公开(公告)号：WO9815589A3

公开(公告)日：1998-06-25

申请号：PCT/EP9705204

申请日：1997-09-23

Applicant: BASF AG ,  SIGWART CHRISTOPH ,  ELLER KARSTEN ,  BECKER RAINER ,  PLITZKO KLAUS DIETER ,  FISCHER ROLF ,  STEIN FRANK ,  MUELLER ULRICH ,  HESSE MICHAEL

Inventor： SIGWART CHRISTOPH ,  ELLER KARSTEN ,  BECKER RAINER ,  PLITZKO KLAUS-DIETER ,  FISCHER ROLF ,  STEIN FRANK ,  MUELLER ULRICH ,  HESSE MICHAEL

IPC: C08G65/10 ,  C08G18/48 ,  C08G65/20 ,  C08G65/28 ,  B01J23/24

CPC classification number: C08G65/20 ,  C08G18/4854

Abstract: The invention concerns a process for preparing polytetrahydrofuran, copolymers of tetrahydrofuran and 2-butin-1,4-diol, diesters of these polymers with C2-C20 monocarboxylic acids or monoesters of these polymers with C1-C10 monocarboxylic acids by polymerizing tetrahydrofuran in the presence of one of the following telogens, water, 1,-4-butane diol, 2-butin-1,4-diol, polytetrahydrofuran with a molecular weight of between 200 and 700 Dalton, or of a C1-C10 monocarboxylic acid or a carboxylic acid anhydride produced from C2-C20 monocarboxylic acids or mixtures of these telogens on a heterogeneous carrier catalyst which contains a catalytically active amount of an oxygenous molybdenum and/or tungsten compound on an oxidic carrier material, and which has been calcined at temperatures of between 500 °C and 1000 °C after application of the precursor compounds of the oxygenous molybdenum and/or tungsten compounds to the carrier material precursors. Before it is used as a polymerization catalyst, the catalyst is activated by treatment with a reducing agent.

公开(公告)号：EP0813561A1

公开(公告)日：1997-12-29

申请号：EP96904830

申请日：1996-02-21

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH ,  FISCHER ROLF ,  BECKER RAINER ,  PLITZKO KLAUS-DIETER ,  HEILEN GERD ,  PALM CHRISTOF ,  GROLL PETER

IPC: C08G65/20 ,  C08G65/28 ,  C08G18/67 ,  C08G65/10 ,  C08G65/32

CPC classification number: C08G65/20

Abstract: The invention concerns tetrahydrofuran/but-2-ine-1,4-diol copolymers containing C-C triple bonds, the copolymers having a mean molecular weight Mn of 500 to 3,500 Daltons and containing 0.5 to 3 moles of triple bonds per mole of copolymer, as well as blends of these copolymers with polytetrahydrofuran having a mean molecular weight Mn of 500 to 3,500 Daltons. The invention also concerns a method of producing such copolymers or blends and their use.

公开(公告)号：CA2342178C

公开(公告)日：2008-12-02

申请号：CA2342178

申请日：1999-08-17

Applicant: BASF AG

Inventor： VOIT GUIDO ,  ANSMANN ANDREAS ,  REHFINGER ALWIN ,  MERGER MARTIN ,  MELDER JOHANN-PETER ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF

IPC: C07C209/48 ,  C07B61/00 ,  C07C209/86 ,  C07C211/12

Abstract: The invention relates to a method for the catalytic hydrogenation of adipodinitrile to hexamethylene diamine at a high temperature and at high pressure in the presence of catalysts based on elementary iron as th e catalytic component, and ammonia as a solvent. The method is characterised in that a) adipodinitrile is hydrogenated at temperatures o f 70 to 220 .degree.C and at pressures of 100 to 400 bar in the presence of catalysts based on elementary iron as the catalytic component, and ammoni a as a solvent to produce a mixture containing adipodinitrile, 6-aminocapronitrile, hexamethylene diamine and high boilers, until the sum o f the 6-aminocapronitrile and adipodinitrile concentration is 1 to 50 wt. 3% in relation to the ammonia-free hydrogenation mixture; b) ammonia is separated out of the hydrogenation discharge; c) hexamethylene diamine is separated out of the remaining mixture; d) 6- aminocapronitrile and adipodinitrile are separated from the high boilers together or separately and e) 6-aminocapronitrile, adipodinitrile or their mixtures are returned to step a).

公开(公告)号：MY125884A

公开(公告)日：2006-08-30

申请号：MYPI9801951

申请日：1998-04-30

Applicant: BASF AG

Inventor： FUCHS EBERHARD ,  FISCHER ROLF

IPC: C07D201/08

Abstract: THE DISCLOSURE IS A PROCESS FOR PREPARING CYCLIC LACTAMS OF THE FORMULA 1:WHERE R1 IS HYDROGEN, ALKYL, CYCLOALKYL OR ARYL, AND A IS C3-C12-ALKYLENE UNSUBSTITUTED OR SUBSTITUTED BY 1,2, 3, 4, 5 OR 6 SUBSTITUTUENTS SELECTED INDEPENDENTLY OF ONE ANOTHER FROM THE GROUP CONSISTING OF ALKYL, CYCLOALKYL AND ARYL, BY CONVERSION OF AN W-AMINOCARBONITRILE OF THE FORMULA 2;ER1N -A – CN WHERE R1 AND A ARE EACH AS DEFINED ABOVE, IN THE PRESENCE OF AT LEAST ONE CATALYST, WHICH COMPRISES CONVERTING SAID NITRILE II INTO AN OLIGOMER MIXTURE, AND TREATING WITH SUPERHEATED STEAM.

公开(公告)号：CA2265513C

公开(公告)日：2006-04-04

申请号：CA2265513

申请日：1997-09-01

Applicant: BASF AG

Inventor： EBEL KLAUS ,  FISCHER ROLF ,  FLICK KLEMENS ,  MERGER MARTIN ,  VOIT GUIDO

IPC: B01J23/78 ,  C07C253/30 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C255/24

Abstract: Process for the manufacture of aliphatic alpha, omega amino nitriles by partial hydrogenation of aliphatic alpha, omega dinitriles in the presence of a catalyst, characterized by the fact that a catalyst is use d for partial hydrogenation containing (a) iron or a compound based on iron or its mixtures and (b) 0.01 - 5 wt % related to (a) of a promotor o n the basis of 2,3,4 or 5 elements selected from aluminium, silicon, zirconium, titanium and vanadium and (c) 0 - 5 wt % related to (a) of a compound based on an alkali metal or alkaline earth metal.

公开(公告)号：MY119330A

公开(公告)日：2005-05-31

申请号：MYPI9703536

申请日：1997-08-02

Applicant: BASF AG

Inventor： ROPER MICHAEL ,  PACIELLO ROCCO ,  SCHNURR WERNER ,  FISCHER ROLF

IPC: C07C255/00 ,  B01J31/18 ,  B01J31/24 ,  C07C209/26 ,  C07C253/30 ,  C07C255/24 ,  C07F9/6574

Abstract: MANUFACTURE OF 6-AMINOCAPRONITRILE OR 6-AMINOCAPRONITRILE/ HEXAMETHYLENEDIAMINE DIAMINE MIXTURES, INVOLVINGA)THE REACTING AT LEAST ONE PENTENENITRILE SELECTED FROM THE GROUP CONSISTING OF 2,3 AND 4-PENTENENITRILE, WITH CARBON MONOXIDE AND HYDROGEN IN THE PRESENCE OF A CATALYST, WITH CONTAIN AT LEAST ONE ELEMENT OF THE EIGHTH SUBGROUP AS ACTIVE COMPONENT ,OBTAIN A HYDROFORMYLATION FORMYLATING DISCHARGE (I), B)THE OPTIONAL SEPARATION OF CARBON MONOXIDE, HYDROGEN AND THE CATALYST FROM THE HYDROFORMYLATION FORMYLATING DISCHARGE (I), OBTAIN A HYDROFORMYLATION FORMYLATING DISCHARGE (II),C)THE SEPARATION OF 5-FORMYL VALERONITRILE FROM THE HYDROGENATION FORMYLATING DISCHARGE (I) OR (II),D)THE REACTION OF 5-FORMYL VALERONITRILE WITH AMMONIA AND HYDROGEN IN THE PRESENCE OF A HYDROGENATION CATALYST SELECTED FROM THE GROUP CONSISTING OF RHENIUM, COPPER AND ITS COMPOUNDS AS WELL AS METALS AND METALLIC COMPOUNDS OF THE EIGHT GROUP, OBTAINING A HYDROGENATION DISCHARGE , AND E)OBTAINING 6-AMINOCAPRONITRILE AND IF NECESSARY HEXAMETHYLENE- DIAMINE .

公开(公告)号：ES2224250T3

公开(公告)日：2005-03-01

申请号：ES97925004

申请日：1997-05-28

Applicant: BASF AG

Inventor： FISCHER ROLF ,  PINKOS ROLF ,  SCHAFER MARTIN ,  HOHN ARTHUR ,  SCHWAB PETER

IPC: B01J23/36 ,  B01J23/72 ,  B01J31/24 ,  C07B61/00 ,  C07C41/01 ,  C07C41/26 ,  C07C41/30 ,  C07C43/13 ,  C07C43/15 ,  C07C43/178 ,  C07D307/08

Abstract: PROCEDIMIENTO PARA LA OBTENCION DE TETRAHIDROFURANO MEDIANTE LA REACCION DE ETERES DE 1,4 - BUTENDIOL DE FORMULA (I) RO CH 2 - CH = CH - CH 2 - OR Y/O (II) - RO - CH SUB,2 - CH 2 = CH - CH 2 - OR, EN LAS CUALES LOS RADIC ALES R PUEDEN SER IGUALES O DIFERENTES, Y SON RADICALES DE ALQUILO DE C 1 -C 15 O CICLOALQUILO, DE RADICALES ARILO DE C 6 -C 12 O RADICALES ARALQUILO DE C 7 C 15 , CON AGUA E HIDROGENO A TEMPERATURAS DE 20 A 300° C Y A UNA PRESION DE 1 A 300 BARES EN PRESENCIA DE CATALIZADORES O COMBINACIONES CATALITICAS, QUE TAMBIEN CONTIENEN COMPONENTES, QUE SE PUEDEN HIDROGENAR, Y QUE TAMBIEN TIENEN CENTROS ACIDOS O BASICOS, ASI COMO UN NUEVO PROCEDIMIENTO PARA LA OBTENCION DE LOS ETERES DE 1,4 - BUTENDIOL DE FORMULA (I) MEDIANTE METATESIS.

公开(公告)号：MY118960A

公开(公告)日：2005-02-28

申请号：MYPI9903711

申请日：1999-08-27

Applicant: BASF AG

Inventor： FISCHER ROLF ,  XDFLER PETER BA DR ,  LUYKEN HERMANN ,  OHLBACH FRANK ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  ANSMANN ANDREAS ,  ALWIN REHFINGER DR ,  VOIT GUIDO

IPC: C07C209/48 ,  C07B61/00 ,  C07C209/86 ,  C07C211/12

Abstract: A PROCESS FOR CATALYTIC HYDROGENATION OF ADIPONITRILE TO HEXAMETHYLENEDIAMINE AT ELEVATED TEMPERATURE AND ELEVATED PRESSURE IN THE PRESENCE OF CATALYSTS BASED ON ELEMENTAL IRON AS CATALYTICALLY ACTIVE COMPONENT AND AMMONIA AS SOLVENT COMPRISESA) HYDRO

公开(公告)号：CZ294605B6

公开(公告)日：2005-02-16

申请号：CZ76899

申请日：1997-08-21

Applicant: BASF AG

Inventor： FLICK KLEMENS ,  FISCHER ROLF ,  EBEL KLAUS ,  SCHNURR WERNER ,  VOIT GUIDO

IPC: B01J23/75 ,  B01J23/74 ,  B01J23/76 ,  B01J25/00 ,  C07B61/00 ,  C07C253/30 ,  C07C255/24 ,  C07C255/25

Abstract: In the present invention, there is disclosed a catalyst suitable for preparing aliphatic alpha, omega-aminonitriles by partial hydrogenation of aliphatic dinitriles containing: (a) metallic cobalt, a cobalt compound or a mixture thereof wherein the proportion of metallic cobalt based on (a) being from 20 to 100 percent by weight, (b) from 10 to 70 percent by weight, based on the component (a), of metallic iron, iron oxide, a further iron compound or a mixture thereof wherein the proportion of iron oxide based on the component (b) being from 20 to 100 percent by weight, and (c) from 0 to 1 percent by weight, based on the sum of the component (a) and (b), of a compound based on an alkali metal, an alkaline earth metal or zinc. Disclosed is also a process for preparing aliphatic alpha, omega-aminonitriles by partial hydrogenation of aliphatic dinitriles at elevated temperature and elevated pressure being carried out in the presence of the above-described catalyst, preferably at pressure ranging within 2 to 30 MPa and temperature in the range of 20 to 150 degC.

公开(公告)号：DE59910856D1

公开(公告)日：2004-11-18

申请号：DE59910856

申请日：1999-07-15

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH ,  NARBESHUBER THOMAS ,  GEHRER EUGEN ,  FISCHER ROLF ,  STEINBRENNER ULRICH ,  LIANG SHELUE

IPC: C08F4/06 ,  C08F4/10 ,  C08F4/12 ,  C08F4/18 ,  C08F4/24 ,  C08F4/26 ,  C08F110/10

Abstract: A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 60 mol % and an average molecular weight Mn of 800-3000 dalton by cationic polymerization in the liquid phase of isobutene over an acidic, essentially halogen-free heterogeneous catalyst, wherea) a hydrocarbon mixture of essentially C4-hydrocarbons comprising isobutene in an amount of from 10 to 80% by weight is used as the starting material andb) polymerization is carried out continuously at from -30 to 0° C. with average starting material residence times of one hour or less, where the temperature and the residence time are selected such that the isobutene conversion is less than 60% and, after separation from the resulting polyisobutene, the isobutene is either enriched in the partially converted hydrocarbon mixture and returned to the polymerization or passed to another isobutene reaction coupled with the polymerization.