公开(公告)号：EP0249813A1

公开(公告)日：1987-12-23

申请号：EP87108081.8

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Knudsen, Christopher Glade

IPC: C07C225/20 ,  C07C217/14 ,  C07C239/14 ,  C07D295/10 ,  C07D277/04 ,  A01N35/06 ,  A01N41/10 ,  A01N43/78

CPC classification number: C07D295/116 ,  A01N35/06 ,  A01N37/44 ,  A01N41/10 ,  A01N43/78 ,  C07C255/00 ,  C07D277/04

Abstract: A compound of the formula
wherein R is halogen, C₁-C₂ alkyl, C₁-C₂ alkoxy, nitro; cyano; C₁-C₂ halo­alkyl, or R a SO n - wherein n is 0 or 2 and R a is C₁-C₂ alkyl; R¹ is hydrogen or C₁-C₄ alkyl; R² is hydrogen or C₁-C₄ alkyl; or R¹ and R² together are alkylene having 2 to 5 carbon atoms; R³ is hydrogen or C₁-C₄ alkyl; R⁴ is hydrogen or C₁-C₄ alkyl; or R³ and R⁴ are oxo; R⁵ is hydrogen or C₁-C₄ alkyl; R⁶ is hydrogen or C₁-C₄ alkyl; and R⁷ and R⁸ independently are (1) hydrogen; (2) halogen; (3) C₁-C₄ alkyl; (4) C₁-C₄ alkoxy; (5) trifluoro­methoxy; (6) cyano; (7) nitro; (8) C₁-C₄ haloalkyl; (9) R b SO n - wherein n is the integer 0, 1 or 2; and R b is (a) C₁-C₄ alkyl; (b) C₁-C₄ alkyl sub­stituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C₁-C₄ alkyl; (11) R e C(O)-­wherein R e is C₁-C₄ alkyl or C₁-C₄ alkoxy; (12) SO₂NR c R d wherein R c and R d are as defined; or (13) -N(R c )C(O)R d wherein R c and R d are as defined; R⁹ is hydrogen or C₁-C₄ alkyl, R¹⁰ is (a) hydrogen; (b) C₁-C₆ alkyl, (c) C₄-C₆ cycloalkyl, (d) substituted C₁-C₆ alkyl, (e) phenyl; (f) substituted phenyl; (g) C₁-C₆ alkoxy; (h) benzyl; (i) phenethyl; (j) C₁-C₄ alkyl-C(O)-; (k) C₁-C₄ alkoxy-C(O)-; (l) C₂-C₆ alkenyl; or (m) C₂-C₆ alkynyl; and R⁹ and R¹⁰ together form a heterocyclic ring with the nitro­gen to which they are attached containing 0, 1 or 2 additional hetero atoms (nitrogen, sulfur or oxygen).

Abstract translation: 式CHEM的化合物，其中R是卤素，C 1 -C 2烷基，C 1 -C 2烷氧基，硝基; 氰基; C 1 -C 2卤代烷基或R a SO n - ，其中n为0或2，R a为C 1 -C 2烷基; R 1是氢或C 1 -C 4烷基; R 2是氢或C 1 -C 4烷基; 或R 1和R 2一起是具有2至5个碳原子的亚烷基; R 3是氢或C 1 -C 4烷基; R 4是氢或C 1 -C 4烷基; 或R 3和R 4是氧代; R 5是氢或C 1 -C 4烷基; R 6是氢或C 1 -C 4烷基; 和R 7和R 8独立地是（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C1-C4烷氧基; （5）三氟甲氧基; （6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）R bnn-其中n是整数0,1或2; 和R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NR c R d其中R c和R d独立地是氢或C 1 -C 4烷基; （11）R e（O） - 其中R e是C 1 -C 4烷基或C 1 -C 4烷氧基; （12）SO 2 NR c R d其中R c和R d如所定义; 或（13）-N（R c）C（O）R d，其中R c和R d如定义; R 9是氢或C 1 -C 4烷基，R 1是（a）氢; （b）C 1 -C 6烷基，（c）C 4 -C 6环烷基，（d）取代的C 1 -C 6烷基，（e）苯基; （f）取代的苯基; （g）C1-C6烷氧基; （h）苄基; （i）苯乙基; （j）C 1 -C 4烷基-C（O） - ; （k）C1-C4烷氧基-C（O） - ; （1）C 2 -C 6烯基; 或（m）C 2 -C 6炔基; 并且R 9和R 1一起形成与它们相连的氮含有0,1或2个另外的杂原子（氮，硫或氧）的杂环。

公开(公告)号：EP0249257A1

公开(公告)日：1987-12-16

申请号：EP87200684.6

申请日：1987-04-13

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Leone-Bay, Andrea ,  Bay, William Elliot ,  Timony, Peter Edward

IPC: C07C17/22 ,  C07C25/06 ,  C07C25/08 ,  C07C25/10 ,  C07C25/13 ,  C07C25/22 ,  C07C41/22 ,  C07D213/61 ,  C07D239/30

CPC classification number: C07D239/30 ,  C07B39/00 ,  C07C17/093 ,  C07C41/22 ,  C07D213/61 ,  C07C43/225

Abstract: A process for selectively substituting an aromatic nitro group with a halo group which comprises contacting the nitroaromatic compound with a phosphorushalide of formula: R n PX 5-n wherein n is selected from 0, 1, and 3; R is selected from the group consisting of C-6 to C-10 aryl and substituted aryl wherein the substituents are selected from the group consisting of: straight and branched chain alkyl, alkoxy, and haloalkyl; halogen, sulfonate and mixtures thereof; and X is a halogen in the presence of an arylphosphorusoxydihalide solvent. The use of an arylphosphorustetrahalide and particularly phenylphosphorustetrachloride is preferred. The arylphosphorustetrahalide can be prepared in situ by contacting a solution of the corresponding arylphosphorusdihalide in an arylphosphorusoxydihalide solvent with a halogen. The process can further comprise the step of heating the reaction mixture to maintain a temperature of from about 100°C to about 175°C for from about 1 hour to about 24 hours.

Abstract translation: 一种选择性地用卤素取代芳族硝基的方法，该方法包括使硝基芳族化合物与式RnPX5-n的三卤化磷接触，其中n选自0,1和3; R选自C-6至C-10芳基和取代的芳基，其中取代基选自：直链和支链烷基，烷氧基和卤代烷基; 卤素，磺酸酯及其混合物; X是在芳基磷氧基二卤化物溶剂存在下的卤素。 使用芳基四卤化磷，特别是苯基四氯化磷是优选的。 芳基四卤化磷可通过使相应的芳基二卤化物在芳基磷氧基二卤化物溶剂中的溶液与卤素接触而原位制备。 该方法可以进一步包括加热反应混合物以保持约100℃至约175℃的温度约1小时至约24小时的步骤。

公开(公告)号：EP0249149A1

公开(公告)日：1987-12-16

申请号：EP87108079.2

申请日：1987-06-04

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Curtis, Jeff Kimo

IPC: C07D211/86 ,  C07D213/69 ,  C07D207/38 ,  A01N43/40 ,  A01N43/36

CPC classification number: C07D213/69 ,  A01N43/36 ,  A01N43/40 ,  C07D211/86 ,  C07D221/20

Abstract: Compounds having the formula
wherein R is halogen; C₁-C₂ alkyl; C₁-C₂ alkoxy; nitro; cyano; C₁-C₂ halo­alkyl; or R a SO n - wherein n is 0 or 2 and R a is C₁-C₂ alkyl; R¹ is hydrogen or C₁-C₄ alkyl; R² is hydrogen or C₁-C₄ alkyl; or R¹ and R² together are alkylene having 2-5 carbon atoms; R³ is hydrogen or C₁-C₄ alkyl; R⁴ is hydrogen or C₁-C₄ alkyl; or R³ and R⁴ together are carbonyl; and R⁵ and R⁶ independently are (1) hydrogen; (2) halogen; (3) C₁-C₄ alkyl; (4) C₁-C₄ alkoxy; (5) trifluoromethoxy; (6) cyano; (7) nitro; (8) C₁-C₄ haloalkyl; (9) R b SO m - wherein m is the integer 0, 1 or 2; and R b is (a) C₁-C₄ alkyl; (b) C₁-C₄ alkyl substituted with halogen or cyano; (c) phenyl; or (d) benzyl; (10) -NR c R d wherein R c and R d independently are hydrogen or C₁-C₄ alkyl; (11) R e C(O)- wherein R e is C₁-C₄ alkyl or C₁-C₄ alkyl or C₁-C₄ alkoxy; or (12) -SO₂NR c R d wherein R c and R d are as defined; and (13) -N(R c )C(O)R d wherein R c and R d are as defined; R⁷ is C₁-C₄ alkyl or phenyl; and t is the integer 0 or 1 and their salts are useful as herbicides.

Abstract translation: 具有式CHEM的化合物，其中R是卤素; C1-C2烷基; C1-C2烷氧基; 硝基; 氰基; C 1 -C 2卤代烷基; 或R a SO n - ，其中n为0或2，R a为C 1 -C 2烷基; R 1是氢或C 1 -C 4烷基; R 2是氢或C 1 -C 4烷基; 或R 1和R 2一起是具有2-5个碳原子的亚烷基; R 3是氢或C 1 -C 4烷基; R 4是氢或C 1 -C 4烷基; 或R 3和R 4一起是羰基; 和R 5和R 6独立地是（1）氢; （2）卤素; （3）C 1 -C 4烷基; （4）C1-C4烷氧基; （5）三氟甲氧基; （6）氰基; （7）硝基; （8）C 1 -C 4卤代烷基; （9）R b SO m - 其中m是整数0,1或2; 和R b是（a）C 1 -C 4烷基; （b）被卤素或氰基取代的C 1 -C 4烷基; （c）苯基; 或（d）苄基; （10）-NR c R d其中R c和R d独立地是氢或C 1 -C 4烷基; （11）R e（O） - 其中R e是C 1 -C 4烷基或C 1 -C 4烷基或C 1 -C 4烷氧基; 或（12）-SO 2 NR c R d其中R c和R d如定义; 和（13）-N（R c）C（O）R d，其中R c和R d如定义; R 7是C 1 -C 4烷基或苯基; 且t为0或1的整数，并且它们的盐可用作除草剂。

公开(公告)号：EP0243972A2

公开(公告)日：1987-11-04

申请号：EP87106297.2

申请日：1987-04-30

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Baker, Don Robert ,  Brownell, Keith Harvey ,  Kezerian, Charles

IPC: C07D213/82 ,  C07D405/12 ,  A01N53/00

CPC classification number: C07D213/75 ,  A01N53/00 ,  C07D213/76 ,  C07D405/12 ,  C07F7/10

Abstract: Novel fungicidal pyridyl cyclopropane carboxamides having the general structural formula
wherein Z is
R is selected from the group consisting of cycloalkyl, preferably cyclopropyl, hydrogen, alkyl, haloalkyl, substituted alkyl, aryl, substituted aryl, heteroalkyl, alkenyl, OR 1 , SR, and
wherein n is 0-10, preferably 0-2, ad R 1 is C 1 -C 4 alkyl; R 2 is selected from the group consisting of halogen such as chlorine, fluorine and bromine, preferably chlorine, C 1 -C 3 alkoxy such as propoxy ethoxy and methoxy, preferably methoxy and C 1 -C 3 haloalkoxy; R 3 is selected from the group consisting of hydrogen and methyl; X is oxygen or sulfur and Y is oxygen or sulfur; or Z is SR 9 wherein R 9 is selected from the group consisting of haloalkyl, preferably C 1 -C 3 haloalkyl, C 1 -C 8 alkyl, aryl, substituted aryl, and arylalkyl wherein the preferred aryl is phenyl, the alkyl is C 1 -C 3 alkyl and the preferred substitutions are Cl, Br, F and nitro, alkanoyl, preferably C 1 -C 4 alkanoyl,
wherein R 4 and R 5 can be alkyl, alkanoyl, alkoxycarbonyl, benzyl, pyridyl and substituted pyridyl; provided that when Z is -SR 9 Y is oxygen; and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.

Abstract translation: 具有通式结构式的新型杀真菌吡啶基环丙烷甲酰胺，其中Z为-R; R选自环烷基，优选环丙基，氢，烷基，卤代烷基，取代的烷基，芳基，取代的芳基，杂烷基，烯基，OR 1，SR 1和 - （CH 2）n R OR 1，其中n为0-10， 优选0-2，并且R 1是C 1 -C 4烷基; R 2选自卤素如氯，氟和溴，优选氯，C 1 -C 3烷氧基如丙氧基乙氧基和甲氧基，优选甲氧基和C 1 -C 3卤代烷氧基; R3选自氢和甲基; X是氧或硫，Y是氧或硫; 或Z是SR 9，其中R 9选自卤代烷基，优选C 1 -C 3卤代烷基，C 1 -C 8烷基，芳基，取代的芳基和芳烷基，其中优选的芳基是苯基，所述烷基是C 1 -C 3烷基，优选的 取代基是Cl，Br，F和硝基，烷酰基，优选C 1 -C 4烷酰基，其中R 4和R 5可以是烷基，烷酰基，烷氧基羰基，苄基，吡啶基和取代的吡啶基; 条件是当Z为-SR 9时，Y为氧; 及其杀真菌可接受的有机和无机盐，它们是用作预防和治疗性杀真菌剂的高效杀真菌剂。

公开(公告)号：EP0171157A3

公开(公告)日：1987-09-30

申请号：EP85304482

申请日：1985-06-24

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： DiSalvo, Anthony Leonard ,  Kim, Ki-Soo

IPC: C08J03/16 ,  H01B01/20

CPC classification number: H01B1/24 ,  C08G59/145 ,  C08L79/08 ,  C09J163/00 ,  H01B1/20 ,  H01B1/22 ,  H05K3/321 ,  H05K3/386

Abstract: Adhesive compositions are disclosed which comprise: (a) an epoxy resin; (b) a soluble polyimide resin; and (c) a monoepoxy diluent. Such compositions are curable by using conventional epoxy curing agent(s). Conductive adhesives of this type can be formed by blending the composition with a conductive filler component.

公开(公告)号：EP0232262A1

公开(公告)日：1987-08-19

申请号：EP85904319.0

申请日：1985-08-15

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： MASCARENHAS, Desmond

IPC: C12N15 ,  C12P13

CPC classification number: C12N15/52 ,  C12P13/227

Abstract: Microorganismes d'Escherichia coli véhiculant des informations génétiques portées par les plasmides et relatives à la production de L-tryptophane, et procédés permettant de produire ou d'accroître la production de L-tryptophane par fermentation.

公开(公告)号：EP0186117A3

公开(公告)日：1987-06-16

申请号：EP85116161

申请日：1985-12-18

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Heather, James Brian ,  Milano, Pamela Denise

IPC: C07C45/54 ,  C07C49/813 ,  C07C45/46 ,  C07C49/403 ,  C07C79/36 ,  C07C121/76 ,  C07C120/00 ,  C07C67/14 ,  C07C149/32

CPC classification number: C07C201/12 ,  C07C45/455 ,  C07C45/54 ,  C07C253/30 ,  C07C319/20 ,  C07C49/403 ,  C07C49/83 ,  C07C205/45 ,  C07C255/56 ,  C07C323/22

Abstract: An acylated diketonic compound is produced by rearrangement of the corresponding enol ester in the presence of a cyanide source. In one embodiment the cyanide source is employed with a molar excess of a moderate base, with respect to the enol ester. In another embodiment, the cyanide source is a stoichiometric amount, with respect to the enol ester, of potassium or lithium cyanide and a catalytic amount of a Crown ether is used.

公开(公告)号：EP0222460A1

公开(公告)日：1987-05-20

申请号：EP86201980.9

申请日：1986-11-11

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Epstein, Ronald Alan

IPC: C07C51/10 ,  C07C67/36 ,  C07C69/614 ,  C07C43/164

CPC classification number: C07C51/10

Abstract: High yields of aromatic, aromatic acetic and olefinic acids, esters, amides and the like are derived from a pro­cess wherein a halo-hydrocarbon is carbonylated in the pres­ence of a palladium catalyst, a hindered amine base and phosphine in excess. The hindered amine base can comprise C₃-C₁₀ branched alkyls, cyclic compounds, or mixtures of the above. The preferred amine is N,N-diisopropylethyl amine. The preferred catalyst is PdCl₂(PPH₃)₂ with the excess phos­phine generally supplied by a compound of the formula PR¹R²R³ where R¹,R² and R³ are preferably phenyl.

公开(公告)号：EP0153790A3

公开(公告)日：1987-05-20

申请号：EP85200262

申请日：1985-02-26

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Jacobs, Barry Alan ,  Fesman, Gerald

IPC: C08J09/00 ,  C08J09/02 ,  C08J09/14 ,  B68G05/00 ,  C08L75/06

CPC classification number: C08J9/143 ,  A61F2013/15341 ,  A61G7/057 ,  A61L15/425 ,  C08J9/0014 ,  C08J2375/06

Abstract: A polyester polyurethane foam formulation useful in medical pads to support bedridden patients is described. The foam is formed by reaction of a polyester polyol, isocyanate and blowing agent combination of water and halogenated hydrocarbon auxiliary blowing agent. A halogenated flame retardant, e.g., an organophosphorus compound, is present. A liquid char forming and dripping ember retardant additive is also present.

公开(公告)号：EP0220902A2

公开(公告)日：1987-05-06

申请号：EP86308108.9

申请日：1986-10-20

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Chan, Jimmy Hua-Hin ,  Burval, Jan

IPC: A01N57/20 ,  A01N25/30

CPC classification number: A01N57/20 ,  A01N25/30 ,  A01N25/04 ,  A01N25/02 ,  A01N2300/00

Abstract: A liquid phytoactive composition characterised in that it comprises:

(a) an N-phosphonomethyl-N-carboxymethyl compound;
(b) one or more liquid nonionic surfanctants;
(c) a dispersing medium for the said N-phosphonomethyl-N-carboxymethyl compound; and
(d) one or more inert adjuvants is disclosed.
A liquid herbicidal concentrate characterised in that it comprises:
(a) an herbicidally effective N-phosphonomethyl-N-carboxymethyl compound
(b) one or more liquid nonionic surfactants;
(c) a solvent for the said N-phosphonomethyl-N-carboxymethyl compound; and
(d) one or more inert adjuvants is also disclosed.

The formulation of this invention has the advantage that it can contain a high amount of active ingredient, is thermally stable over a wide temperature range, is compatible with and dilutable in both hard and soft water, and is also compatible and dilutable with a nitrogeneous fertilizer solution, and is minimally irritable to the eyes. Also, the formulation of this invention is stable upon aging over months of storage, over a wide temperature range. In addition, the nonionic surfactants are derived from naturally occurring products and are readily broken down by microorganisms.

Abstract translation: 一种液体植物活性组合物，其特征在于它包含： （a）N-膦酰基甲基-N-羧甲基化合物; （b）一种或多种液体非离子表面活性剂; （c）所述N-膦酰基甲基-N-羧甲基化合物的分散介质; 和（d）公开了一种或多种惰性佐剂。 一种液体除草浓缩物，其特征在于其包含：（a）除草有效的N-膦酰基甲基-N-羧甲基化合物（b）一种或多种液体非离子表面活性剂; （c）所述N-膦酰基甲基-N-羧甲基化合物的溶剂; 和（d）还公开了一种或多种惰性佐剂。 本发明的配方具有以下优点：它可以含有大量的活性成分，在宽的温度范围内是热稳定的，与硬水和软水相容并且可稀释，并且也可与氮肥混合 解决方案，并且对眼睛微不足道。 此外，本发明的制剂在几个月的储存下，在宽的温度范围内是老化的。 此外，非离子表面活性剂衍生自天然产物并易于被微生物分解。