公开(公告)号：UA49813C2

公开(公告)日：2002-10-15

申请号：UA97063031

申请日：1995-11-14

Applicant: BASF AG

Inventor： KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: ⁁牰捯獥⁳獩搠獩汣獯摥映牯瀠敲慰楲杮栠污杯湥瑡摥洠瑥票敢穮祯祣湡摩獥栠癡湩⁧桴⁥潦浲汵⁡䤨㨩倠ⵈ佃䌭ⱎ椠桷捩⁨䡐猠慴摮⁳潦⁲⁡桰湥汹爠獥⁴畳獢楴畴整⁤祢挠汨牯浯瑥票牯戠潲潭敭桴汹琠慨⁴慭⁹灯楴湯污祬挠牡祲ㄠ㐭漠桴牥爠獥獴‬牦浯栠污杯湥瑡摥洠瑥票敢穮祯档潬楲敤⁳慨楶杮琠敨映牯畭慬⠠䥉㨩倠ⵈ佃䌭⹬吠敨挠浯潰湵⁤慨楶杮琠敨映牯畭慬⠠䥉
獩爠慥瑣摥眠瑩⁨⁡祣湡摩ⵥ敲敬獡湩⁧潣灭畯摮椠桴⁥牰獥湥散漠⁦⁡敌楷⁳捡摩‬灯楴湯污祬椠湡椠敮瑲漠杲湡捩猠汯敶瑮漠⁲楤畬湥ⱴ愠摮琠敨瀠潲畤瑣漠瑢楡敮⁤祢琠楨⁳牰捯獥⁳獩琠敨獩汯瑡摥‮桔⁥慨潬敧慮整⁤敭桴汹戠湥潺汹挠慹楮敤⁳慨楶杮琠敨映牯畭慬⠠⥉愠敲椠灭牯慴瑮椠瑮牥敭楤瑡⁥牰摯捵獴映牯琠敨猠湹桴獥獩漠⁦汰湡⁴牰瑯捥楴敶愠敧瑮⹳਍਍਍

公开(公告)号：CZ20021978A3

公开(公告)日：2002-09-11

申请号：CZ20021978

申请日：2000-11-27

Applicant: BASF AG

Inventor： GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/60 ,  C07C57/76 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R 1 to R 4 can be the same or different and represent hydrogen C 1 -C 4 alkyl, halogen or trifluoromethyl, by reaction benzo condensed lactones of formula (II), in which R 1 to R 4 have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.

公开(公告)号：CA2405763A1

公开(公告)日：2001-10-18

申请号：CA2405763

申请日：2001-04-04

Applicant: BASF AG

Inventor： RACK MICHAEL ,  WOLF BERND ,  GOTZ ROLAND

IPC: C07B61/00 ,  C07C249/12 ,  C07C251/38 ,  C07C249/14 ,  C07C251/32

Abstract: The invention relates to a method for producing oxime ethers of formula (I), in which the substituents R1 and R2 can be identical or different and can respectively represent cyano, alkyl, haloalkyl, cycloalkyl, phenyl and naphthyl and R3 can represent alkyl, by the alkylation of oximes of the formula (II), under alkaline conditions, using an alkylation agent from the group containing alkyl halides, dialkyl sulfates and dialkyl carbonates. The reaction is carried out in a mixture consisting of between 5 and 25 wt.- % polar aprotic solvents, selected from the group containing nitriles, N- alkylpyrrolidones, cyclic urea derivatives, dimethylformamide and dimethylacetamide, between 55 and 95 wt.- % non-polar solvents, selected fro m the group containing aliphatic hydrocarbons, aromatic hydrocarbons, alkyl esters of alkyl carboxylic acid and ethers and between 0 and 25 wt.- % water , whereby the sum of said proportions amounts to 100 %.

公开(公告)号：DE19958758A1

公开(公告)日：2001-07-05

申请号：DE19958758

申请日：1999-12-07

Applicant: BASF AG

Inventor： GOETZ ROLAND ,  GOETZ NORBERT ,  KEIL MICHAEL ,  WOLF BERND ,  STEINMETZ ADRIAN ,  STAMM ARMIN ,  HENKELMANN JOCHEM

IPC: C07C51/60 ,  C07C51/58 ,  C07C63/10 ,  C07C63/68

Abstract: Production of o-chloromethylbenzoyl chlorides (I) by reacting benzo-condensed lactones (II) with thionyl chloride is carried out in the presence of catalytic amounts of (a) a catalyst (III) containing boron, selected from boric acid and anhydride, borates, boronic acid and boronic esters, and (b) a quaternary ammonium salt (IV). Production of o-chloromethylbenzoyl chlorides of formula (I) by reacting benzo-condensed lactones of formula (II) with thionyl chloride is carried out in the presence of catalytic amounts of (a) a catalyst (III) containing boron, selected from boric acid and anhydride, borates, boronic acid and boronic esters, and (b) a quaternary ammonium salt (IV). R1-R4 = H, 1-4C alkyl, halogen or CF3.

公开(公告)号：AU2837201A

公开(公告)日：2001-06-18

申请号：AU2837201

申请日：2000-11-27

Applicant: BASF AG

Inventor： STAMM ARMIN ,  GOTZ ROLAND ,  GOTZ NORBERT ,  HENKELMANN JOCHEM ,  KNEUPER HEINZ-JOSEF ,  WOLF BERND

IPC: C07C51/58 ,  C07B61/00 ,  C07C51/09 ,  C07C57/76 ,  C07C51/00

Abstract: The invention relates to a method for producing o-choromethyl benzenecarbonyl chlorides of formula (I), wherein R -R can be the same or different and stand for hydrogen, C1-C4-alkyl, halogen or trifluoromnethyl, by converting benzocondensed lactones of formula (II), wherein R -R have the aforementioned meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterized in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst

公开(公告)号：DE19959066C1

公开(公告)日：2001-05-03

申请号：DE19959066

申请日：1999-12-08

Applicant: BASF AG

Inventor： GOETZ ROLAND ,  STAMM ARMIN ,  GOETZ NORBERT ,  KEIL MICHAEL ,  HENKELMANN JOCHEM ,  WOLF BERND ,  STEINMETZ ADRIAN

IPC: C07C51/60 ,  C07C51/58 ,  C07C63/10 ,  C07C63/68

Abstract: Preparation of o-chloromethyl-benzoyl chloride derivatives (I) by reaction of benzo-fused lactones (phthalides) (II) with thionyl chloride is catalyzed by boron trifluoride dihydrate and a quaternary ammonium salt. The preparation of o-chloromethyl-benzoyl chloride derivatives of formula (I) by reaction of benzo-fused lactones of formula (II) with thionyl chloride is carried out in presence of catalytic amounts of each of boron trifluoride dihydrate and a quaternary ammonium salt. R1-R4 = H, 1-4C alkyl, halo or CF3.

公开(公告)号：PL180802B1

公开(公告)日：2001-04-30

申请号：PL32034395

申请日：1995-11-14

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST ,  WETTLING THOMAS

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

公开(公告)号：AU4116596A

公开(公告)日：1996-06-17

申请号：AU4116596

申请日：1995-11-14

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST ,  WETTLING THOMAS

IPC: C07B61/00 ,  C07C253/14 ,  C07C255/40

Abstract: PCT No. PCT/EP95/04463 Sec. 371 Date May 6, 1997 Sec. 102(e) Date May 6, 1997 PCT Filed Nov. 14, 1995 PCT Pub. No. WO96/16023 PCT Pub. Date May 30, 1996Halomethylbenzoyl cyanides I PH-CO-CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH-CO-Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.

公开(公告)号：HU9400996D0

公开(公告)日：1994-06-28

申请号：HU9400996

申请日：1994-04-07

Applicant: BASF AG

Inventor： WETTLING THOMAS ,  WOLF BERND ,  KEIL MICHAEL ,  ISAK HEINZ ,  DOETZER REINHARD

IPC: C07C253/14 ,  C07C255/32 ,  C07C255/40

Abstract: A process for preparing halomethylbenzoyl cyanides I Ph-CO-CNI (Ph=phenyl radical substituted by chloromethyl or bromomethyl which, if desired, can additionally carry 1-4 further radicals) by reacting halomethylbenzoyl chlorides II Ph-CO-ClII with an alkali metal cyanide or transition metal cyanide, if appropriate in an organic diluent, and novel halomethylbenzoyl cyanides I' I' (X=halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C5-alkyl-(C1-C5-alkyl)hydroxyimino or C1-C5-alkyl-(C2-C5-alkenyl)hydroxyimino; m=0 to 4 and Y=chloromethyl or bromomethyl) are described. The halomethylbenzoyl cyanides I are important intermediates for the synthesis of plant protection agents.

公开(公告)号：HUT64300A

公开(公告)日：1993-12-28

申请号：HU9300296

申请日：1993-02-04

Applicant: BASF AG

Inventor： ISAK HEINZ ,  KEIL MICHAEL ,  WOLF BERND ,  WINGERT HORST

IPC: C07C67/313 ,  C07B61/00 ,  C07C59/68 ,  C07C59/84 ,  C07C67/31 ,  C07C69/708 ,  C07C69/716 ,  C07C249/04 ,  C07C249/08 ,  C07C249/12 ,  C07C251/48 ,  C07C251/40

Abstract: The present invention relates to a process for the preparation of E-oxime ethers of phenylglyoxylic esters of the general formula I in which X and Y denote halogen, alkyl, alkoxy, CF3, C(=NOR)R (R = alkyl and alkenyl), by reacting oximes of the formula II with a methylating agent in an organic diluent, and process for the preparation of E-oximes of phenylglyoxylic esters of the formula II by isomerising the E/Z oximes.