公开(公告)号：DE4211140A1

公开(公告)日：1993-10-07

申请号：DE4211140

申请日：1992-04-03

Applicant: BASF AG

Inventor： BURKHART BERND DR ,  OFTRING ALFRED DR ,  SCHWENDEMANN VOLKER DR ,  GLASER KLAUS

IPC: C07F9/54 ,  C25D3/12 ,  C25D3/14

Abstract: Phosphonium salts of formula (I) in which: R to R are C1 to C18 alkyl which may be substituted by carboxyl groups or C1 to C4 alkoxycarbonyl groups or cyano groups, C2 to C12 alkenyl, C2 to C12 alkinyl, C5 to C8 cycloalkyl, C7 to C12 phenylalkyl, phenyl which may be substitued by one or two C1 to C4 alkyl radicals, C1 to C4 alkoxy radicals, halogen atoms, hydroxyl groups, phenyl radicals or C1 to C4 alkoxy carbonyl groups, or mono or di(C1 to C4 alkyl)amino; R and R are hydrogen or C1 to C4 alkyl; A is hydrogen or a group of the formula -OCO-H, -CO-R , -CO-OH, -CO-OR , -CO-CH2-CO-OR , -O-CO-H, O-CO-R , -OR , -SO2-R , -SO2-OH, -SO2-OR , -PO(OH)2, PO(OH)(OR ), -PO(OR )2, -OPO(OH)2, -OPO(OH)(OR ) or -OPO(OR )2; where R is C1 to C12 alkyl, C2 to C12 alkenyl, C2 to C12 alkinyl, C5 to C8 cycloalkyl, C7 to C12 phenylalkyl or phenyl which may be substituted by one or two C1 to C4 alkyl radicals, C1 to C4 alkoxy radicals, halogen atoms, hydroxyl groups, phenyl radicals or C1 to C4 alkoxy carbonyl groups; Y stands for the group -CH=CH- or -C=C-; m is a number from 0 to 10; n is a number from 1 to 4; p is 0 or 1; and q is a number from 0 to 10; and X- is an n-valent inorganic or organic anion improving water solubility. The phosphonium salts I are suitable as brighteners for aqueous-acid galvanic nickel baths.

公开(公告)号：DE4119341A1

公开(公告)日：1992-12-17

申请号：DE4119341

申请日：1991-06-12

Applicant: BASF AG

Inventor： HAHN ERWIN DR ,  DUNG BERNHARD DR ,  BURKHART BERND DR ,  TSCHANG CHUNG-JI DR

IPC: C25D3/22 ,  C25D3/56

Abstract: The invention relates to the production of bright zinc-plated or zinc-alloy-plated shaped parts by the electrolytic desposition or zinc or a zinc alloy from an acidic aqueous galvanic bath containing as its essential components one or more zinc salts and optionally salts of other alloy metals, one or more conducting salts, one or more surface-active agents and one or more brighteners. Used as brighteners are compounds of the formula (I), in which R is a C1-C8 alkoxy, phenoxy, benzyloxy, amino, C1-C6 alkylamino or di(C1-C6) alkylamino group; R is a C1-C4 alkyl, phenyl or benzyl group or one of the groups given for R ; Ar is a phenyl or naphthyl group which may be substituted by one to three C1-C4 alkyl or C1-C4 alkoxy groups.

公开(公告)号：DE59504247D1

公开(公告)日：1998-12-24

申请号：DE59504247

申请日：1995-04-27

Applicant: BASF AG

Inventor： OFTRING ALFRED DR ,  BURKHART BERND DR ,  WEHLAGE THOMAS DR ,  DYLLICK-BRENZINGER RAINER DR ,  BECK KARIN HEIDRUN DR

IPC: C07D231/12 ,  C07D233/58 ,  G03G9/097

Abstract: Electrostatic toner contains a polymeric binder and, as charge stabiliser, a phenylacyl cpd. of formula (I): Het (+) - L - CD - Phe-R An (-) (I); Het (+) = a positively charged gp. derived from an heterocycle of the pyrazole, imidazole, pyridine, (iso)quinoline series; L = 1-8C alkylene; Phe = phenylene, opt. with an annelated benzene ring; R = H, OH, 1-4C alkoxy, NH2, 1-4C mono- or dialkylamino or an opt. substd. 1-6C alkyl, phenyl, phenoxy, mono- or diphenylamino or N-(1-4C alkyl)-N-phenyl-amino gp.; and An (-) = the equiv. of an anion. Also claimed is the use of (I) as charge stabiliser in electrostatic toners.

公开(公告)号：DE19650107A1

公开(公告)日：1998-06-04

申请号：DE19650107

申请日：1996-12-03

Applicant: BASF AG

Inventor： OFTRING ALFRED DR ,  OETTER GUENTER DR ,  BAUR RICHARD DR ,  BORZYK OLIVER DR ,  BURKHART BERND DR ,  OTT CHRISTIAN DR ,  KAHMEN MARTIN AUS DEM DR

IPC: C07C231/02 ,  C07C231/24 ,  C07C233/05 ,  C07C233/09 ,  C07C233/18 ,  C07C233/20 ,  C11D19/00

Abstract: Separation of glycerol (I) from a reaction mixture containing (I) and fatty acid amides (II) comprises separation into an aqueous phase containing (I) and an organic phase containing (II) by adding aqueous acid solution to pH 1-7 and separating the aqueous phase. Also claimed is a method of preparing (II) by reacting fatty acid glycerides (III) with amines, in which the reaction mixture is treated in this way.

公开(公告)号：DE19701123A1

公开(公告)日：1997-08-07

申请号：DE19701123

申请日：1997-01-15

Applicant: BASF AG

Inventor： KOBER REINER DR ,  SCHNEIDER KARL-HEINRICH DR ,  RADEMACHER WILHELM DR ,  STADLER REINHOLD DR ,  BURKHART BERND DR ,  OETTER GUENTER DR ,  GERBER MATTHIAS DR ,  NUYKEN WESSEL DR ,  SCHMIDT OSKAR DR ,  ZIEGLER HANS DR ,  KIBLER ELMAR DR ,  KROEHL THOMAS DR

IPC: A01N37/04

Abstract: A silicone-oil-free mixture (S) comprises: (a) at least one dicarboxylic acid ester of formula (I); and (b) the product (II) from the reaction of a triglyceride-based oil or fat with ethylene and/or propylene oxide in the presence of a base. ROOC-A-COOR(I) R = 1-20C alkyl; and A = 1-20C alkylene, 2-20C alkenylene, 2-20C alkynylene, 5-6C cycloalkylene, 5-6C cycloalkenylene or phenylene. The oil or fat contains 2-30C with at least one carboxylic acid group. Also claimed is a crop protection composition (P) containing (S) and at least one pesticidal crop protection active compound (T).

公开(公告)号：DE4446347A1

公开(公告)日：1996-06-27

申请号：DE4446347

申请日：1994-12-23

Applicant: BASF AG

Inventor： WEHLAGE THOMAS DR ,  BURKHART BERND DR ,  OFTRING ALFRED DR ,  SCHROEDER ULRICH DR ,  WIDDER RUDI DR

IPC: C07C45/74 ,  C07C67/343 ,  C07C69/72 ,  C07C47/54 ,  C25D3/02

Abstract: Prepn. of 2-(benzylidene or naphthylidene) acylacetic or malonic acid esters or amides of formula Ar-CH=C(COR )(COR ) (I) involves reacting an aromatic aldehyde of formula ArCHO (II) with an active methylene cpd. of formula CH2(COR )(COR ) (III). In the formulae, Ar = phenyl or naphthyl (both opt. substd. by 1-3 or 1-4C alkyl, 1-4C alkoxy and OH); R = 1-8C alkoxy, phenoxy, benzyloxy or -NR R ; R ,R = H or 1-6C alkyl; R = 1-4C alkyl, phenyl, benzyl or as R . The novelty is that the reaction mixt., at the end of the reaction, is washed with aq. alkali metal (hydrogen) sulphite soln. to remove residual, unconverted (II). Pref. the organic solvent in the organic phase obtd. after the (bi)sulphite wash is distilled off to give a technical prod. contg. (I). The use of this technical prod. as brightener is claimed. Preferably, Ar = phenyl (opt. substd. by 1 or 2 of Me, Et, OMe and OEt); R = 1-8C alkoxy; R = 1-4C alkyl or 1-6C alkoxy. Esp. Ar = Ph, R = OMe or OEt, and R = Me, OMe or OEt.

公开(公告)号：DE4338395A1

公开(公告)日：1995-05-11

申请号：DE4338395

申请日：1993-11-10

Applicant: BASF AG

Inventor： WOLF GERHARD DR ,  BURKHART BERND DR ,  OFTRING ALFRED DR

IPC: C07C41/54 ,  C07C43/315 ,  C09K23/00 ,  C09K23/42 ,  C11D1/72 ,  C11D1/825 ,  C07C43/303 ,  C07C43/10 ,  B01F17/42 ,  B01J31/04

Abstract: Preparation of mixtures of low-foam non-ionic surfactants having acetal structure, containing A) 70 to 99% by weight of one or more asymmetrical acetals where R is a C1- to C30-alkyl radical, a C3- to C30-alkenyl radical or a C7- to C30-aralkyl radical or -alkaryl radical, R is a C1- to C10-alkyl radical, A is a 1,2-alkylene group having 2 to 4 C atoms and x can assume values from 1 to 50, and B) 1 to 30% by weight of one or more symmetrical acetals II where the variables R , A and x have the abovementioned meanings, by reaction of alkoxylates III R -(OA)x-OH (III> with vinyl ethers IV H2C=CH-O-R (IV> in the presence of protic acids as catalyst, by employing as catalysts organic acids having a pKa of 1 to 7, based on the first dissociation stage of the acids in water.