprisesa) introducing a catalytic amount of a monoisocyanate (isocyanate a) into an inert solvent together with phosgene;b) adding the primary amine, andc) reacting the resulting reaction mixture with phosgene.

公开(公告)号：AT263752T

公开(公告)日：2004-04-15

申请号：AT00951530

申请日：2000-08-23

Applicant: BASF AG

Inventor： STAMM ARMIN ,  KNEUPER HEINZ-JOSEF ,  THIL LUCIEN ,  HENKELMANN JOCHEM

IPC: C07C263/10 ,  C07C265/08 ,  C07C265/10 ,  C07C265/12

Abstract: The present invention relates to a process for the preparation of aliphatic, cycloaliphatic, araliphatic and aromatic mono- and oligoisocyanates by phosgenation of the corresponding primary amines at atmospheric pressure, which comprisesa) introducing a catalytic amount of a monoisocyanate (isocyanate a) into an inert solvent together with phosgene;b) adding the primary amine, andc) reacting the resulting reaction mixture with phosgene.