公开(公告)号：SK281068B6

公开(公告)日：2000-11-07

申请号：SK66797

申请日：1995-12-01

Applicant: BASF AG

Inventor： BASSLER PETER ,  KOPIETZ MICHAEL

IPC: B03B9/06 ,  C07D201/12 ,  C08J11/14

Abstract: Disclosed is a method of obtaining caprolactam from polymers containing caprolactam in the presence of superheated water. The proposed method is based on the use of polymers containing the repeating unit -[-N(H)-(CH2)5-C(O)-]- or mixtures consisting essentially of: a polymer containing the repeating unit -[-N(H)-(CH2)5-C(O)-]-; of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes; of organic and/or inorganic additives; of polymers which do not contain polyamide; of polyamides with the exception of polycaprolactam and copolyamides based on caprolactam. These polymers or mixtures are brought into contact with superheated water at a temperature of 280 - 320 C and at a pressure of 7.5 - 15 Mpa, the weight ratio of water to the polymer containing the repeating unit -[-N(H)-(CH2)5-C(O)-]- being between 5 : 1 and 13 : 1 and the reaction time less than 3 hours. The reaction mixture consisting essentially of water and the polymers or mixture indicated above should contain no gaseous phase under the conditions of hydrolysis. Also disclosed is an apparatus for making the same and the use of the said method and apparatus for recycling polycaprolactam-containing wastes.

公开(公告)号：ES2149514T3

公开(公告)日：2000-11-01

申请号：ES96943913

申请日：1996-12-11

Applicant: BASF AG

Inventor： ACHHAMMER GUNTHER ,  BASSLER PETER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  LUYKEN HERMANN ,  SCHNURR WERNER

IPC: C07C209/48 ,  C07C209/86 ,  C07C211/12 ,  C07D201/08

Abstract: PCT No. PCT/EP96/05521 Sec. 371 Date Jun. 16, 1998 Sec. 102(e) Date Jun. 16, 1998 PCT Filed Dec. 11, 1996 PCT Pub. No. WO97/23454 PCT Pub. Date Jul. 3, 1997Caprolactam and hexamethylenediamine are prepared simultaneously starting from adiponitrile.

公开(公告)号：ID25619A

公开(公告)日：2000-10-19

申请号：ID20001721

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A material useful as catalyst for the hydrogenation of alpha, omega-dinitriles comprises (a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.

公开(公告)号：CA2195574C

公开(公告)日：2000-10-10

申请号：CA2195574

申请日：1995-07-07

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  LINGELBACH PETER ,  BASSLER PETER ,  HARDER WOLFGANG ,  ELLER KARSTEN ,  KOHL VERONIKA ,  DEMBOWSKI JUERGEN ,  RIEBER NORBERT ,  FISCHER MARTIN

IPC: C07D301/06 ,  B01J23/40 ,  B01J29/04 ,  B01J29/74 ,  B01J29/76 ,  B01J29/89 ,  C01B15/029 ,  C07D301/04 ,  C07D301/12 ,  C07D303/04 ,  B01J37/02 ,  B01J29/076 ,  C08F8/08

Abstract: In an oxidation catalyst based an a titanium or vanadium silica-lite having a zeolite structure and containing from 0.01 to 20% by weight of one or more platinum metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum, the platinum metals are each present in at least two different bond energy states and preferably have no metal-metal bonds.

公开(公告)号：DE59605731D1

公开(公告)日：2000-09-14

申请号：DE59605731

申请日：1996-12-11

Applicant: BASF AG

Inventor： ACHHAMMER GUENTHER ,  BASSLER PETER ,  FISCHER ROLF ,  FUCHS EBERHARD ,  LUYKEN HERMANN ,  SCHNURR WERNER ,  VOIT GUIDO ,  HILPRECHT LUTZ

IPC: C07C209/48 ,  C07C209/86 ,  C07C211/12 ,  C07D201/08

Abstract: PCT No. PCT/EP96/05521 Sec. 371 Date Jun. 16, 1998 Sec. 102(e) Date Jun. 16, 1998 PCT Filed Dec. 11, 1996 PCT Pub. No. WO97/23454 PCT Pub. Date Jul. 3, 1997Caprolactam and hexamethylenediamine are prepared simultaneously starting from adiponitrile.

公开(公告)号：NO20004424L

公开(公告)日：2000-09-05

申请号：NO20004424

申请日：2000-09-05

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A material useful as catalyst for the hydrogenation of alpha, omega-dinitriles comprises (a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.

公开(公告)号：NO20004424A

公开(公告)日：2000-09-05

申请号：NO20004424

申请日：2000-09-05

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  B01J23/78

CPC classification number: C07C253/30 ,  B01J23/8892 ,  C07C209/48 ,  C07C211/12 ,  C07C255/24

公开(公告)号：CA2342177A1

公开(公告)日：2000-03-09

申请号：CA2342177

申请日：1999-08-17

Applicant: BASF AG

Inventor： MERGER MARTIN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  BASSLER PETER ,  REHFINGER ALWIN ,  ACHHAMMER GUNTHER ,  OHLBACH FRANK ,  VOIT GUIDO ,  FISCHER ROLF

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for simultaneous preparation of 6- aminocapronitrile and hexamethylene diamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the eight subgroup as catalytically active component to obtain a mixture containing 6-aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers; b) separating by distillation hexamethylene diamine from the mixture containing 6-aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers and c1) separating by distillation 6-aminocapronitrile and subsequently d1) separating by distillation adipodinitrile or c2) simultaneously separating by distillation 6- aminocapronitrile and adipodinitrile into separate fractions. The method is characterized in that the temperature of the bottom in steps d1) or c2) is below 185 ~ C.

公开(公告)号：CA2339710A1

公开(公告)日：2000-02-17

申请号：CA2339710

申请日：1999-08-09

Applicant: BASF AG

Inventor： WENZEL ANNE ,  HARDER WOLFGANG ,  BASSLER PETER ,  WALCH ANDREAS ,  RESCH PETER ,  ZEHNER PETER ,  RUPPEL WILHELM ,  RIEBER NORBERT ,  TELES JOAQUIM HENRIQUE

IPC: C07D301/19 ,  B01J20060101 ,  B01J8/04 ,  C07B20060101 ,  C07B33/00 ,  C07B41/00 ,  C07B61/00 ,  C07D20060101 ,  C07D301/03 ,  C07D301/12 ,  C07D303/04

Abstract: The invention relates to a method for reacting an organic compound with a hydroperoxide, comprising at least the following steps (i) to (iii): (i) reacting the hydroperoxide with the organic compound to obtain a mixture composed of a reacted organic compound and a non-reacted hydroperoxide; (ii) separating the non-reacted hydroperoxide from the mixture resulting in step (i); (iii) reacting the hydroperoxide separated in step (ii) with the organi c compound.

公开(公告)号：AU5029899A

公开(公告)日：2000-02-14

申请号：AU5029899

申请日：1999-07-02

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  OHLBACH FRANK ,  ANSMANN ANDREAS ,  BASSLER PETER ,  FISCHER ROLF ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  REHFINGER ALWIN DR ,  VOIT GUIDO ,  ACHHAMMER GUNTHER

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C209/86 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for simultaneous production of 6-aminocapronitrile and hexamethylenediamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the VIII subgroup thereby obtaining a mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers; b) distillative separation of hexamethylenediamine from the mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers or c1) distillative separating 6-aminocapronitrile and subsequently d1) distillative separation of adipodinitrile or c2) simultaneous distillative separation of 6-aminocapronitrile and adipodinitrile into separate fractions. The invention is characterized in that temperatures in the bottoms of the column in steps d1) or c2) are under 185 DEG C. The adipodinitrile thus obtained contains less impurities than for instance 1-amino-2-cyanocyclopentenes.