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121.
公开(公告)号:DE3563043D1
公开(公告)日:1988-07-07
申请号:DE3563043
申请日:1985-11-29
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF DR , HAHN ERWIN DR , KUD ALEXANDER DR , OFTRING ALFRED DR
IPC: C08F20/00 , C07C67/00 , C07C67/343 , C07C69/732 , C07C253/00 , C07C255/23 , C08F20/10 , C08F20/42 , C08F20/52 , C08F220/00 , C07C93/193 , C07C121/413 , C07C120/00
Abstract: 2-(1-Hydroxycarbalkoxymethyl)-acrylonitriles and 2-(1-hydroxycarbalkoxymethyl)-acrylates are prepared by a process in which an acrylonitrile or an acrylate is reacted with a glyoxylate in an aqueous medium at a pH greater than or equal to 6, in the presence of a tertiary amine as a catalyst.
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公开(公告)号:DE3444097A1
公开(公告)日:1986-06-05
申请号:DE3444097
申请日:1984-12-04
Applicant: BASF AG
Inventor: FIKENTSCHER ROLF DR , HAHN ERWIN DR , KUD ALEXANDER DR , OFTRING ALFRED DR
IPC: C08F20/00 , C07C67/00 , C07C67/343 , C07C69/732 , C07C253/00 , C07C255/23 , C08F20/10 , C08F20/42 , C08F20/52 , C08F220/00 , C07C121/34
Abstract: 2-(1-Hydroxycarbalkoxymethyl)-acrylonitriles and 2-(1-hydroxycarbalkoxymethyl)-acrylates are prepared by a process in which an acrylonitrile or an acrylate is reacted with a glyoxylate in an aqueous medium at a pH greater than or equal to 6, in the presence of a tertiary amine as a catalyst.
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公开(公告)号:AT257466T
公开(公告)日:2004-01-15
申请号:AT97101598
申请日:1994-06-07
Applicant: BASF AG
Inventor: SCHNEIDER JUERGEN DR , POTTHOFF-KARL BIRGIT DR , KUD ALEXANDER DR , BAUR RICHARD DR , OFTRING ALFRED DR , GREINDL THOMAS DR
IPC: C07D307/54 , A23C7/02 , A61K8/44 , A61Q11/00 , C07B61/00 , C07C227/00 , C07C227/02 , C07C227/18 , C07C227/26 , C07C229/16 , C07C229/26 , C07C229/30 , C07C229/34 , C07C229/36 , C07C255/24 , C07C255/25 , C07D207/337 , C07D211/74 , C07D213/55 , C07D263/32 , C07D277/30 , C07D307/24 , C07D333/24 , C11D3/33 , C11D11/00 , C11D17/06 , D06L1/14 , D06L3/02 , D06L4/12 , D06L4/30 , D06M11/40 , D21C9/10 , D21C9/16 , G03C5/305 , G03C5/38 , G03C5/44 , G03C7/42
Abstract: Use of glycine-N,N-diacetic acid derivs. of formula (I) is claimed as complex formers for alkaline earth or heavy metals. R = 1-20C alkyl, 2-20C alkenyl or -A.CH(COOM).N(CH2COOM)2; A = 1-12C alkylene or a chemical bond; M = H, alkali metal or opt. substd. ammonium. The use of ~a-alanine-N,N-diacetic acids as builders in textile-washing powders or as Ca sequestrants in oral hygiene compsns. is specifically excluded. Also claimed are 2-alkylglycine-N,N-diacetonitriles or 2-alkylglycinenitrile -N,N-diacetonitriles (where alkyl = 1-20C alkyl or 2-20 C alkenyl); and cpds. of formula (II). X = carboxylic acid or nitrile function. Cpds. of formula (I) are new except when R = 1-3C alkyl and A = chemical bond.
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公开(公告)号:AT226241T
公开(公告)日:2002-11-15
申请号:AT97122735
申请日:1994-06-07
Applicant: BASF AG
Inventor: SCHNEIDER JUERGEN DR , POTTHOFF-KARL BIRGIT DR , KUD ALEXANDER DR , BAUR RICHARD DR , OFTRING ALFRED DR , GREINDL THOMAS DR
IPC: C07D307/54 , A23C7/02 , A61K8/44 , A61Q11/00 , C07B61/00 , C07C227/00 , C07C227/02 , C07C227/18 , C07C227/26 , C07C229/16 , C07C229/26 , C07C229/30 , C07C229/34 , C07C229/36 , C07C255/24 , C07C255/25 , C07D207/337 , C07D211/74 , C07D213/55 , C07D263/32 , C07D277/30 , C07D307/24 , C07D333/24 , C11D3/33 , C11D11/00 , C11D17/06 , D06L1/14 , D06L3/02 , D06L4/12 , D06L4/30 , D06M11/40 , D21C9/10 , D21C9/16 , G03C5/305 , G03C5/38 , G03C5/44 , G03C7/42
Abstract: Use of glycine-N,N-diacetic acid derivs. of formula (I) is claimed as complex formers for alkaline earth or heavy metals. R = 1-20C alkyl, 2-20C alkenyl or -A.CH(COOM).N(CH2COOM)2; A = 1-12C alkylene or a chemical bond; M = H, alkali metal or opt. substd. ammonium. The use of ~a-alanine-N,N-diacetic acids as builders in textile-washing powders or as Ca sequestrants in oral hygiene compsns. is specifically excluded. Also claimed are 2-alkylglycine-N,N-diacetonitriles or 2-alkylglycinenitrile -N,N-diacetonitriles (where alkyl = 1-20C alkyl or 2-20 C alkenyl); and cpds. of formula (II). X = carboxylic acid or nitrile function. Cpds. of formula (I) are new except when R = 1-3C alkyl and A = chemical bond.
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公开(公告)号:ES2145341T3
公开(公告)日:2000-07-01
申请号:ES96108081
申请日:1996-05-21
Applicant: BASF AG
Inventor: GREINDL THOMAS DR , OFTRING ALFRED DR , BRAUN GEROLD DR , WILD JOCHEN DR , POTTHOFF-KARL BIRGIT DR , SCHUH GEORG
IPC: C07C227/18 , C07C227/14 , C07C227/16 , C07C227/24 , C07C227/26 , C07C229/16
Abstract: Prepn. of glycine-N,N-diacetic acid derivs. of formula (I), where R = 1-30C alkyl or 2-30C alkenyl, which can also contain, as substits., up to 5 hydroxyl gps., formyl gps., 1-4C alkoxy gps., phenoxy gps. of 1-4C alkoxycarbonyl gps., and which can be interrupted by up to 5 non-adjacent O atoms, alkoxylate groupings of formula -(CH2)k-O-(A O)m-(A O)n-Y, phenyl alkyl gps. with 1-20C atoms in the alkyl, phenyl, a 5- or 6-membered (un)satd. heterocyclic ring with up to 3 heteroatoms from N, O and S which can also be benzo-condensed, whereby all phenyl cores and heterocyclic rings given for R can also contain as substits. up to 3 1-4C alkyl gps., hydroxyl, gps., carboxyl gps., sulpho gps. or 1-4C alkoxy carbonyl gps., or a gp. of formula (II); A = 1-12C alkylene bridge or a chemical bond; A , A = 2-4C 1,2-alkylene gps.; Y = H, 1-12 C alkyl, phenyl or 1-4 C alkoxycarbonyl; k = 1, 2 or 3; m, n = 0-50; m+n = at least 4; and M = H, alkali metal, alkaline earth metal, ammonium or substd. ammonium in the corresp. stoichiometric quantities, comprises reacting corresp. 2-substd. glycines or 2-substd. glycine nitriles or double glycines of formula (III) or double glycine nitriles of formula (IV) or precursors of the glycine derivs. given as starting materials with formaldehyde and alkali metal cyanide in aq. alkaline medium at a pH of 8-14. The novelty is that 0.5-30 % of the quantity of alkali metal cyanide required for reaction is added to the glycine derivs. or their precursors and then the remaining amt. of alkali metal cyanide and the formaldehyde is added simultaneously over 0.5-12 hrs.
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公开(公告)号:DE59504247D1
公开(公告)日:1998-12-24
申请号:DE59504247
申请日:1995-04-27
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , BURKHART BERND DR , WEHLAGE THOMAS DR , DYLLICK-BRENZINGER RAINER DR , BECK KARIN HEIDRUN DR
IPC: C07D231/12 , C07D233/58 , G03G9/097
Abstract: Electrostatic toner contains a polymeric binder and, as charge stabiliser, a phenylacyl cpd. of formula (I): Het (+) - L - CD - Phe-R An (-) (I); Het (+) = a positively charged gp. derived from an heterocycle of the pyrazole, imidazole, pyridine, (iso)quinoline series; L = 1-8C alkylene; Phe = phenylene, opt. with an annelated benzene ring; R = H, OH, 1-4C alkoxy, NH2, 1-4C mono- or dialkylamino or an opt. substd. 1-6C alkyl, phenyl, phenoxy, mono- or diphenylamino or N-(1-4C alkyl)-N-phenyl-amino gp.; and An (-) = the equiv. of an anion. Also claimed is the use of (I) as charge stabiliser in electrostatic toners.
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公开(公告)号:DE19704143A1
公开(公告)日:1998-08-06
申请号:DE19704143
申请日:1997-02-04
Applicant: BASF AG
Inventor: KAPPES ELISABETH DR , WEHLAGE THOMAS DR , OFTRING ALFRED DR , BOECKH DIETER DR
IPC: C07D487/04 , C07C251/62 , C07C259/04 , C07D209/48 , C07D209/56 , C07D265/32 , C07D491/18 , C08F22/40 , C08F26/02 , C11D3/26 , C11D3/37 , C11D3/39 , C11D3/395 , C11D1/825
Abstract: Disclosed are carbonates of general formula (I): A-O-CO-OR , in which A is a radical (Ia) R R C=N- or a radical (Ib), or the hydromidesters of the general formula (I) or the polymer derivates thereof are used with radicals having the meaning of R to R , especially alkyl and aryl with or without substituents, R /R representing inter alia hydrogen or, jointly, an alkyl group, while R /R represent inter alia jointly an alkyl group and R /R a carbocycle, as activators for anorganic per compounds.
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128.
公开(公告)号:DE19650107A1
公开(公告)日:1998-06-04
申请号:DE19650107
申请日:1996-12-03
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , OETTER GUENTER DR , BAUR RICHARD DR , BORZYK OLIVER DR , BURKHART BERND DR , OTT CHRISTIAN DR , KAHMEN MARTIN AUS DEM DR
IPC: C07C231/02 , C07C231/24 , C07C233/05 , C07C233/09 , C07C233/18 , C07C233/20 , C11D19/00
Abstract: Separation of glycerol (I) from a reaction mixture containing (I) and fatty acid amides (II) comprises separation into an aqueous phase containing (I) and an organic phase containing (II) by adding aqueous acid solution to pH 1-7 and separating the aqueous phase. Also claimed is a method of preparing (II) by reacting fatty acid glycerides (III) with amines, in which the reaction mixture is treated in this way.
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公开(公告)号:DE19647636A1
公开(公告)日:1998-05-20
申请号:DE19647636
申请日:1996-11-18
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , KAHMEN MARTIN AUS DEM DR , OETTER GUENTER DR , BAUR RICHARD DR
IPC: C07C231/02 , C07C235/10 , C07C235/28 , C09K23/22 , C09K23/46 , C11D1/52 , G03C1/38 , B01F17/22 , B01F17/46 , C11D1/66 , A61K7/48
Abstract: Compounds have the general formula (I) R -CO-NR (-A)n-B-N((-D)m-R )2, in which R is a linear or branched aliphatic C5-23-radical with 0 to 4 C-C double bonds and at least one hydroxyl group; R is H or (-A)n-B-N((-D)m-R )2; R is H or a C1-4-alkyl radical; A and D independently represent CH2-CHR -O, in which R is H, CH3, C2H5; B is C1-12-alkylene; n equals 0 to 6 and m equals 1 to 10. These compounds are used as surface-active substances, non-ionic surfactants or emulsifiers.
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公开(公告)号:ES2046408T5
公开(公告)日:1997-05-16
申请号:ES89115869
申请日:1989-08-29
Applicant: BASF AG
Inventor: BAUR RICHARD DR , GOUSETIS CHARALAMPOS DR , TRIESELT WOLFGANG DR , BOCHNITSCHEK WERNER DR , OFTRING ALFRED DR
IPC: C07C227/14 , C07C227/06 , C07C227/18 , C07C229/16
Abstract: Preparation of beta -alaninediacetic acid (Ia) or its alkali metal or ammonium salts (Ib) by reacting iminodiacetic acid and acrylic acid a) with one another in non-basic aqueous medium for the preparation of Ia and b) with one another in alkaline or nigrogen-basic aqueous medium for the preparation of Ib or converting the Ia formed in non-basic medium into Ib using an alkali metal base, ammonia or an amine.
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