公开(公告)号：DE19650958A1

公开(公告)日：1998-06-10

申请号：DE19650958

申请日：1996-12-07

Applicant: BASF AG

Inventor： GRUND CLEMENS DR ,  REICHELT HELMUT DR ,  SCHMIDT ANDREAS JOHANN DR ,  WUERTHNER FRANK DR ,  SENS RUEDIGER DR ,  BECKMANN STEFAN DR

IPC: B41M5/385 ,  C09B23/10 ,  D06P1/16 ,  D06P5/00 ,  D06P5/13 ,  G03G9/09 ,  A61K7/13 ,  B41M5/30

Abstract: Indolenine methine dyes of formula (I), i.e. 4- (3,3 -dimethyl indolenine)-5- (3-cyano- 4-trifluoro methyl- tetrahydro pyridin-2,6- dione)- dimethine merocyanine derivative. In (I), ring A may be substituted; R1 = H, (substituted) 1-13 C alkyl (optionally with 1-4 ether oxygen (O) atoms in the chain), 3-4 C alkenyl, 5-7 C cycloalkyl or (substituted) phenyl; R2 = (substituted) 1-13 C alkyl (optionally with 1-4 ether O atoms in the chain), 3-4 C alkenyl, (substituted) phenyl or NE E ; E , E = H, (substituted) 1-13 C alkyl (optionally with 1-4 ether O atoms in the chain), 5-7 C cycloalkyl, 1-13 C alkoxy carbonyl, 5-7 C cycloalkyl sulphonyl, pyridyl carbonyl, thienyl carbonyl or a (substituted) phenyl, pyridyl, 1-13 C alkanoyl, 1-13 C alkyl sulphonyl, phenyl sulphonyl, pyridyl sulphonyl or benzoyl; or NE E = succinimido or phthalimido (optionally substituted by 1-4 C alkyl) or a 5-6-membered saturated heterocyclic, optionally containing other hetero-atom(s).

公开(公告)号：DE19648564A1

公开(公告)日：1998-05-28

申请号：DE19648564

申请日：1996-11-23

Applicant: BASF AG

Inventor： GRUND CLEMENS DR ,  REICHELT HELMUT DR ,  SCHMIDT ANDREAS JOHANN DR ,  WUERTHNER FRANK DR ,  SENS RUEDIGER DR ,  BECKMANN STEFAN DR

IPC: C07D401/06 ,  C09B23/10 ,  D01F6/62 ,  D06P1/16

Abstract: Novel indolenine methine dyes of formula (I) are claimed, in which ring A may be substituted; R = hydrogen (H), (substituted) 1-13C alkyl (optionally with 1-4 ether oxygen (O) atoms in the chain), 3-4C alkenyl, 5-7C cycloalkyl or (substituted) phenyl; R = (substituted) 1-13C alkyl (optionally with 1-4 ether O atoms in the chain), 3-4C alkenyl, (substituted) phenyl or NE E ; E , E = H, (substituted) 1-13C alkyl (optionally with 1-4 ether O atoms in the chain), 3-4C alkenyl, 1-13C alkoxycarbonyl, 5-7C cycloalkyl-sulphonyl, pyridylcarbonyl, thienylcarbonyl or a (substituted) phenyl, pyridyl, 1-13C alkanoyl, 1-13C alkylsulphonyl, phenylsulphonyl, pyridylsulphonyl or benzoyl group; or NE E = a succinimido or phthalimido group, optionally substituted by 1-4C alkyl, or a 5-6-membered heterocyclic group, optionally containing other hetero-atoms.

公开(公告)号：DE19618528A1

公开(公告)日：1997-11-13

申请号：DE19618528

申请日：1996-05-08

Applicant: BASF AG

Inventor： GRUND CLEMENS DR ,  REICHELT HELMUT DR ,  SCHMIDT ANDREAS JOHANN DR ,  BECKMANN STEFAN DR

IPC: C07D213/85 ,  B41M5/34 ,  B41M5/385 ,  B41M5/39 ,  C07D211/68 ,  C07D213/69 ,  C07D277/42 ,  C07D401/00 ,  C07D401/02 ,  C07D401/06 ,  C07D409/02 ,  C07D413/00 ,  C07D413/02 ,  C07D417/06 ,  C09B23/00 ,  C09B23/01 ,  C09B23/06 ,  C09B23/16 ,  C09B55/00 ,  D06P1/00 ,  D06P1/16 ,  D06P3/30 ,  D06P3/32 ,  D06P5/13

Abstract: - Trifluoro-methylpyridone methine or azamethine dyes of formula (I) and their salts are new; in which X = nitrogen (N) or methine (CH); R = an optionally substituted carbo- or hetero-cyclic group, optionally with an anellated optionally substituted aryl group, with orbitals capable of conjugation; R = cyano (CN), carbamoyl, carboxy, alkoxycarbonyl or alkanoyl; R = (a) alkyl, optionally with 1, 2 or 3 substituents selected from alkylaminocarbonyloxy, alkoxycarbonyl or alkoxycarbonyloxy group (in which the alkyl groups may have 1, 2 or 3 ether oxygen (O) atoms in the chain and may be substituted by phenyl or phenoxy), alkanoyloxy, cycloalkyl (optionally with 1-5 alkyl substituents), aryl (optionally with 1-3 substituents selected from alkyl, alkoxy, halogen, nitro and carboxyl), cycloalkoxy, phenoxy, halogen, alkoxy, hydroxyl or CN and/or 1-3 ether O atoms in the chain; (b) cycloalkyl, optionally with 1-5 alkyl substituents; (c) aryl, optionally with 1-3 alkyl, alkoxy, halogen, nitro or carboxyl substituents; or NE E ; in which E , E = as R (except NE E ) or pyridyl (optionally with 1-3 alkyl, alkoxy, halogen, nitro or carboxyl substituents), alkanoyl, alkoxycarbonyl, alkylsulphonyl, cycloalkyl sulphonyl, pyridylcarbonyl, thienylcarbonyl or an optionally substituted phenylsulphonyl, pyridylsulphonyl or benzoyl group; or NE E = succinimido (optionally mono- or di-substituted by alkyl), phthalimido (optionally mono- or di-substituted by 1-4 C alkyl) or a 5-6-membered saturated heterocyclic group (optionally with alkyl substituent(s) and/or with 1 or 2 other hetero-atoms selected from O, N and sulphur (S). Also claimed are colourants containing dye(s) (I).

公开(公告)号：DE4433073A1

公开(公告)日：1996-03-21

申请号：DE4433073

申请日：1994-09-16

Applicant: BASF AG

Inventor： HARTMANN HORST PROF DR ,  FLAIG RONALD ,  BECKMANN STEFAN DR

IPC: C07D277/38 ,  C07D277/42

Abstract: Prepn. of 2,4-di-(dialkylamino, diphenylamino and/or cyclic amino)-thiazoles of formula (I) or their acid addn. salts comprises reacting a haloacetamide of formula R COCH2Hal (II) with a thiourea of formula H2NCSR (III) in presence of an (in)organic acid halide in an organic diluent at 0-70 deg C, then treating with mineral acid at 0-70 deg C. R (same or different) = a (a) 1-10C dialkylamino (where the alkyl gps. are opt. interrupted by 1-3 ether O), (b) diphenylamino or (c) a 5- or 6-membered satd. heterocycle, contg. a ring N and opt. a further N or O heteroatom, bonded to the thiazole ring via N; Hal = halo.

公开(公告)号：DE4429548A1

公开(公告)日：1996-02-22

申请号：DE4429548

申请日：1994-08-19

Applicant: BASF AG

Inventor： GRUND CLEMENS DR ,  SCHEFCZIK ERNST DR ,  LAMM GUNTHER DR ,  MERGER ROLAND DR ,  SENS RUEDIGER DR ,  BECKMANN STEFAN DR

IPC: C07D401/04 ,  C07D495/04 ,  C07D495/06 ,  C09B57/00 ,  C09B57/06 ,  C07D495/02

Abstract: The invention concerns naphtholactam derivatives of formula (I), in which: R represents hydrogen, optionally substituted C1-C6 alkyl, C5-C6 cycloalkyl or substituted phenyl; R and R represent hydrogen, C1-C8 alkanoyl, optionally substituted benzoyl, optionally substituted C2-C4 alkyl, optionally substituted C2-C4 alkenyl, optionally substituted C2-C4 alkinyl, a halogen, nitro, sulphamoyl, optionally substituted hydroxy, optionally substituted mercapto, C1-C6 alkylsulphonyl or optionally substituted phenylsulphonyl; R represents hydrogen or, with R , a group of formula (II); R represents hydrogen or C1-C6 alkyl; R represents cyano, carbamoyl, C1-C4 mono- or dialkylcarbamoyl, carboxyl or C1-C4 alkoxycarbonyl; and R represents substituted C1-C4 alkyl, optionally substituted C5-C13 alkyl or benzoyl. Also disclosed is the use of these derivatives for dyeing or printing textiles.

公开(公告)号：DE4339712A1

公开(公告)日：1995-05-24

申请号：DE4339712

申请日：1993-11-22

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR

IPC: G02F1/35 ,  C07D495/04 ,  C08F20/38 ,  C09B29/00 ,  C09B29/033 ,  C09B29/09 ,  C09B69/10 ,  G02F1/355 ,  G02F1/361 ,  C08F28/06

Abstract: PCT No. PCT/EP94/03685 Sec. 371 Date May 8, 1996 Sec. 102(e) Date May 8, 1996 PCT Filed Nov. 9, 1994 PCT Pub. No. WO95/14957 PCT Pub. Date Jun. 1, 1995Use of azo dyes having a diazo component derived from an aminothienothiophene and a coupling component of the aniline series in nonlinear optics, polymers derived from these azo dyes, the use thereof in nonlinear optics, and novel phenylthienothienylazoanilines.

公开(公告)号：DE4335540A1

公开(公告)日：1995-04-20

申请号：DE4335540

申请日：1993-10-19

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR ,  HAEBERLE KARL DR

IPC: G02F1/35 ,  C08G18/30 ,  C08G18/38 ,  C09B69/10 ,  G02F1/355 ,  G02F1/361 ,  C08G18/65 ,  C09D175/04

Abstract: Polyadducts containing azo dyes and urethane groups comprising (a) at least one organic polyisocyanate, (b) at least one diol of a heterocyclic azo dye, and optionally (c) one or more compounds containing at least two NCO-reactive groups and having a mean molecular weight Mn of up to 500 g/mol, and/or (d) one or more polyhydroxyl compounds having mean molecular weights Mn of from 500 to 5000 g/mol. These polyadducts are suitable for applications in non-linear optics.

公开(公告)号：DE4319675A1

公开(公告)日：1994-12-15

申请号：DE4319675

申请日：1993-06-14

Applicant: BASF AG

Inventor： BECKMANN STEFAN DR ,  SCHEFCZIK ERNST DR

IPC: B01J31/02 ,  C07B61/00 ,  C07D213/89 ,  C07D213/69 ,  C07D403/04

公开(公告)号：DE4317094A1

公开(公告)日：1994-11-24

申请号：DE4317094

申请日：1993-05-21

Applicant: BASF AG

Inventor： ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR ,  BECKMANN STEFAN DR

IPC: C08G63/00 ,  C08G63/685 ,  C09B69/10 ,  C09K9/02 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  C08G63/91 ,  C09K19/38

Abstract: The invention relates to polyesters containing nonlinear-optical chromophors, which have mean molecular weights Mw of between 5000 and 500,000 and contain units of the general formula (I) in which A is a divalent radical, D is an electron donor, G is a heterocyclic ring as electron acceptor, x and y are identical or different numbers, m and n are identical or different numbers, and R and R are identical or different radicals. The polyesters according to the invention are suitable, for example, as components in communications technology.

公开(公告)号：DE19643769A1

公开(公告)日：1998-04-30

申请号：DE19643769

申请日：1996-10-23

Applicant: BASF AG

Inventor： MERGER ROLAND DR ,  BECKMANN STEFAN DR ,  REICHELT HELMUT DR

IPC: C07C211/52 ,  C09B35/025 ,  C09B35/205 ,  C07C211/50 ,  C08J3/20 ,  C08L67/00 ,  D06P1/18 ,  D06P3/54

Abstract: Disazo dyes of formula (I) are new. R , R , R and R independently = Br or CN, R and R independently = H, 1-10 C alkyl (optionally substituted by 1-4 C alkoxy, OH or CN), 3-4 C alkenyl, 5-8 C cycloalkyl, phenyl or phenylalkyl, A = 1-10 C alkylene which may be interrupted by 1-3 non-adjacent O atoms and optionally substituted by 1-4 C alkyl, and K = a residue from the benzene-, indole-, quinoline-, naphthalene-, thiophene-, thiazole-, pyrrole-, benzimidazole-, benzthiazole- or pyridine series. The bis-aniline compounds used as starting materials in the preparation of (I) are also claimed.