公开(公告)号：DE19727505A1

公开(公告)日：1999-01-07

申请号：DE19727505

申请日：1997-06-27

Applicant: BASF AG

Inventor： MORRISON BRADLEY DR ,  MATHAUER KLEMENS DR ,  FISCHER MICHAEL DR ,  DURANT YVON DR

IPC: C08F2/22 ,  C08F4/00

Abstract: Radically initiated aqueous emulsion polymerisation process giving an aqueous polymer dispersion comprises emulsifying an ethylenically unsaturated group-containing compound(s) in aqueous medium using a dispersing agent and polymerising either using a radical polymerisation initiator in the presence of a stable N-oxyl radical(s) or using a compound(s) which decomposes on heating into a stable N-oxyl radical(s) and a radical polymerisation initiator. The emulsion obtained comprises droplets of diameter at most 500 nm and is polymerised by increasing the temperature. Also claimed are the obtained aqueous polymer dispersions.

公开(公告)号：DE19727502A1

公开(公告)日：1999-01-07

申请号：DE19727502

申请日：1997-06-27

Applicant: BASF AG

Inventor： FISCHER MICHAEL DR ,  MORRISON BRADLEY ROLAND DR ,  SUTORIS HEINZ FRIEDRICH DR ,  DURANT YVON DR

IPC: C08F2/00 ,  C08F2/22 ,  C08F2/24 ,  C08F4/00 ,  C08F4/04 ,  C08F4/28 ,  C08F4/34 ,  C08F12/08 ,  C08F12/12 ,  C08F20/18 ,  C08F20/44

Abstract: A radical-initiated emulsion polymerisation method for the preparation of an aqueous polymer dispersion, containing at least one compound with an ethylenic unsaturated group emulsified in an aqueous medium using a dispersant, is carried out using a radical polymerisation initiator in the presence of a stabil N-oxyl radical. The initiator is a (hydro)peroxide and/or azo compound which has a molar solubility in water at 25 deg C and a bar which is greater than or equal to the corresponding molar solubility of tert-butyl hydroperoxide in water, and which has a degradation temperature less than 100 deg C in the polymerisation medium. The polymerisation step is carried out at a temperature greater than 100 deg C at a pressure greater than the vapour pressure of the polymer mixture present in the polymerisation vessel. Also claimed are aqueous polymer dispersions prepared by this method.

公开(公告)号：DE19631148A1

公开(公告)日：1998-02-05

申请号：DE19631148

申请日：1996-08-01

Applicant: BASF AG

Inventor： FISCHER MICHAEL DR ,  LINDENSCHMIDT GERHARD DR ,  MAC KEE GRAHAM EDMUND DR ,  ROSENAU BERNHARD DR ,  NAARMANN HERBERT DR

IPC: C08F2/16 ,  C08F2/22 ,  C08F265/04 ,  C08F290/12 ,  C08L69/00

Abstract: Compounds are disclosed having the general formula (I) H(-CH2-CR R )m(-CH2-CR R )n-H, in which R is H or methyl; R is -C(O)-Y-R , R being H, methyl, ethyl or allyl; R is -C(O)-Y-allyl; and Y is O or NH; or in which R is H or C1-20-alkyl; R is H; and R is (-CH2-CR =CR -CH2)p-H, R and R independently representing H, methyl, ethyl, chlorine, and p = 1-100; or in which R is H; R is OH or O-allyl; and R is O-allyl; or in which R is H; R is OH or R , R being (meth)acrylate, -O-C(O)-CH=CH-COOH or -O-C(O)-CH2-C(=CH2)-COOH, m is an integer from 5 to 500,000 and n is an integer from 2 to 100,000. These compounds are used as crosslinkers in particulate emulsion polymers with a glass transition temperature below 0 DEG C and a mean particle size from 50 to 1000 nm.

公开(公告)号：DE19523080A1

公开(公告)日：1997-01-02

申请号：DE19523080

申请日：1995-06-26

Applicant: BASF AG

Inventor： FISCHER MICHAEL DR ,  KOCH JUERGEN DR ,  ROSENAU BERNHARD DR ,  MAC KEE GRAHAM EDMUND DR ,  GRABOWSKI SVEN DR ,  MOSBACH NORBERT ,  FISCHER WOLFGANG DR

IPC: C08F257/02 ,  C08F265/04 ,  C08F285/00 ,  C08L69/00 ,  C08F257/00 ,  C08J5/18 ,  C08L53/02

Abstract: Graft copolymer (I) with definite core-shell morphology contains: (A) 1-95 wt.% graft substrate of a material (II) with a Tg of at least 25 deg C and an average particle size d(d50) of at least 150 nm; (B) 4.9-98.9 wt.% grafted material (III) with a Tg of at most 0 deg C; and (C) 0.1-90 wt.% other grafted material(s); where: (I) comprises: (a1) 50-99.8 wt.% vinyl-aromatic monomer(s), (a2) 0-49.8 wt.% copolymer(s). (a3) 0.1-25 wt.% crosslinker, comprising: ( alpha ) 0.1-100 wt.% dihydrodicyclopentadienyl acrylate; and ( beta ) 0-99.9 wt.% other crosslinker(s) with functional gps. of different reactivity; and (a4) 0.1-25 wt.% other crosslinker(s) with functional gps. with the same reactivity. Also claimed are: (i) a method of producing (I); (ii) thermoplastic moulding compsns.; and (iii) mouldings, films, fibres and coatings contg. (I).

公开(公告)号：MY130453A

公开(公告)日：2007-06-29

申请号：MYPI20015288

申请日：2001-11-19

Applicant: BASF AG

Inventor： WINTERLING HELMUT DR ,  FISCHER MICHAEL DR

IPC: C08G69/00 ,  C08G69/08 ,  C08G69/04 ,  C08G69/16 ,  C08G69/28

Abstract: A PROCESS FOR PREPARING POLYAMIDES COMPRISES POLYMERIZING STARTING MONOMERS IN THE PRESENCE OF FROM 2.3 TO 10 MMOL, BASED ON 1 MOL OF CARBOXAMIDE GROUP OF THE POLYAMIDE, OF A CHAIN REGULATOR CONTAINING A NITRILE GROUP AND A FUNCTIONAL GROUP CAPABLE OF FORMING A CARBOXAMIDE GROUP.

公开(公告)号：MY122687A

公开(公告)日：2006-04-29

申请号：MYPI20000257

申请日：2000-01-26

Applicant: BASF AG

Inventor： FISCHER MICHAEL DR ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08J5/04 ,  B32B5/18 ,  C08K7/02 ,  B32B27/36 ,  C08K3/04 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  C08L87/00

Abstract: A PROCESS FOR THE PREPARATION OF FIBER-REINFORCED MOLDINGS FOR MOTOR VEHICLES WHEREIN THE MOLDING COMPRISES (A) FROM 1 TO 96.86% BY WEIGHT OF AT LEAST ONE POLYCONDENSATE, (B) FROM 1 TO 12% BY WEIGHT OF AT LEAST ONE PARTICULATE GRAFT COPOLYMER WHOSE SOFT PHASE HAS A GLASS TRANSITION TEMPERATURE BELOW 0?C. AND WHOSE MEDIAN PARTICLE SIZE IS FROM 50 TO 1000 NM, (C) FROM 1 TO 12% BY WEIGHT OF AT LEAST ONE COPOLYMER MADE FROM THE FOLLOWING MONOMERS, (C1) FROM 50 TO 90% BY WEIGHT OF AT LEAST ONE VINYLAROMATRIC MONOMER, AND (C2) FROM 10 TO 50% BY WEIGHT OF ACRYLONITRILE AND/OR METHACRYLONITRILE, BASED IN EACH CASE ON COMPONENT C, (D) FROM 0 TO 20% BY WEIGHT OF (E) FROM 0.01 TO 15% BY WEIGHT OF POLYCARBONATE, (F) FROM 0.01 TO 2% BY WEIGHT OF A CARBON BLACK, (G) FROM 0 TO 12% BY WEIGHT OF A POLYMER OTHER THAN COMPONENT B, (H) FROM 0 TO 20% BY WEIGHT OF A POLYESTER OTHER THAN COMPONENT A, (I) FROM 0.1 TO 10% BY WEIGHT OF CONVENTIONAL ADDITIVES, SUCH AS UV STABILIZERS, OXIDATION RETARDERS, LUBRICANTS AND MOLD-RELEASE AGENTS. MOLDINGS AND COMPOSITES MADE FROM THESE MOLDING COMPOSITIONS ARE AS DESCRIBED AS IS THE USE OF THE MOLDING COMPOSITIONS, THE MOLDINGS AND THE COMPOSITES.

公开(公告)号：DE19714900A1

公开(公告)日：1998-10-15

申请号：DE19714900

申请日：1997-04-10

Applicant: BASF AG

Inventor： KLATT MARTIN DR ,  GRUTKE STEFAN DR ,  HEITZ THOMAS DR ,  RAUSCHENBERGER VOLKER DR ,  PLESNIVY THOMAS DR ,  WOLF PETER DR ,  WUENSCH JOSEF DR ,  FISCHER MICHAEL DR

IPC: C08K3/32 ,  C08K3/34 ,  C08K7/02 ,  C09K21/14 ,  C08L77/00 ,  C08J5/00 ,  C08J5/04 ,  C08J5/18 ,  C08K3/02 ,  D01F6/60

Abstract: A thermoplastic moulding composition (I) contains (A) 10-98 wt.% polyamide (B) 1-20 wt.% red phosphorous (C) 0.1-15 wt.% delaminated layer silicate (phyllosilicate) (D) 0-70 wt.% additional additives and processing aids. An article (II) prepared from the composition (I) is also claimed. Preferably the composition (I) contains 5-40 wt.% fibrous reinforcement as component (D). The polyamide (A) contains at least 5 wt.% units resulting from lactam monomers. (A) comprises 5-95 wt.% (A1) polyamide 6 and 5-95 wt.% (A2) a different polyamide. (A) is polyamide 6, polyamide 12, polyamide 6/66, polyamide 6/6T, polyamide 6/6I, polyamide 66, polyamide 610 and /or polyamide 46. The layer silicate (C) is montmorillonite, smectite, illite, sepiolite, polygorskite, muscovite, allevardite, amesite, hectorite, talc, fluorhectorite, beidellite, nontronite, stevensite, bentonite, mica, vermiculite, fluorvermiculite, halloysite and/or fluorine containing synthetic talc. The moulded article (II) has a layer structure equivalent to 1--2-1-n-Z; 1 = the thermoplastic matrix; and 2 = the delaminated layer silicate, having preferably a 40 deg A gap between layers.

公开(公告)号：DE19626838A1

公开(公告)日：1998-01-08

申请号：DE19626838

申请日：1996-07-04

Applicant: BASF AG

Inventor： FISCHER MICHAEL DR ,  KOCH JUERGEN DR

IPC: C08F293/00 ,  C08F297/00

Abstract: Block copolymers (BC) prepared by reacting the following monomers at 100-160 deg C in the presence of radical initiators and N-oxyl radicals are new :(A) monomers chosen from (alpha-methyl)styrene, (meth)acrylonitrile, methyl methacrylate or maleic acid, forming blocks with a glass transition temperature (Tg) greater than 0 deg C ; and (B) monomers chosen from n-butyl acrylate, methyl acrylate or 2-ethylhexyl acrylate, forming blocks with a Tg less 0 deg C. Also claimed are (i) the preparation of (BC), (ii) transparent or translucent films or moulded articles comprising (BC), and (iii) the use of (BC) for the preparation of these films or articles.

公开(公告)号：DE19602540A1

公开(公告)日：1997-07-31

申请号：DE19602540

申请日：1996-01-25

Applicant: BASF AG

Inventor： FISCHER MICHAEL DR ,  KOCH JUERGEN DR

IPC: C08F293/00 ,  C08F297/00 ,  C08J5/00

Abstract: Block copolymers (I) are claimed, which are obtained by reacting (A) monomers selected from styrene, alpha -methylstyrene, (meth)acrylonitrile, methyl methacrylate and maleic anhydride to blocks A with a Tg > 0 deg C; and (B) monomers selected from n-butyl, methyl and 2-ethylhexyl acrylate to blocks B with a Tg

公开(公告)号：MY141926A

公开(公告)日：2010-07-30

申请号：MYPI20054913

申请日：2005-10-19

Applicant: BASF AG

Inventor： EIBECK PETER DR ,  BRUCHMANN BERND DR ,  EIPPER ANDREAS DR ,  STUMBE JEAN-FRANCOIS DR ,  NEUHAUS RALF DR ,  FISCHER MICHAEL DR ,  ENGELMANN JOCHEN DR ,  DESBOIS PHILIPPE DR

IPC: C08L69/00

Abstract: THERMOPLASTIC MOLDING COMPOSITIONS, COMPRISING A) FROM 10 TO 99% BY WEIGHT OF AT LEAST ONE THERMOPLASTIC POLYAMIDE, B) FROM 0.01 TO 50% BY WEIGHT OF B1) AT LEAST ONE HIGHLY BRANCHED OR HYPERBRANCHED POLYCARBONATE WITH AN OH NUMBER OF FROM 1 TO 600 MG KOH/G OF POLYCARBONATE (TO DIN 53240, PART 2), OR B2) AT LEAST ONE HIGHLY BRANCHED OR HYPERBRANCHED POLYESTER OF AX8Y TYPE, WHERE X IS AT LEAST 1.1 AND Y IS AT LEAST 2.1, OR A MIXTURE OF THESE, C) FROM 0 TO 60% BY WEIGHT OF OTHER ADDITIVES, WHERE THE TOTAL OF THE PERCENTAGES BY WEIGHT OF COMPONENTS A) TO C) IS 100%.