公开(公告)号：CZ9602113A3

公开(公告)日：1997-02-12

申请号：CZ211396

申请日：1996-07-17

Applicant: BASF AG

Inventor： ELLER KARSTEN DR ,  MULLER ULRICH DR ,  KUMMER RUDOLF DR ,  STOPS PETER

IPC: B01J29/70 ,  B01J29/74 ,  B01J29/76 ,  B01J29/78 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/17 ,  C07C211/21 ,  C07C211/23 ,  C07C211/27 ,  C07C211/35 ,  C07C211/45 ,  B01J29/06

CPC classification number: C07C209/60 ,  Y02P20/582

公开(公告)号：ES2058181T3

公开(公告)日：1994-11-01

申请号：ES88109085

申请日：1988-06-08

Applicant: BASF AG

Inventor： BERTLEFF WERNER DR ,  FISCHER ROLF DR ,  KUMMER RUDOLF DR ,  MERGER FRANZ DR ,  SCHNEIDER HEINZ-WALTER DR

IPC: C07B61/00 ,  C07C67/313 ,  C07C67/333 ,  C07C67/38 ,  C07C69/533 ,  C07C69/66 ,  C07C69/67 ,  C07C69/716

Abstract: The preparation of 5-formylvaleric esters comprises the following steps… a) hydroformylation of pentenoic esters by reaction with carbon monoxide and hydrogen at elevated temperature and pressure in the presence of carbonyl complexes of metals from Group VIII of the Periodic Table with the formation of a mixture of 5-, 4- and 3-formylvaleric esters… b) separation of 5-formylvaleric esters from the mixture thus obtained of 5-, 4- and 3-formylvaleric esters, leaving a mixture substantially comprising 4- and 3-formylvaleric esters behind… c) cleavage of the mixture substantially comprising 4- and 3-formylvaleric esters to give pentenoic esters at a temperature of 50 to 400 DEG C in the presence of catalysts and… d) recycling of the pentenoic esters into step a.

公开(公告)号：DE59006008D1

公开(公告)日：1994-07-14

申请号：DE59006008

申请日：1990-08-03

Applicant: BASF AG

Inventor： JOERG KLAUS DR ,  KUMMER RUDOLF DR ,  MUELLER FRANZ-JOSEF DR

IPC: B01J27/122 ,  B01J31/02 ,  C07B61/00 ,  C07C68/00 ,  C07C69/96

Abstract: Process for the preparation of dialkyl carbonates of the general formula I in which R represents a C1- to C10-alkyl group, by reacting the alcohols R OH with a gaseous carbon monoxide/oxygen mixture in the presence of a copper catalyst and of a cosolvent, at increased temperature and under increased pressure, in which the cosolvent used is a cyclic urea of the general formula II in which n is the number 2, 3 or 4 and R represents hydrogen or a C1- to C4-alkyl group.

公开(公告)号：DE3778866D1

公开(公告)日：1992-06-11

申请号：DE3778866

申请日：1987-12-22

Applicant: BASF AG

Inventor： FRANZ DIETER DR ,  KUMMER RUDOLF DR ,  MACH HELMUT DR ,  RATH HANS PETER DR

IPC: C10M145/02 ,  C07C69/003 ,  C10L1/14 ,  C10L1/18 ,  C10L1/182 ,  C10L1/19 ,  C10L1/198 ,  C10L1/22 ,  C10L1/2383 ,  C10L10/08 ,  C10M129/06 ,  C10M129/16 ,  C10M129/68 ,  C10M129/90 ,  C10M129/95 ,  C10M133/06 ,  C10M133/52 ,  C10M133/54 ,  C10M133/56 ,  C10M141/06 ,  C10M145/24 ,  C10M149/02 ,  C10N20/04 ,  C10N40/25

Abstract: (A) Esters and (poly)alkoxylates of polybutyl or polyisobutyl alcohol of formula R-CH2-O-R' (I) are new, where R = polybutyl or polyisobutyl gp. derived from isobutene and up to 20 wt.% n-butene, R' = acyl, or R'0 = (poly)alkoxylate. (B) Fuel or lubricant compsns. contain polybutyl or polyisobutyl alcohol(s) of formula R-CH2OH (II) where R = as above, or a (poly)alkoxylate or ester thereof. In (A), the acyl gp. R' is derived from an (un)satd., aliphatic or aromatic, (a)cyclic, mono- or polycarboxylic acid; and the (poly)alkoxylate gp., R'0 = -(-0-(CH2)n)-)m-OH (III), n = 2-8, m = 1-200. In (B) the polyalkoxylate is defined as in (A).

公开(公告)号：DE3760307D1

公开(公告)日：1989-08-17

申请号：DE3760307

申请日：1987-08-12

Applicant: BASF AG

Inventor： MAERKL ROBERT DR ,  BERTLEFF WERNER DR ,  KUMMER RUDOLF DR

IPC: C07B61/00 ,  B01J31/00 ,  B01J31/20 ,  B01J31/24 ,  C07C41/00 ,  C07C41/48 ,  C07C43/315 ,  C07C67/00 ,  C07D317/22 ,  C07D319/06 ,  C07D321/06

公开(公告)号：DE3700363A1

公开(公告)日：1988-07-21

申请号：DE3700363

申请日：1987-01-08

Applicant: BASF AG

Inventor： FRANZ DIETER DR ,  KUMMER RUDOLF DR ,  MACH HELMUT DR ,  RATH HANS PETER DR

IPC: C10M145/02 ,  C07C69/003 ,  C10L1/14 ,  C10L1/18 ,  C10L1/182 ,  C10L1/19 ,  C10L1/198 ,  C10L1/22 ,  C10L1/2383 ,  C10L10/08 ,  C10M129/06 ,  C10M129/16 ,  C10M129/68 ,  C10M129/90 ,  C10M129/95 ,  C10M133/06 ,  C10M133/52 ,  C10M133/54 ,  C10M133/56 ,  C10M141/06 ,  C10M145/24 ,  C10M149/02 ,  C10N20/04 ,  C10N40/25

Abstract: Fuel motor compositions and lubricant compositions contain small amounts of one or more polybutyl or polyisobutyl alcohols of the formula (I) R-CH2-OH (I) where R is a polybutyl or polyisobutyl radical derived from isobutene and up to 20% by weight of n-butene, or a corresponding (poly)alkoxylate or a corresponding carboxylate of the polybutyl or polyisobutyl alcohol. These additives reduce deposition at the valves of piston engines.

公开(公告)号：DE3532877A1

公开(公告)日：1987-03-26

申请号：DE3532877

申请日：1985-09-14

Applicant: BASF AG

Inventor： MAERKL ROBERT DR ,  BERTLEFF WERNER DR ,  HARDER WOLFGANG DR ,  KUMMER RUDOLF DR

IPC: C07B61/00 ,  B01J31/00 ,  C07C29/15 ,  C07C29/158 ,  C07C31/20

公开(公告)号：DE3460025D1

公开(公告)日：1986-03-06

申请号：DE3460025

申请日：1984-05-03

Applicant: BASF AG

Inventor： SCHNEIDER HEINZ-WALTER DR ,  KUMMER RUDOLF DR ,  TAGLIEBER VOLKER DR

IPC: C07C67/313 ,  B01J29/12 ,  B01J31/00 ,  B01J31/20 ,  C07B61/00 ,  C07C67/333 ,  C07C67/38 ,  C07C69/67

Abstract: delta -Formylvalerates are prepared by a process wherein a 3-pentenoate is treated with an isomerization catalyst at elevated temperatures and a 4-pentenoate is distilled off, and the resulting 4-pentenoate is reacted with carbon monoxide and hydrogen at from 80 to 160 DEG C. under from 1 to 30 bar in the presence of a rhodium carbonyl complex which has been modified with tertiary organic phosphines or phosphites.

公开(公告)号：DE3317164A1

公开(公告)日：1984-11-15

申请号：DE3317164

申请日：1983-05-11

Applicant: BASF AG

Inventor： SCHNEIDER HEINZ-WALTER DR ,  KUMMER RUDOLF DR ,  TAGLIEBER VOLKER DR

IPC: C07C67/313 ,  B01J29/12 ,  B01J31/00 ,  B01J31/20 ,  C07B61/00 ,  C07C67/333 ,  C07C67/38 ,  C07C69/67

Abstract: delta -Formylvalerates are prepared by a process wherein a 3-pentenoate is treated with an isomerization catalyst at elevated temperatures and a 4-pentenoate is distilled off, and the resulting 4-pentenoate is reacted with carbon monoxide and hydrogen at from 80 to 160 DEG C. under from 1 to 30 bar in the presence of a rhodium carbonyl complex which has been modified with tertiary organic phosphines or phosphites.

公开(公告)号：DE3161044D1

公开(公告)日：1983-11-03

申请号：DE3161044

申请日：1981-10-22

Applicant: BASF AG

Inventor： RICHTER WOLFGANG DR ,  KUMMER RUDOLF DR ,  SCHWIRTEN KURT DR

IPC: C07C27/22 ,  B01J31/00 ,  B01J31/24 ,  B01J31/28 ,  C07B61/00 ,  C07C27/00 ,  C07C29/158 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C67/00

Abstract: A process for hydroformylating olefinically unsaturated compounds by means of rhodium/triphenylphosphine/carbonyl complexes formed in situ from rhodium acetate, triphenylphosphine and carbon monoxide, wherein the hydroformylation reaction is preceded by a starting phase in which the mixture of the hydroformylation medium, the triphenylphosphine and rhodium acetate is heated at from 90 DEG to 120 DEG C. under a CO/H2 pressure of from 5 to 20 bar and the acetic acid liberated is discharged from the reactor in gaseous form in a stream of CO and H2, until virtually no more acetic acid can be detected in this gaseous discharge.