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公开(公告)号：JPH0333125A
公开(公告)日：1991-02-13
申请号：JP16741889
申请日：1989-06-29
Applicant: TORAY INDUSTRIES
Inventor： YAMANAKA TORU , INOUE SHUNEI
IPC: C08G63/685 , C08G63/19 , C08G63/60
Abstract: PURPOSE:To obtain the title polyester excellent in heat resistance and mechanical properties and useful as, e.g. a plastics as a substitute for a metal by constituting it from specified structural units. CONSTITUTION:This polyester is composed of structural units of formulas I-III (wherein R1-3 are each a group selected from among groups of formula X, etc.) and at least one kind of units selected from among imide bond-containing structural units of formulas IV-IX (wherein R4-9 and R11-14 are groups such as R1) or structural units of formulas I and II and at least one kind of units selected from among imide bond-containing structural units of formulas IV-IX, and contains 1-30mol%, based on the entire, total of structural units of formulas IV-IX.
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公开(公告)号：JPH0314863A
公开(公告)日：1991-01-23
申请号：JP7431290
申请日：1990-03-23
Applicant: TORAY INDUSTRIES
Inventor： OKAMOTO MASARU , ICHIKAWA YASUNORI , INOUE SHUNEI
IPC: C08L63/00 , C08G59/00 , C08K5/15 , C08K5/1515 , C08L67/00
Abstract: PURPOSE:To prepare a thermotropic liquid crystal polyester compsn. excellent in the heat resistance represented by the hydrolysis resistance and long-term aging properties by compounding an org. epoxy compd. into a thermotropic liquid crystal polyester comprising specific structural units. CONSTITUTION:0.01-10 pts.wt. org. epoxy compd. is compounded into 100 pts.wt. thermotropic liquid crystal polyester which forms an anisotropic molten phase having a heat distortion temp. of 150 deg.C or higher and comprises structural units of formulas I to IV in molar ratios of (I+II)/(I+II+III), III/(I+II+III), and I/II of 0.750.95, 0.25-0.05, and 75/25-95/5 respectively, wherein R1 is formula V; and R2 is formula VI. The org. epoxy compd. is not particularly limited.
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公开(公告)号：JPH02206644A
公开(公告)日：1990-08-16
申请号：JP2687789
申请日：1989-02-06
Applicant: TORAY INDUSTRIES
Inventor： OKAMOTO MASARU , INOUE SHUNEI
Abstract: PURPOSE:To obtain thermoplastic resin composition having excellent mechanical properties and surface gloss by compounding specific liquid-crystalline polyester with specific amount of previously fiber-reinforced thermoplastic resin. CONSTITUTION:In following composition, B is previously melt-blended with C and then, melt-blended with A. The composition is composed of 100 pts.wt. resin composition comprising (A) 50-99wt.% liquid-crystalline polymer containing preferably structural formula expressed by formula III-formula V selected from structural unit expressed by formula I and formula II (X is bifunctional aromatic residue; Y and Z are bifunctional aromatic, aliphatic or alicyclic residue; R is O or NH) and having 150-280 deg.C heat distortion temperature and (B) 50-1wt.% thermoplastic polymer (e.g. polyamide or polycarbonate) and 1-200 pts.wt., preferably 5-150 pts.wt. (C) filler (e.g. glass fiber).
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公开(公告)号：JPH01292058A
公开(公告)日：1989-11-24
申请号：JP12133388
申请日：1988-05-18
Applicant: TORAY INDUSTRIES
Inventor： KAYABA KEIJI , OKAMOTO MASARU , INOUE SHUNEI
Abstract: PURPOSE:To obtain a thermoplastic resin composition having excellent heat resistance, moldability, fluidity, hydrolysis resistance and mechanical properties, by blending a liquid crystal polyester having a specific structure with polyphenylene sulfide. CONSTITUTION:A composition comprising (A) 1-99wt.% liquid crystal polyester which consists of structural units shown by formula I-formula III (X is group shown by formula IV, formula V, CH2CH2, etc., CO groups of the formula II and formula III are mutually in para- or meta-position and >=50mol% of the CO groups are in para-position), has 190-280 deg.C heat distortion temperature, =10,000 poise melt viscosity and forms anisotropic melt phase, (B) 99-1wt.% polyphenyl sulfide and preferably further containing 0.1-70 pts.wt. based on 100 pts.wt. total amounts of the components A and B, 0.1-70 pts.wt. olefinic polymer, 5-400 pts.wt. reinforcing agent (fibrous or granular) and 1-5,000 pts.wt. thermoplastic polyester.
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公开(公告)号：JPS63223038A
公开(公告)日：1988-09-16
申请号：JP5536487
申请日：1987-03-12
Applicant: TORAY INDUSTRIES
Inventor： INOUE SHUNEI , GOTO NORIAKI
Abstract: PURPOSE:To obtain the titled polyester composed of plural structural units, moldable by melt-molding and suitable for the molding of thin-walled parts and precision parts, etc., by copolymerizing a specific amount of a hydroxycarboxylic acid. CONSTITUTION:The objective polyester containing 30-90mol.% of a structural unit of formula I (X is bivalent benzene ring, etc.), formula II (Y is bivalent benzene ring, etc.) and formula III (Y is bivalent benzene ring, etc.) at a ratio [II/(II+III)] of 10-100mol.% and having a melt viscosity of preferably 100-1,500 poise can be produced by mixing (A) an aromatic dicarboxylic acid such as 1,2-bis(2-chlorophenoxy)ethane-4,4'-dicarboxylic acid with e.g. an acylated product of (B) p-hydroxybenzoic acid and/or 6-hydroxy-2-naphthoic acid and (C) a dioxy compound (e.g. hydroquinone) and subjecting the mixture to deacetylating polycondensation reaction.
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Patent Agency Ranking
公开(公告)号：JPS62292832A
公开(公告)日：1987-12-19
申请号：JP13612786
申请日：1986-06-13
Applicant: TORAY INDUSTRIES
Inventor： INOUE SHUNEI , OKAMOTO MASARU , KATAOKA SHIRO
IPC: C08G63/60 , C08G63/66 , C08G63/672 , C08G63/68 , C08G63/682 , C08G63/688 , C09K19/38 , F16L23/028
Abstract: PURPOSE:To obtain a melt-moldable aromatic polyester excellent in heat resistance and flow, comprising three specified kinds of structural units. CONSTITUTION:This heat-resistant aromatic polyester comprises three kinds of structural units of formulas I, II and III, wherein structural units (I) amount to 55-80mol% based on the total, structural units [II+III] amount to 45-20mol% based on the total and the molar ratio of structural units (II) to structural units (III) is 1-5. In formulas I-III, X is at least one group selected from among groups of formulas IV and V, etc., and Y is at least one group selected from among groups of formulas VI and VII, etc., provided that the case where Y is a group of formula VI when X is at least one group selected from groups of formulas IV and V is excluded. Said polyester can be produced by, for example, subjecting an aromatic dihydroxy compound such as p- hydroxybenzoic acid or t-butylhydroquinone, a dicarboxylic acid such as terephthalic acid and acetic anhydride to a polycondensation reaction by elimination of acetic acid.
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公开(公告)号：JPS62218436A
公开(公告)日：1987-09-25
申请号：JP6077686
申请日：1986-03-20
Applicant: TORAY INDUSTRIES
Inventor： NAKAMURA SEIICHI , INOUE SHUNEI , KOBAYASHI HIROKAZU
Abstract: PURPOSE:To obtain the titled composition excellent in mechanical properties at high temperature, appearance of a molding, heat resistance and hydrolysis resistance, by mixing a thermoplastic polyester with a reinforcement, polyphenylene sulfide and a glycidyl group-containing olefin copolymer. CONSTITUTION:Polyphenylene sulfide which is a polymer containing at least 70mol% repeating units of formula I (wherein -Ph- is a group of formula II, III or IV or the like) is heated with water by agitating to 80 deg.C or above to obtain a hot-water-treated polyphenylene sulfide (B). 100pts.wt. thermoplastic polyester (A) having an intrinsic viscosity of 0.5-1.3 (as measured in a 0.5% o-chlorophenol solution at 25 deg.C) is mixed with 1-100pts.wt. component B, 5-150 pts.wt. fibrous and/or particulate reinforcements (C) (e.g., glass fiber chopped strand) and 0.5-80pts.wt. glycidyl group-containing olefin copolymer (D) comprising an alpha-olefin and a glycidyl ester of an alpha,beta-unsaturated carboxylic acid (e.g., ethylene/glycidyl methacrylate copolymer).
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公开(公告)号：JPS62199615A
公开(公告)日：1987-09-03
申请号：JP4183686
申请日：1986-02-28
Applicant: TORAY INDUSTRIES
Inventor： OKUMURA ATSUSHI , INOUE SHUNEI
Abstract: PURPOSE:To obtain the titled high-polymerization degree polyester outstanding in solvent and heat resistances and mechanical properties, by interfacial polycondensation with a dicarboxylic acid dichloride, using each specific bisphenol, catalyst and organic solvent. CONSTITUTION:First, an organic solvent solution is prepared by dissolving in (A) an organic solvent, i.e. a 1-10C halogenated hydrocarbon of a boiling point T >=35 deg.C (e.g. methylene dichloride) (B) pref. 1-40wt% of isophthaloyl dichloride and/or terephthaloyl dichloride. This solution is then incorporated with (C) an aqueous alkali solution of bisphenol >=50mol% of which is bis(4- hydroxyphenyl)sulfone, with a concentration e.g. 1-30wt% and (D) a phosphonium salt of formula (R1-R4 are each 1-16C hydrocarbon; X is chlorine, etc.) followed by polycondensation at (T-15)-(T+15) deg.C, thus obtaining the objective polyester.
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公开(公告)号：JPS62174255A
公开(公告)日：1987-07-31
申请号：JP1573386
申请日：1986-01-29
Applicant: TORAY INDUSTRIES
Inventor： OKITA KIYOMI , YONETANI KIICHI , INOUE SHUNEI
Abstract: PURPOSE:To obtain a resin compsn. having excellent antistatic properties, heat resistance and mechanical properties, by blending polybutylene terephthalate with a metal salt of a specified alkylsulfonic acid and a hindered phenol compd. CONSTITUTION:A compsn. is obtd. by blending 100pts.wt. polybutylene terephthalate resin (A) having a relative viscosity of 1.30-2.00 and a terminal carboxyl group content of 10-80 equivalents/ton with 0.01-10pts.wt. metal salt of an alkyl sulfonic acid (B) of the formula (wherein R is a Cm alkyl group; R' is a Cn alkyl group; m>=2; n>=2; 6
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公开(公告)号：JPS62167351A
公开(公告)日：1987-07-23
申请号：JP806386
申请日：1986-01-20
Applicant: TORAY INDUSTRIES
Inventor： YAMANAKA TORU , INOUE SHUNEI , YONETANI KIICHI
Abstract: PURPOSE:To obtain a polyester composition giving a molded article having excellent mechanical properties, especially high impact strength at or below room temperature and high elongation at break, by dispersing a specific modified olefin copolymer in an aromatic polyester in the form of particles. CONSTITUTION:The objective composition is composed of (A) 100pts.(wt.) of an aromatic polyester having a relative viscosity of 1.40-1.80 and (B) 1-180pts. of a modified olefin copolymer dispersed in the component A. The compound B has a melt index of 0.1-2.0 at 190 deg.C, a glass transition temperature of
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