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公开(公告)号:ES2198788T3
公开(公告)日:2004-02-01
申请号:ES98965854
申请日:1998-12-17
Applicant: BASF AG
Inventor: MOHR JURGEN , DOCKNER TONI
IPC: C07C41/02 , C07B61/00 , C07C29/128 , C07C41/03 , C07C213/04 , C07C217/50 , C08G65/10 , C08G73/02 , C08G73/04
Abstract: In a process for preparing alkoxylated amines or alcohols in which a reaction mixture comprising an amine or an alcohol or a mixture of two or more amines and/or alcohols and an alkylene oxide, or a mixture of two or more different alkylene oxides, is reacted in one or more successive reaction steps, at least one of the reaction steps is carried out in the presence of a basic catalyst and, in at least one of the reaction steps, formic acid or a salt of formic acid or a mixture of two or more thereof is present in the reaction mixture or the reaction mixture is admixed with formic acid or a salt of formic acid, or a mixture of two or more thereof, after the alkoxylation is complete. The alkoxylates prepared by the process of the present invention have a light color and a low odor.
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公开(公告)号:DE59808104D1
公开(公告)日:2003-05-28
申请号:DE59808104
申请日:1998-12-17
Applicant: BASF AG
Inventor: MOHR JUERGEN , DOCKNER TONI
IPC: C07C41/02 , C07B61/00 , C07C29/128 , C07C41/03 , C07C213/04 , C07C217/50 , C08G65/10 , C08G73/02 , C08G73/04
Abstract: In a process for preparing alkoxylated amines or alcohols in which a reaction mixture comprising an amine or an alcohol or a mixture of two or more amines and/or alcohols and an alkylene oxide, or a mixture of two or more different alkylene oxides, is reacted in one or more successive reaction steps, at least one of the reaction steps is carried out in the presence of a basic catalyst and, in at least one of the reaction steps, formic acid or a salt of formic acid or a mixture of two or more thereof is present in the reaction mixture or the reaction mixture is admixed with formic acid or a salt of formic acid, or a mixture of two or more thereof, after the alkoxylation is complete. The alkoxylates prepared by the process of the present invention have a light color and a low odor.
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公开(公告)号:CA2375262A1
公开(公告)日:2000-12-28
申请号:CA2375262
申请日:2000-06-21
Applicant: BASF AG
Inventor: DOCKNER TONI , KINGMA AREND JOUKE , KASEL WOLFGANG , MUNDINGER KLAUS , KOSER STEFAN
Abstract: The invention relates to a method for producing bisphenol alcoxylates, where by at least one bisphenol is reacted with alkylene oxide in the presence of a phosphine catalyst that contains essentially no alkali hydroxide.
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公开(公告)号:BR9814500A
公开(公告)日:2000-10-10
申请号:BR9814500
申请日:1998-12-17
Applicant: BASF AG
Inventor: MOHR JURGEN , DOCKNER TONI
IPC: C07C41/02 , C07B61/00 , C07C29/128 , C07C41/03 , C07C213/04 , C07C217/50 , C08G65/10 , C08G73/02 , C08G73/04
Abstract: In a process for preparing alkoxylated amines or alcohols in which a reaction mixture comprising an amine or an alcohol or a mixture of two or more amines and/or alcohols and an alkylene oxide, or a mixture of two or more different alkylene oxides, is reacted in one or more successive reaction steps, at least one of the reaction steps is carried out in the presence of a basic catalyst and, in at least one of the reaction steps, formic acid or a salt of formic acid or a mixture of two or more thereof is present in the reaction mixture or the reaction mixture is admixed with formic acid or a salt of formic acid, or a mixture of two or more thereof, after the alkoxylation is complete. The alkoxylates prepared by the process of the present invention have a light color and a low odor.
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公开(公告)号:CA2326888A1
公开(公告)日:1999-11-11
申请号:CA2326888
申请日:1999-04-22
Applicant: BASF AG
Inventor: PETERS JARREN , DOCKNER TONI , BENFER REGINA , BIRNBACH STEFAN , MOHR JURGEN , ZEHNER PETER , BIEG WALTER , WEINLE WERNER , RUGE BERND
IPC: C07D317/36 , C07D317/38
Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2- ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first pa rt of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the seco nd part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout th e reactor.
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公开(公告)号:DE19819586A1
公开(公告)日:1999-11-04
申请号:DE19819586
申请日:1998-04-30
Applicant: BASF AG
Inventor: BIRNBACH STEFAN , DOCKNER TONI , MOHR JUERGEN , BENFER REGINA , BIEG WALTER , PETERS JARREN , RUGE BERND , WEINLE WERNER , ZEHNER PETER
IPC: C07D317/36 , C07D317/38 , C07D317/44
Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first part of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the second part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout the reactor.
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公开(公告)号:BR9703409A
公开(公告)日:1999-01-05
申请号:BR9703409
申请日:1997-05-27
Applicant: BASF AG
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公开(公告)号:ID15886A
公开(公告)日:1997-08-14
申请号:ID970347
申请日:1997-02-05
Applicant: BASF AG
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公开(公告)号:HRP931372A2
公开(公告)日:1996-08-31
申请号:HRP931372
申请日:1993-11-04
Applicant: BASF AG
Inventor: LERMER HELMUT , HOELDERICH WOLFGANG , DOCKNER TONI , KOEHLER HERMANN
IPC: B01J29/04 , B01J29/08 , C07D231/12 , C07D233/64
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公开(公告)号:CA1331004C
公开(公告)日:1994-07-26
申请号:CA606131
申请日:1989-07-19
Applicant: BASF AG
Inventor: SCHOMMER CHARLES , EBEL KLAUS , DOCKNER TONI , IRGANG MATTHIAS , HOELDERICH WOLFGANG , RUST HARALD
IPC: B01J21/06 , B01J23/04 , C07B61/00 , C07C45/00 , C07C45/48 , C07C45/74 , C07C49/04 , C07C49/76 , C07C49/792 , C07C67/00 , C07D213/50 , C07C45/41
Abstract: Ketones of the general formula (I) (I) where R1 and R2 independently of one another are each alkyl, cycyloalkyl, arylalkyl, aryl or hetaryl, and one or more of the radicals R1 and R2 carry one or more hydrogen atoms on the .alpha.-carbon atom, are prepared by reacting two carboxylic acids of the general formulae (IIa/IIb), R1-COOH (IIa) and R2-COOH (IIb) or by reacting carbocylic acid R1-COOH (IIa) and a ketone (Ib) or by reacting a mixture of IIa, IIb and Ib, in the gas phase in the presence of a catalyst, by a process in which a catalyst is used whose active material contains at least 50% by weight of titanium dioxide having a specific surface area greater than 10 m2/g.O
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