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    12.
    发明专利
    未知

    公开(公告)号：DE502004004069D1

    公开(公告)日：2007-07-26

    申请号：DE502004004069

    申请日：2004-07-01

    Applicant: BASF AG

    Inventor： WEINLE WERNER ,  BEY OLIVER ,  ZEHNER PETER

    IPC: B01D3/20 ,  B01J10/00 ,  B01D3/00 ,  B01J3/00 ,  B01J8/18 ,  B01J8/22 ,  B01J8/34 ,  B01J19/26

    Abstract: A reactor, used for reactions between liquid/gas, or gases/liquids/solids, and has a vertical longitudinal axis with an educt feed pipe in the upper part of the reactor. Incoming gas (3) enters via an aperture in the base (5), and is distributed via a gas distributor module (9) that consists solely of straight pipes (14, 15). The gas distributor module has no curved or bent pipes. All pipes within the module are cylindrical and of circular cross section. Pipe sections are joined at right angles to each other. Horizontal distributor pipes (15) are at 40-90% of reactor chamber (4) depth.

    15.
    发明专利
    未知

    公开(公告)号：DE102005050283A1

    公开(公告)日：2007-04-26

    申请号：DE102005050283

    申请日：2005-10-20

    Applicant: BASF AG

    Inventor： GERLINGER WOLFGANG ,  MATTKE TORSTEN ,  BEY OLIVER

    IPC: B01J4/00 ,  B01F3/04 ,  B01J8/06

    Abstract: A shell-and-tube reactor is disclosed. Contact tubes are disposed within a cylindrical housing and are secured to tube plates. Gas and liquid phases are received via a feed opening in a lower end cap and discharged via an upper end cap in the housing. A distributor device is disposed in the housing, such that the tube plates serve as a horizontal plate for the distributor device to back up the gas phase and form a gas cushion, and vertical elements extend from the contact tubes. The vertical elements are adapted to conduct the liquid phase, are open in the upstream direction, and project outward in the direction of the feed opening through the gas cushion. The vertical elements further include at least one first opening on the circumference for the gas phase and at least one second opening for the liquid phase.

    Preparation of optically active 3-phenylpropionic acid derivatives, used for preparing halo-phenyl compounds, comprises hydrogenating cis-isomer mixture of phenyl compound, crystallizing enantiomer mixture and isolating solid material
    16.
    发明专利
    Preparation of optically active 3-phenylpropionic acid derivatives, used for preparing halo-phenyl compounds, comprises hydrogenating cis-isomer mixture of phenyl compound, crystallizing enantiomer mixture and isolating solid material 未知

    公开(公告)号：DE102005029228A1

    公开(公告)日：2006-12-28

    申请号：DE102005029228

    申请日：2005-06-23

    Applicant: BASF AG

    Inventor： HETTCHE FRANK ,  VOELKERT MARTIN ,  JAEKEL CHRISTOPH ,  BEY OLIVER

    IPC: C07C59/64 ,  C07C43/225

    Abstract: Preparation of an optically active 3-phenylpropionic acid derivative (I) comprises: (a) an enantioselective hydrogenation of a cis-isomer or cis/trans-isomer mixture of a phenyl compound (II) in the presence of a chiral hydrogenation catalyst to give an enantiomer enriched enantiomer mixture; (b) crystallization of the enantiomer enriched enantiomer mixture by supplementation of a basic salt former in a solvent and isolating the stereoisomer enriched solid material; and (c) optionally isolation of the protonated isomer or a substitutional cation. Preparation of an optically active 3-phenylpropionic acid derivative of formula (I) comprises: (a) an enantioselective hydrogenation of a cis-isomer or cis/trans-isomer mixture of a phenyl compound of formula (II) in the presence of a chiral hydrogenation catalyst to give an enantiomer enriched enantiomer mixture; (b) crystallization of the enantiomer enriched enantiomer mixture by supplementation of a basic salt former in a solvent and isolating the stereoisomer enriched solid material; and (c) optionally isolation of the protonated isomer or a substitutional cation. R 1>-R 4>H, 1-6C alkyl, halo-1-6C alkyl, OH-1-6C alkyl, 1-6C alkoxy, OH-1-6C alkoxy, 1-6C alkoxy-1-6C alkyl, OH-1-6C alkoxy-1-6C alkyl, 1-6C alkoxy-1-6C alkoxy or OH-1-6C alkoxy-1-6C alkoxy; R 5>1-6C alkyl, 5-8C cycloalkyl, phenyl or benzyl; and A : H or cationic equivalent. Independent claims are also included for: (1) the preparation of optically active halo-phenyl compound of formula (III), which comprises protonating (I) in to an acid; reducing the acids or the metal salts to give an alcohol compound of formula (IV); and halodehydroxylating (IV); and (2) an optically active compound 3-phenylpropionic acid derivative (I). Hal : Cl, Br or I. [Image] [Image].

    METHOD FOR PRODUCING DIALDEHYDES AND/OR ETHYLENICALLY UNSATURATED MONOALDEHYDES BY HYDROFORMYLATING ETHYLENICALLY UNSATURATED COMPOUNDS
    18.
    发明专利
    METHOD FOR PRODUCING DIALDEHYDES AND/OR ETHYLENICALLY UNSATURATED MONOALDEHYDES BY HYDROFORMYLATING ETHYLENICALLY UNSATURATED COMPOUNDS 未知

    公开(公告)号：AU2003267348A1

    公开(公告)日：2004-04-08

    申请号：AU2003267348

    申请日：2003-09-12

    Applicant: BASF AG

    Inventor： SAVA XAVIER ,  LOBER OLIVER ,  BEY OLIVER ,  STEPHAN JURGEN ,  HAESE FRANK ,  VOLLAND MARTIN ,  AHLERS WOLFGANG ,  EBEL KLAUS ,  PACIELLO ROCCO ,  ROPER MICHAEL ,  MACKEWITZ THOMAS ,  BOHM VOLKER

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/12 ,  C07F9/572 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/6584 ,  C07F9/6596 ,  C07C47/21

    Abstract: A process for the production of dialdehydes and/or ethylenically unsaturated monoaldehydes by reaction of at least one compound having at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst comprising at least one complex of a Group VIII metal with at least one ligand comprising a pnicogen chelate compound. A process for the production of dialdehydes and/or ethylenically unsaturated monoaldehydes by reaction of at least one compound having at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst comprising at least one complex of a Group VIII metal with at least one ligand comprising a pnicogen chelate compound of formula (1). Q = bridging group of formula (2); A1, A2 = O, S, SiRaRb, NRc or CRdRe; Ra-Rc = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; Rd, Re = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl or two Rd groups and/or two Re groups form an intermolecular bridging group D; D = bivalent bridging group of formula (3)-(6); R9,R10 = H, alkyl, cycloalkyl, aryl, halo, trifluoromethyl, carboxyl, carboxylate or cyano or together form a 3-4C alkylene bridge; R11-R14 = H, alkyl, cycloalkyl, aryl, halo, trifluoromethyl, COOH, carboxylate, cyano, alkoxy, SO3H, sulfonate, NE1E2, alkylene-NE1E2E3+X-, acyl or nitro; C = 0 or 1; Y = chemical bond; RI-RVI = H, alky, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; COORf, COO-M+, SO3Rf, SO3-M+, NE1E2, NE1E2E3+X-, alkylene-NE1E2E3+X-, ORf, SRf, (CHRgCH2O)xRf, (CH2N(E1))xRf, (CH2CH2N(E1))xRf, halo, trifluoromethyl, nitro, acyl or cyano or 2 neighboring groups, together with two neighboring C atoms of the benzene ring to which they are bonded form a condensed ring system of 1-3 further rings; Rf, E1-E3 = H, alkyl, cycloalkyl or aryl; R9 = H, methyl or ethyl; M+ = cation, X-=anion; x = 1-120; a, b = 0 or 1; Pn = P, As or Sb; R1-R4 = heteroaryl, heteroaryloxy, alkyl, alkoxy, aryl, aryloxy, cycloalkyl, cycloalkoxy, heterocycloalkyl, heterocycloalkoxy or NE1E2 with the proviso that is R1 and R3 are bonded via the N atom to the pnicogen atom bonded pyrrole ring or R1 with R2 and/or R3 together with R4 form a divalent group E of formula Py-I-W or R1 and R2 and/or R3 and R4 form a bispyrrole group of formula Py-I-Py; Py = pyrrole group that is bonded via its N atom to Pn; I = chemical bond, O, S, SiRaRb, NRc, optionally substituted 1-10C alkylene or CRhCRi; W = cycloalkyl, cycloalkoxy, aryl, aryloxy, heteroaryl or heteroaryloxy; Rh and Ri = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl

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