Poly:amide based thermoplastic moulding composition

    公开(公告)号:DE19714900A1

    公开(公告)日:1998-10-15

    申请号:DE19714900

    申请日:1997-04-10

    Applicant: BASF AG

    Abstract: A thermoplastic moulding composition (I) contains (A) 10-98 wt.% polyamide (B) 1-20 wt.% red phosphorous (C) 0.1-15 wt.% delaminated layer silicate (phyllosilicate) (D) 0-70 wt.% additional additives and processing aids. An article (II) prepared from the composition (I) is also claimed. Preferably the composition (I) contains 5-40 wt.% fibrous reinforcement as component (D). The polyamide (A) contains at least 5 wt.% units resulting from lactam monomers. (A) comprises 5-95 wt.% (A1) polyamide 6 and 5-95 wt.% (A2) a different polyamide. (A) is polyamide 6, polyamide 12, polyamide 6/66, polyamide 6/6T, polyamide 6/6I, polyamide 66, polyamide 610 and /or polyamide 46. The layer silicate (C) is montmorillonite, smectite, illite, sepiolite, polygorskite, muscovite, allevardite, amesite, hectorite, talc, fluorhectorite, beidellite, nontronite, stevensite, bentonite, mica, vermiculite, fluorvermiculite, halloysite and/or fluorine containing synthetic talc. The moulded article (II) has a layer structure equivalent to 1--2-1-n-Z; 1 = the thermoplastic matrix; and 2 = the delaminated layer silicate, having preferably a 40 deg A gap between layers.

    Production of 4,4'-di:halo-di:phenyl-sulphone

    公开(公告)号:DE19726805A1

    公开(公告)日:1999-01-07

    申请号:DE19726805

    申请日:1997-06-24

    Applicant: BASF AG

    Abstract: A process for the production of 4,4'-dihalo-diphenyl- sulphones (DHDPSO) comprises reacting chloro-, bromo- or fluoro- benzenes with 4-halophenylsulphonyl chlorides of formula (I); in which X = chlorine, bromine or fluorine. The reaction is carried out in the liquid phase at elevated temperature in presence of solid catalysts with acid centres, comprising (K1) layer silicates with negative layer charges neutralised by protons and essentially not doped with Lewis acids, (K2) zeolites in the acidic H-form, or (K3) mixed oxides with acid centres, consisting of a combination of (a) oxides of titanium, zirconium, hafnium, tin, iron or chromium(III) with (b) oxides of vanadium, chromium(VI), molybdenum, tungsten or scandium, or sulphated or phosphatised oxides of group (a), such mixed oxides having been calcined at 450-800 deg C after combination. Preferably type (K1) comprises aluminium silicate in which part of the silicon is replaced by aluminium and/or part of the Al is replaced by magnesium, especially a montmorillonite. Type (K2) comprises zeolites of structural types MFI, MEL, BOG, BEA, EMT, MOR, FAU, MTW, LTL, NES, CON or MCM 22, especially 12-ring zeolites of the BETA, Y, EMT or mordenite type, or 10-ring zeolites of the pentasil type. Type (K3) may be super-acid mixed oxides, preferably with group (a) oxides and group (b) oxides in a mol ratio of (70:30)-(98:2). The process comprises reacting chlorobenzene (PhCl) with 4-chlorophenyl-sulphonyl chloride (ClPhSOCl) in a mol ratio of 1-100, preferably using excess PhCl, at 100-250 deg C and 1-50 bar, preferably at boiling pt. under normal or autogenous pressure. The catalyst is in the form of a solid bed, and the reaction may be carried out as a continuous process in which excess PhCl is returned to the reactor.

    Production of 4,4'-di:halo-di:phenyl-sulphone

    公开(公告)号:DE19726807A1

    公开(公告)日:1999-01-07

    申请号:DE19726807

    申请日:1997-06-24

    Applicant: BASF AG

    Abstract: A process for the production of 4,4'-dihalo-diphenyl- sulphones (DHDPSO) comprises reacting chloro-, bromo- or fluoro- benzenes with 4-halophenylsulphonyl chlorides of formula (I); in which X = chlorine, bromine or fluorine. The reaction is carried out in the liquid phase at elevated temperature in presence of solid catalysts with acid centres, comprising (K1) layer silicates with negative layer charges neutralised by protons and essentially not doped with Lewis acids, (K2) zeolites in the acidic H-form, or (K3) mixed oxides with acid centres, consisting of a combination of (a) oxides of titanium, zirconium, hafnium, tin, iron or chromium(III) with (b) oxides of vanadium, chromium(VI), molybdenum, tungsten or scandium, or sulphated or phosphatised oxides of group (a), such mixed oxides having been calcined at 450-800 deg C after combination. Preferably type (K1) comprises aluminium silicate in which part of the silicon is replaced by aluminium and/or part of the Al is replaced by magnesium, especially a montmorillonite. Type (K2) comprises zeolites of structural types MFI, MEL, BOG, BEA, EMT, MOR, FAU, MTW, LTL, NES, CON or MCM 22, especially 12-ring zeolites of the BETA, Y, EMT or mordenite type, or 10-ring zeolites of the pentasil type. Type (K3) may be super-acid mixed oxides, preferably with group (a) oxides and group (b) oxides in a mol ratio of (70:30)-(98:2). The process comprises reacting chlorobenzene (PhCl) with 4-chlorophenyl-sulphonyl chloride (ClPhSOCl) in a mol ratio of 1-100, preferably using excess PhCl, at 100-250 deg C and 1-50 bar, preferably at boiling pt. under normal or autogenous pressure. The catalyst is in the form of a solid bed, and the reaction may be carried out as a continuous process in which excess PhCl is returned to the reactor.

    Production of 4,4'-di:halo-di:phenyl-sulphone

    公开(公告)号:DE19726806A1

    公开(公告)日:1999-01-07

    申请号:DE19726806

    申请日:1997-06-24

    Applicant: BASF AG

    Abstract: A process for the production of 4,4'-dihalo-diphenyl- sulphones (DHDPSO) comprises reacting chloro-, bromo- or fluoro- benzenes with 4-halophenylsulphonyl chlorides of formula (I); in which X = chlorine, bromine or fluorine. The reaction is carried out in the liquid phase at elevated temperature in presence of solid catalysts with acid centres, comprising (K1) layer silicates with negative layer charges neutralised by protons and essentially not doped with Lewis acids, (K2) zeolites in the acidic H-form, or (K3) mixed oxides with acid centres, consisting of a combination of (a) oxides of titanium, zirconium, hafnium, tin, iron or chromium(III) with (b) oxides of vanadium, chromium(VI), molybdenum, tungsten or scandium, or sulphated or phosphatised oxides of group (a), such mixed oxides having been calcined at 450-800 deg C after combination. Preferably type (K1) comprises aluminium silicate in which part of the silicon is replaced by aluminium and/or part of the Al is replaced by magnesium, especially a montmorillonite. Type (K2) comprises zeolites of structural types MFI, MEL, BOG, BEA, EMT, MOR, FAU, MTW, LTL, NES, CON or MCM 22, especially 12-ring zeolites of the BETA, Y, EMT or mordenite type, or 10-ring zeolites of the pentasil type. Type (K3) may be super-acid mixed oxides, preferably with group (a) oxides and group (b) oxides in a mol ratio of (70:30)-(98:2). The process comprises reacting chlorobenzene (PhCl) with 4-chlorophenyl-sulphonyl chloride (ClPhSOCl) in a mol ratio of 1-100, preferably using excess PhCl, at 100-250 deg C and 1-50 bar, preferably at boiling pt. under normal or autogenous pressure. The catalyst is in the form of a solid bed, and the reaction may be carried out as a continuous process in which excess PhCl is returned to the reactor.

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