公开(公告)号：CA2298563C

公开(公告)日：2006-07-11

申请号：CA2298563

申请日：1998-07-20

Applicant: BASF AG

Inventor： MULLER BERND ,  KEIL MICHAEL ,  WINGERT HORST ,  GOTZ NORBERT

IPC: C07B39/00 ,  C07C17/14 ,  C07C25/02 ,  C07C67/307 ,  C07C69/76 ,  C07C201/12 ,  C07C205/11 ,  C07C253/30 ,  C07C255/50

Abstract: The invention concerns a method for preparing substituted benzyl bromides of general formula (I), wherein at least one substituent R1-5 represents an electroattractive group, such as fluorine, chlorine, bromine, C1-C4 alkoxycarbonyl, cyano or nitro, and the remaining R1-5 substituents represent hydrogen or methyl, by bromination of substitute d toluenes of general formula (II) with a bromination agent at temperatures from 20 to 95 .degree. C.

公开(公告)号：ZA200409518B

公开(公告)日：2006-06-28

申请号：ZA200409518

申请日：2004-11-25

Applicant: BASF AG

Inventor： ENGEL STEFAN ,  KEIL MICHAEL ,  RACK MICHAEL ,  OTT CHRISTIAN

IPC: C07B61/00 ,  C07C20060101 ,  C07C253/30 ,  C07C255/56

Abstract: A process is described for preparing 3-trifluoromethylphenyl 4-cyanobenzyl ketone by reacting a C 1 -C 2 -alkyl 3-trifluoromethylbenzoate with 4-tolunitrile in an aprotic polar solvent or an aprotic polar solvent mixture in the presence of at least an equimolar amount of a base which is selected from potassium alkoxides of primary C 1 -C 4 -alkanols.

公开(公告)号：ES2250425T3

公开(公告)日：2006-04-16

申请号：ES01947430

申请日：2001-06-29

Applicant: BASF AG

Inventor： LOCHTMAN RENE ,  KEIL MICHAEL ,  GEBHARDT JOACHIM ,  RACK MICHAEL ,  VON DEYN WOLFGANG

IPC: C07C209/74 ,  C07C211/52 ,  C07D261/04 ,  C07C251/48 ,  C07D413/10 ,  C07C209/82 ,  C07C211/46

Abstract: Procedimiento para la obtención de derivados de la 4-bromo-anilina de la fórmula I en la que los substituyentes tienen los siguientes significados: R1 significa alquilo con 1 a 6 átomos de carbono, halógenoalquilo con 1 a 6 átomos de carbono, alcoxi con 1 a 6 átomos de carbono, halógenoalcoxi con 1 a 6 átomos de carbono, cicloalquilo con 3 a 8 átomos de carbono, halógeno, R2 significa alquilo con 1 a 6 átomos de carbono, alcoxi con 1 a 6 átomos de carbono, cicloalquilo con 3 a 8 átomos de carbono, alquenilo con 2 a 6 átomos de carbono, ciano o un resto heterocíclico, en la que R1 y R2 tienen los significados anteriormente indicados, con un agente para la bromación, en piridina a modo de disolvente, o en una mezcla de disolventes con al menos un 55% en peso de piridina.

公开(公告)号：PL377943A1

公开(公告)日：2006-02-20

申请号：PL37794303

申请日：2003-12-01

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  HOFFMANN NICO ,  KEIL MICHAEL ,  VOGELBACHER UWE JOSEF ,  WEVERS JAN HENDRIK

IPC: C07C45/46 ,  C07C45/81 ,  C07C49/84 ,  C07C51/363 ,  C07C51/60

公开(公告)号：BR0316844A

公开(公告)日：2005-10-18

申请号：BR0316844

申请日：2003-12-01

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  HOFFMANN NICO ,  KEIL MICHAEL ,  VOGELBACHER UWE JOSEF ,  WEVERS JAN HENDRIK

IPC: C07C45/46 ,  C07C45/81 ,  C07C51/363 ,  C07C51/60 ,  C07C49/84

Abstract: A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C 1 -C 6 -alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride of the formula II where X and Y are as defined above with 3,4,5-trimethoxytoluene, which comprises carrying out the reaction in the presence of a) an aromatic hydrocarbon as a diluent and b) from 0.01 to 0.2 mol % of an iron catalyst, based on the acid chloride, c) at a temperature between 60° C. and the boiling point of the particular diluent.

公开(公告)号：NO318079B1

公开(公告)日：2005-01-31

申请号：NO20005652

申请日：2000-11-09

Applicant: BASF AG

Inventor： HAGEN HELMUT ,  KEIL MICHAEL ,  BAUMANN ERNST ,  RHEINHEIMER JOACHIM ,  GOTZ NORBERT ,  WITSCHEL MATTHIAS ,  RACK MICHAEL ,  GEBHARDT JOACHIM ,  LOCHTMAN RENE ,  DEYN WOLFGANG VON ,  MISSLITZ ULF

IPC: C07C20060101 ,  C07C201/12 ,  C07C205/44 ,  C07C249/06 ,  C07C251/48 ,  C07C251/52 ,  C07C253/00 ,  C07C255/50 ,  C07C317/32 ,  C07C319/14 ,  C07C323/09 ,  C07D20060101 ,  C07D261/02 ,  C07D261/04 ,  C07D261/08 ,  C07D413/02 ,  C07D413/10 ,  C07C251/40

公开(公告)号：BR0307533A

公开(公告)日：2004-12-21

申请号：BR0307533

申请日：2003-02-06

Applicant: BASF AG

Inventor： MAYER GUIDO ,  CULLMANN OLIVER ,  WOLF BERND ,  KEIL MICHAEL

IPC: C07C249/12 ,  C07B61/00 ,  C07C251/38 ,  C07C251/48

Abstract: The invention relates to a method for producing 2-chloromethylphenyl acetic acid derivatives of formula (I), in which X represents C1-C4 alkoxy or methylamino, by cleaving the ether bonds in compounds of formula (II), in which R represents C1-C4 alkyl, C1-C4 alkoxy, C1-C2 alkyl halide, C1-C4 alkylcarbonyl, C1-C4 alkylcarbonyloxy, halogen, nitro or cyano, and X has the above-mentioned meaning. The inventive method is characterized in that the transformation takes place in the presence of hydrogen chloride and of an inert solvent, and in that a catalyst selected from the group comprised of: iron, indium or halogenides, oxides or triflates thereof is added to the reaction mixture.

公开(公告)号：PL187954B1

公开(公告)日：2004-11-30

申请号：PL33844298

申请日：1998-07-20

Applicant: BASF AG

Inventor： WINGERT HORST ,  GOETZ NORBERT ,  KEIL MICHAEL ,  MUELLER BERND

IPC: C07B39/00 ,  C07C17/14 ,  C07C25/02 ,  C07C67/307 ,  C07C69/76 ,  C07C201/12 ,  C07C205/11 ,  C07C253/30 ,  C07C255/50

Abstract: PCT No. PCT/EP98/04485 Sec. 371 Date Jan. 11, 2000 Sec. 102(e) Date Jan. 11, 2000 PCT Filed Jul. 20, 1998 PCT Pub. No. WO99/06339 PCT Pub. Date Feb. 11, 1999Substituted benzyl bromides of the formula I where at least one substituent R1-5 is an electron-attracting group such as fluorine, chlorine, bromine, C1-C4-alkoxycarbonyl, cyano or nitro, and the other substituents R1-5 are hydrogen or methyl, are prepared by bromination of substituted toluenes of the formula II with a brominating agent at from 20 to 95 DEG C.

公开(公告)号：AU2003294750A1

公开(公告)日：2004-07-09

申请号：AU2003294750

申请日：2003-12-01

Applicant: BASF AG

Inventor： MAYWALD VOLKER ,  HOFFMANN NICO ,  KEIL MICHAEL ,  VOGELBACHER UWE JOSEF ,  WEVERS JAN HENDRIK

IPC: C07C45/46 ,  C07C45/81 ,  C07C51/363 ,  C07C51/60 ,  C07C49/84

Abstract: A process for preparing benzophenones of the formula I, where X may be chlorine, hydroxyl, methoxy or C 1 -C 6 -alkylcarbonyloxy, and Y may be chlorine or bromine, by reacting an acid chloride of the formula II where X and Y are as defined above with 3,4,5-trimethoxytoluene, which comprises carrying out the reaction in the presence of a) an aromatic hydrocarbon as a diluent and b) from 0.01 to 0.2 mol % of an iron catalyst, based on the acid chloride, c) at a temperature between 60° C. and the boiling point of the particular diluent.

公开(公告)号：CA2504410A1

公开(公告)日：2004-05-13

申请号：CA2504410

申请日：2003-10-29

Applicant: BASF AG ,  SEITZ WERNER ,  REINHARD ROBERT ,  PUHL MICHAEL ,  HAMPRECHT GERHARD

Inventor： SAGASSER INGO ,  GOTZ NORBERT ,  WOLF BERND ,  KEIL MICHAEL ,  SEITZ WERNER ,  REINHARD ROBERT ,  PUHL MICHAEL ,  HAMPRECHT GERHARD

IPC: C07C303/34 ,  C07C307/06 ,  C07C331/28 ,  C07D207/20 ,  C07D211/18 ,  C07D211/70 ,  C07D213/76 ,  C07D295/26 ,  C07D307/52 ,  C07D319/06 ,  C07D333/20

Abstract: The invention relates to a method for producing phenyliso(thio)cyanates of general formula (I) according to which a compound of general formula (II) or the HCl adduct thereof is reacted with a phosgenating agent, wherein W represents oxygen or sulfur and Ar and A have the meanings as cited in Claim 1. The invention also relates to the use of phenyliso(thio)cyanates for producing plant protection products.