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公开(公告)号:AT209620T
公开(公告)日:2001-12-15
申请号:AT97907075
申请日:1997-03-06
Applicant: BASF AG
Inventor: EICKEN KARL , GEBHARDT JOACHIM , RANG HARALD , RACK MICHAEL , SCHAEFER PETER
IPC: B01J31/24 , C07B37/04 , C07B61/00 , C07C201/12 , C07C205/06 , C07C205/11 , C07C205/12 , C07C205/35 , C07C253/30
Abstract: The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R meaning C1-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.
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公开(公告)号:PL344332A1
公开(公告)日:2001-11-05
申请号:PL34433299
申请日:1999-05-04
Applicant: BASF AG
Inventor: RHEINHEIMER JOACHIM , VON DEYN WOLFGANG , GEBHARDT JOACHIM , RACK MICHAEL , LOCHTMAN RENE , GOETZ NORBERT , KEIL MICHAEL , WITSCHEL MATTHIAS , HAGEN HELMUT , MISSLITZ ULF , BAUMANN ERNST
IPC: C07C20060101 , C07C201/12 , C07C205/44 , C07C249/06 , C07C251/48 , C07C251/52 , C07C253/00 , C07C255/50 , C07C317/32 , C07C319/14 , C07C323/09 , C07D20060101 , C07D261/02 , C07D261/04 , C07D261/08 , C07D413/02 , C07D413/10 , C07C251/40
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公开(公告)号:GEP20022617B
公开(公告)日:2001-10-10
申请号:GEAP1998003650
申请日:1998-01-08
Applicant: BASF AG
Inventor: OTTEN MARTINA , WESTPHALEN KARL-OTTO , VON DEYN WOLFGANG , HILL REGINA LUISE , MAYER GUIDO , WITSCHEL MATTHIAS , MISSLITZ ULF , KARDORFF UWE , BAUMANN ERNST , ENGEL STEFAN , RACK MICHAEL , GőTZ NORBERT , GEBHARDT JOACHIM , WALTER HELMUT , RHEINHEIMER JOACHIM
IPC: C07D277/10 , C07D413/10 , A01N43/72 , A01N43/76 , A01N43/78 , A01N43/80 , C07D231/20 , C07D237/00 , C07D261/00 , C07D261/04 , C07D261/20 , C07D263/10 , C07D273/00 , C07D277/20 , C07D277/34 , C07D291/04 , C07D311/00 , C07D403/10 , C07D417/10 , C07D419/10 , C07D498/10
Abstract: 1. Technical Result Increase in herbicidal efficiency. 2. Essence A composition of the formula (values of R1, R2, R3, R4, R5 and R6, are defined in the specification), method for their production, a herbicidal means comprised therein and method for undesirable plants control. 3. Field of Application Agriculture. Tables: 4
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公开(公告)号:SK16872000A3
公开(公告)日:2001-06-11
申请号:SK16872000
申请日:1999-05-04
Applicant: BASF AG
Inventor: RHEINHEIMER JOACHIM , VON DEYN WOLFGANG , GEBHARDT JOACHIM , RACK MICHAEL , LOCHTMAN RENE , GOTZ NORBERT , KEIL MICHAEL , WITSCHEL MATTHIAS , HAGEN HELMUT , MISSLITZ ULF , BAUMANN ERNST
IPC: C07C20060101 , C07C201/12 , C07C205/44 , C07C249/06 , C07C251/48 , C07C251/52 , C07C253/00 , C07C255/50 , C07C317/32 , C07C319/14 , C07C323/09 , C07D20060101 , C07D261/02 , C07D261/04 , C07D261/08 , C07D413/02 , C07D413/10 , C07C251/40
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公开(公告)号:CA2351466A1
公开(公告)日:2000-05-25
申请号:CA2351466
申请日:1999-11-17
Applicant: BASF AG
Inventor: RACK MICHAEL , HAGEN HELMUT , GOTZ NORBERT , BAUMANN ERNST , GEBHARDT JOACHIM , LOCHTMAN RENE , VON DEYN WOLFGANG
IPC: C07D261/04
Abstract: The invention relates to a novel method of producing the compounds of formul a (I) wherein the substituents have the following meanings: n is 0,1 or 2; R1, R2 represent C1-C6-alkyl; R3, R4, R5 are hydrogen, C1-C6-alkyl or R4 and R5 together form a bond; R6 is C1, Br. Said method comprises the following step s: a synthesis sequence starting from 1,2-dialkylbenzenes of formula (II); halogenation to form 3,6-dihalogen-1,2-dialkylbenzenes; haloalkylation to fo rm benzyl bromides; oxidation to form benzaldehydes; reaction with alkenes to form isoxazoles; reaction to form thioethers and optionally oxidation to for m sulfenyl or sulfonyl derivatives of formula (I).
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公开(公告)号:AU713547B2
公开(公告)日:1999-12-02
申请号:AU1925797
申请日:1997-03-06
Applicant: BASF AG
Inventor: EICKEN KARL , GEBHARDT JOACHIM , RANG HARALD , RACK MICHAEL , SCHAFER PETER
IPC: B01J31/24 , C07B37/04 , C07B61/00 , C07C201/12 , C07C205/06 , C07C205/11 , C07C205/12 , C07C205/35 , C07C253/30
Abstract: The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R meaning C1-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.
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公开(公告)号:DE19820722C1
公开(公告)日:1999-11-04
申请号:DE19820722
申请日:1998-05-11
Applicant: BASF AG
Inventor: RHEINHEIMER JOACHIM , DEYN WOLFGANG VON , GEBHARDT JOACHIM
IPC: C07C20060101 , C07D20060101 , C07D413/10
Abstract: Preparation of 4-(4-alkylsulfonyl-3-isoxazolyl- benzoyl)-5-hydroxypyrazole derivatives (I) involves reacting a hydroxypyrazole (II) with a bromobenzene (III) in presence of carbon monoxide, a palladium catalyst, a potassium salt and an amine. Preparation of benzoylpyrazole derivatives of formula (I) comprises reacting a hydroxypyrazole compound of formula (II) with a bromobenzene of formula (III) in the presence of carbon monoxide, a palladium catalyst, one or more equivalents of a potassium salt and one or more equivalents of a tertiary amine of formula N(Ra)3 (IV). Reaction is at 0-40 kg/cm and 100-140 deg C. R , R = 1-4C alkyl; R = Cl or CH3; R = H or 1-4C alkyl; M = H or alkali metal; Ra = 1-6C alkyl, or one can be phenyl or naphthyl; the isoxazole or isoxazoline residue is bonded in the 3- or 5-position.
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公开(公告)号:NO993521D0
公开(公告)日:1999-07-16
申请号:NO993521
申请日:1999-07-16
Applicant: BASF AG
Inventor: DEYN WOLFGANG VON , HILL REGINA LUISE , KARDORFF UWE , BAUMANN ERNST , ENGEL STEFAN , MAYER GUIDO , WITSCHEL MATTHIAS , RACK MICHAEL , GOETZ NORBERT , GEBHARDT JOACHIM , MISSLITZ ULF , WALTER HELMUT , WESTPHALEN KARL-OTTO , OTTEN MARTINA , RHEINHEIMER JOACHIM
IPC: C07D277/10 , A01N43/72 , A01N43/76 , A01N43/78 , A01N43/80 , C07D231/20 , C07D237/00 , C07D261/00 , C07D261/04 , C07D261/20 , C07D263/10 , C07D273/00 , C07D277/20 , C07D277/34 , C07D291/04 , C07D311/00 , C07D403/10 , C07D413/10 , C07D417/10 , C07D419/10 , C07D498/10 , C07D
Abstract: Benzoyl derivatives of the formula I where the variables have the following meanings: R1, R2 are hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl or C1-C6-haloalkylsulfonyl; R3 is hydrogen, halogen or alkyl; R4, R5 are hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, it being possible for the 6 last-mentioned radicals to be substituted; X is O, S, NR9, CO or CR10R11; Y is O, S, NR12, CO or CR13R14; R15 is pyrazole which is unsubstituted or substituted, linked in the 4-position and has attached to it in the 5-position a hydroxyl or sulfonyloxy radical; and the agriculturally useful salts thereof; processes and intermediates for the preparation of the 3-heterocyclyl-substituted benzoyl derivatives; compositions comprising them; and the use of these derivatives or compositions comprising them for controlling undesirable plants.
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公开(公告)号:PL328663A1
公开(公告)日:1999-02-15
申请号:PL32866397
申请日:1997-03-06
Applicant: BASF AG
Inventor: EICKEN KARL , GEBHARDT JOACHIM , RANG HARALD , RACK MICHAEL , SCHAEFER PETER
IPC: B01J31/24 , C07B37/04 , C07B61/00 , C07C201/12 , C07C205/06 , C07C205/11 , C07C205/12 , C07C205/35 , C07C253/30
Abstract: The invention concerns a process for preparing nitrobiphenylene of formula (I) wherein m stands for 1 or 2, R means halogen, R' or OR', R' being a C-organic group which can carry groups which are inert in the reaction conditions, n stands for 0, 1, 2 or 3 and, if n is 2 or 3, the R groups can also be different. According to the invention, a chloronitrobenzene of formula (II) is reacted in the presence of a palladium catalyst and a base in a solvent with a phenyl boric acid (IIIa), one of its alkyl esters of formula (IIIb), R meaning C1-C6 alkyl, or one of its anhydrides. The compounds (I) are suitable as initial products for biphenylamines which are in turn intermediate products for fungicidal plant-growth substances.
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公开(公告)号:CA2278331A1
公开(公告)日:1998-07-23
申请号:CA2278331
申请日:1998-01-08
Applicant: BASF AG
Inventor: BAUMANN ERNST , OTTEN MARTINA , ENGEL STEFAN , VON DEYN WOLFGANG , WESTPHALEN KARL-OTTO , KARDORFF UWE , HILL REGINA LUISE , WALTER HELMUT , RHEINHEIMER JOACHIM , WITSCHEL MATTHIAS , MAYER GUIDO , MISSLITZ ULF , RACK MICHAEL , GOETZ NORBERT , GEBHARDT JOACHIM
IPC: C07D277/10 , A01N43/72 , A01N43/76 , A01N43/78 , A01N43/80 , C07D231/20 , C07D237/00 , C07D261/00 , C07D261/04 , C07D261/20 , C07D263/10 , C07D273/00 , C07D277/20 , C07D277/34 , C07D291/04 , C07D311/00 , C07D403/10 , C07D413/10 , C07D417/10 , C07D419/10 , C07D498/10
Abstract: The invention concerns benzoyl derivatives of formula (I) in which the variables have the following meanings: R1, R2: hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkylthio halide, alkylsulphinyl, alkylsulphinyl halide, alkylsulphonyl, or C1-C6 alkylsulphonyl halide; R3: hydrogen, halogen or alkyl; R4, R5: hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the six last-mentioned groups can be substituted; X: O, S, NR9, CO or CR10R11; Y: O, S, NR12, CO or CR13R14; R15: optionally substituted pyrazole which is bonded in position 4 and carries a hydroxy or sulphonyloxy group in position 5. The invention also concerns: the salts of these 3heterocyclyl-substituted benzoyl derivatives which can be used for agricultural purposes; processes and intermediate products for preparing these substances; agents containing them; and the use as herbicides of these derivatives or agents containing them.
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