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    Multimetal oxide materials
    133.
    发明专利
    Multimetal oxide materials 未知

    公开(公告)号：SG75800A1

    公开(公告)日：2000-10-24

    申请号：SG1996010394

    申请日：1996-07-31

    Applicant: BASF AG

    Inventor： TENTEN ANDREAS ,  HIBST HARTMUT ,  MAROSI KASZLO

    IPC: B01J23/88 ,  B01J23/00 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  B01J23/885

    Abstract: Multi-metal oxide compsn. of general formula ÄAÜpÄBÜq (I) is new (where, A = Mo12Va(X b)(X c)(X d)X e)(X f )(X g)Ox, B = X 12CuhHiOy (promoter phase); X = W, Nb, Ta, Cr and/or Ce; X = Cu, Ni, Co, Fe, M n and/or Zn; X = Sb and/or Bi; X = Li, Na, K, Rb, Cs and/or H; X = Mg, Ca, Sr and/or Br; X = Si, Al, Ti and/or Zr; X = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d = 0-50; e = 0-2; f = 0-5; g = 0-50; h = 4-30; i = 0-20; x, y = values determining the valency and frequency of elements different from oxygen in the compsn.; and p, q = values other than zero, whose ratio p/q = 160-1:1. The proportions of (A)p and (B)q are in the form of chemical compsns. differing from their local environment. A and B are distributed relative to each other such as a mixt. of finely divided A and finely divided B, with the proviso that B contains crystals B* of oxometallates of formula CuMoaWbVcNbdTeOy (II) (where, a/(A+B+C+D+E)=0.7-1.3; (B+C+D+E)/A = 0.01-1; and Y = a value determined by the valency and frequency of elements in (II) different from oxygen) of a new structure type (HT-Cu molybdate) defined by the X-ray diffraction pattern: d(A)=6.79+/-0.3; 3.56+/-0.3; 3.54+/-0.3, 3.40+/-0.3; 3.04+/-0.3, 2.96+/-0.3; 2.67+/-0.2; 2.66+/-0.2; 2.56+/-0.2, 2.36+/-0.2; 2.35+/-0.2; 2.27+/-0.2; 2.00+/-0.2;1.87+/-0.3; 1.70+/-0.2; 1.64+/-0.2; 1.59+/-0.2; 1.57+/-0.2; 1.57+/-0.2; 1.55+/-0.2; 1.51+/-0.2; 1.44+/-0.2. Also claimed are: (i) the oxometallates of formula (II); (ii) mixt. of oxometallates (II); (iii) prodn. of the multi-metal oxide compsn..

    Production of enol ether involves reacting alcohol and/or acetal with alkyne and/or allene compound and then working up by distillation with recycling of acetal and alcohol, possibly after catalytic acetalization
    135.
    发明专利
    Production of enol ether involves reacting alcohol and/or acetal with alkyne and/or allene compound and then working up by distillation with recycling of acetal and alcohol, possibly after catalytic acetalization 未知

    公开(公告)号：DE19841552A1

    公开(公告)日：2000-03-16

    申请号：DE19841552

    申请日：1998-09-11

    Applicant: BASF AG

    Inventor： BECKER HEIKE ,  BREUER KLAUS ,  DEMUTH DIRK ,  HIBST HARTMUT ,  TELES JOAQUIM HENRIQUE ,  PREISS THOMAS

    IPC: C07C41/08 ,  C07C41/28 ,  C07C41/42 ,  C07C43/14 ,  C07C43/16 ,  C07C43/162 ,  C07C43/166

    Abstract: Enol ethers (I) are produced by reacting alcohols (II) and/or acetals or ketals (III) derived from (I) with acetylenes (IV) and/or allenes (V), using a mol ratio of (II + III):(IV/V) = 1 or more and working up the product by distillation with recycling of acetal and alcohol, possibly after catalytic acetalization of excess alcohol with the enol ether. A process for the production of enol ethers of formula (I) by reaction of alcohols (II) and/or acetals or ketals (III) with acetylenes (IV) and/or allenes (V) in the gas-phase at elevated temperature in presence of a heterogeneous catalyst containing zinc or cadmium together with silicon and oxygen, followed by distillation to give (I): R = an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic residue (all optionally with other substituents which do not react with acetylenes or allenes); R = H or organic groups as listed for R , which may combine to form rings; m = 0 or 1. In this process, (a) the reaction is carried out with a mol ratio of (II + III):(IV and/or V) = 1 or more, in such a way that the product leaving the reactor (containing I with excess II and III) is practically free from acetylene or allene, after which (b1) this product is immediately distilled to give an azeotrope comprising (I) and (II) as the top fraction (possibly containing unreacted IV/V), enol ether (I) as intermediate fraction and (III) as bottom product, the top and bottom fractions being returned to the reactor, with the proviso that the reaction conditions and the mol ratio of the reactor feed are such that the mol ratio of (I) to (II) in the reactor product is greater than that in the azeotrope, or (b2) if (I) and (II) do not form an azeotrope, the reactor product is immediately distilled to give (I) as top product and a mixture of (III) and (II) as bottom product which is returned to the reactor, and/or (c) the product from the reactor is subjected to reaction at below 100 deg C on an acetalization catalyst, resulting in reaction of excess (II) with the product (I) to form acetal (III), followed by distillation to give the product (I) and acetal (III) which is returned to the reactor.

    Method for producing enol ethers
    138.
    发明专利
    Method for producing enol ethers 未知

    公开(公告)号：AU8626098A

    公开(公告)日：1999-01-04

    申请号：AU8626098

    申请日：1998-06-10

    Applicant: BASF AG

    Inventor： TELES JOAQUIM HENRIQUE ,  RIEBER NORBERT ,  BREUER KLAUS ,  DEMUTH DIRK ,  HIBST HARTMUT ,  ETZRODT HEINZ ,  RHEUDE UDO

    IPC: B01J21/16 ,  C07B61/00 ,  C07C41/08 ,  C07C41/28 ,  C07C43/15 ,  C07C43/16

    Abstract: Enol ethers of the formula Iwhere R1 is an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical which may carry further substituents which do not react with acetylenes or allenes, and the radicals R, independently of one another, are hydrogen or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radicals, which may be bonded to one another to form a ring, and m is 0 or 1, are prepared by reacting an acetal or ketal of the formula IIwith an acetylene or allene of the formula III or IVwhere R and R1 have the abovementioned meanings, in the gas phase at elevated temperatures in the presence of a zinc- or cadmium- and silicon- and oxygen-containing heterogeneous catalyst.

    140.
    发明专利
    未知

    公开(公告)号：ID16006A

    公开(公告)日：1997-08-28

    申请号：ID963350

    申请日：1996-11-15

    Applicant: BASF AG

    Inventor： HIBST HARTMUT ,  TENTEN ANDREAS ,  MAROSI LASZLO

    IPC: C01G1/00 ,  B01J23/00 ,  B01J23/20 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C01G41/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/38 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  B01J27/00

    Abstract: A multimetal oxide of formula (I) Mo12-a-b-cVaM bM cOx is new, where: M = tungsten (W) and/or niobium (Nb); M = titanium (Ti), zirconium (Zr), hafnium (Hf), tantalum (Ta), chromium (Cr), silicon (Si) and/or germanium (Ge); a = 0.1-6; b = 0-6; c = 0-6; a+b+c = 0.1-6; and x = number determined by the valency and frequency of the element in (I) except oxygen. Its atomic space arrangement is determined by powder X-ray diffraction (the intensity A of the diffracted X-ray beam as a function of two-fold diffraction angle (2&thetas; )) using Cu-K alpha -radiation ( lambda = 1.54178 Angstrom ), so that in the 2&thetas; region of 5-50 degrees the following diffraction lines are produced: Al(X-ray diffraction line) = 8.3 plus or minus 0.7 (2&thetas; degrees ); A2=14.4 plus or minus 0.7; A3=22.3 plus or minus 0.2; A4=23.5 plus or minus 0.7; A5=27.2 plus or minus 0.4; A6=32.0 plus or minus 0.8; A7=34.8 plus or minus 0.6; A8=38.7 plus or minus 0.5; A9=45.4 plus or minus 0.4; and A10=48.8 plus or minus 0.4. Also claimed are: (i) a process for catalytic gas phase oxidation of organic compounds using the above multimetal oxide; and (ii) a finely divided mixture containing the above multimetal oxide (I) and a multimetal oxide (II) of formula: M 12CudHeOy, where: M = molybdenum (Mo), W, vanadium (V), Nb and/or Ta; d = 4-30; e = 0-20; and y = a number determined by the valency and frequency of the elements in (II) except oxygen.

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