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    Poly:glycerine fatty acid ester mixts. - for use as emulsifiers for water-in-oil cosmetic and pharmaceutical emulsions
    12.
    发明专利
    Poly:glycerine fatty acid ester mixts. - for use as emulsifiers for water-in-oil cosmetic and pharmaceutical emulsions 未知

    公开(公告)号：DE4005819A1

    公开(公告)日：1991-08-29

    申请号：DE4005819

    申请日：1990-02-23

    Applicant: BASF AG

    Inventor： OPPENLAENDER KNUT DR ,  WEGNER BRIGITTE DR ,  STORK KARL DR ,  FROSCH FRANZ DR ,  WEKEL HANS-ULRICH DR

    IPC: A61K8/06 ,  A61K8/39 ,  A61Q19/00 ,  C07C69/33 ,  C09K23/00 ,  C09K23/34

    Abstract: Polyglycerine fatty acid ester mixts. (I) obtd. by partial esterification of polyglycerine mixts. can be used as emulsifiers in cosmetic and pharmaceutical prepns. The polyglycerine mixts. consist of 0-5 wt% monoglycerine, 15-40 wt% diglycerine, 30-55 wt% triglycerine, 10-25 wt% tetraglycerine, 0-15 wt% pentaglycerine, 0-10 wt% hexaglycerine and 0-5 wt% higher polyglycerines and are partially esterified to a deg. of 20-70% with at least one unsatd. 16-22C fatty acid contg. up to 10 wt% satd. 16-22C fatty acids. USE/ADVANTAGE - (I) can be used as water-in-oil emulsifiers in cosmetic and pharmaceutical prepns. with considerably improved storage stability with the cosmetics and pharmaceuticals emulsified in them, than is usual with water-in-oil emulsions which are more difficult to stabilise than oil-in-water emulsions. Using (I) it is possible to use lower concentrations to achieve the same effect than is the case with conventional emulsifiers. There is no need to bleach (I) after they have been prepd.; thus prods. using (I) are better tolerated by the stain and the body.

    14.
    发明专利
    未知

    公开(公告)号：ES2052289T3

    公开(公告)日：1994-07-01

    申请号：ES91102066

    申请日：1991-02-14

    Applicant: BASF AG

    Inventor： OPPENLAENDER KNUT DR ,  WEGNER BRIGITTE DR ,  STORK KARL DR ,  FROSCH FRANZ DR ,  WEKEL HANS-ULRICH DR

    IPC: A61K8/06 ,  A61K8/39 ,  A61K9/00 ,  A61K47/14 ,  A61Q19/00 ,  C07C69/33 ,  C09K23/00 ,  C09K23/34 ,  B01F17/34 ,  A61K7/00

    Abstract: Use of mixtures of polyglycerol fatty acid esters obtainable by partial esterification of polyglycerol mixtures composed of 0 to 5% by weight of monoglycerol, 15 to 40% by weight of diglycerol, 30 to 55% by weight of triglycerol, 10 to 25% by weight of tetraglycerol, 0 to 15% by weight of pentaglycerol, 0 to 10% by weight of hexaglycerol and O to 5% by weight of higher polyglycerols with at least one saturated fatty acid with 12 to 22 C atoms or at least one unsaturated fatty acid with 16 to 22 C atoms, where the unsaturated fatty acid or fatty acid mixture employed can also contain up to 10% by weight of saturated fatty acids with 16 to 22 C atoms, and the degree of esterification of the saturated or unsaturated fatty acids in the mixture is between 20 and 70%, as emulsifiers in cosmetic and pharmaceutical compositions.

    15.
    发明专利
    未知

    公开(公告)号：DE59101481D1

    公开(公告)日：1994-06-01

    申请号：DE59101481

    申请日：1991-02-14

    Applicant: BASF AG

    Inventor： OPPENLAENDER KNUT DR ,  WEGNER BRIGITTE DR ,  STORK KARL DR ,  FROSCH FRANZ DR ,  WEKEL HANS-ULRICH DR

    IPC: A61K8/06 ,  A61K8/39 ,  A61K9/00 ,  A61K47/14 ,  A61Q19/00 ,  C07C69/33 ,  C09K23/00 ,  C09K23/34 ,  B01F17/34 ,  A61K7/00

    Abstract: Use of mixtures of polyglycerol fatty acid esters obtainable by partial esterification of polyglycerol mixtures composed of 0 to 5% by weight of monoglycerol, 15 to 40% by weight of diglycerol, 30 to 55% by weight of triglycerol, 10 to 25% by weight of tetraglycerol, 0 to 15% by weight of pentaglycerol, 0 to 10% by weight of hexaglycerol and O to 5% by weight of higher polyglycerols with at least one saturated fatty acid with 12 to 22 C atoms or at least one unsaturated fatty acid with 16 to 22 C atoms, where the unsaturated fatty acid or fatty acid mixture employed can also contain up to 10% by weight of saturated fatty acids with 16 to 22 C atoms, and the degree of esterification of the saturated or unsaturated fatty acids in the mixture is between 20 and 70%, as emulsifiers in cosmetic and pharmaceutical compositions.

    17.
    发明专利
    未知

    公开(公告)号：DE4125752A1

    公开(公告)日：1993-02-04

    申请号：DE4125752

    申请日：1991-08-03

    Applicant: BASF AG

    Inventor： MEYER HARALD DR ,  DENZINGER WALTER ,  SANNER AXEL DR ,  REINHARDT ROLF-DIETER DR ,  FROSCH FRANZ DR ,  RAUBENHEIMER HANS-JUERGEN

    IPC: A01N59/12 ,  A61K8/73 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q5/12 ,  C08F220/34 ,  C08F226/00 ,  C08F251/00 ,  C11D3/00 ,  C11D3/22 ,  C11D3/37

    Abstract: Polymers of ethylenically unsaturated compounds containing at least one covalently bonded N atom in the molecule, polymerised in the presence of monosaccharides, oligosaccharides, polysaccharides or derivatives thereof, obtainable by free-radical-initiated copolymerisation of (A) monomers or monomer mixtures from the group consisting of (a) N-vinylimidazoles which are substituted on the heterocyclic ring by up to three C1- to C12-alkyl radicals and can be present in N-quaternary form or in salt form, (b) five- to eight-membered N-vinyllactams which can be substituted on the ring by up to three C1- to C12-alkyl radicals, (c) dialkylaminoalkyl acrylates or methacrylates which have a total of up to 30 C atoms in the dialkylaminoalkyl radical and can be present in N-quaternary form or in salt form, (d) N-(dialkylaminoalkyl)acrylamide or N-(dialkylaminoalkyl)methacrylamide which has a total of up to 30 C atoms in the dialkylaminoalkyl radical and can be present in N-quaternary form or in salt form, and (e) diallyl-C1- to C12-alkylamines or salts thereof or diallyldi(C1- to C12-alkyl) ammonium compounds, where as further comonomers to (A) additionally (f) monoethylenically unsaturated C3- to C10-carboxylic acids and alkali metal salts, alkaline earth metal salts or ammonium salts thereof, (g) monoethylenically unsaturated C3- to C10-carboxylic acid esters and (h) small amounts of compounds containing at least two ethylenically unsaturated, non-conjugated double bonds in the molecule can be present, in the presence of (B) monosaccharides, oligosaccharides, polysaccharides, thermally or mechanically treated, oxidatively, hydrolytically or enzymatically degraded polysaccharides, oxidised, hydrolytically or enzymatically degraded polysaccharides, chemically modified mono-, oligo- and polysaccharides or mixtures of the aforementioned compounds (B) in the ratio by weight (A):(B) of (95 to 20):(5 to 80). The polymers are suitable for use as film-forming conditioners in cosmetic preparations and as stabilisers for perfumes and perfume oils.

    Use of mixts. of poly:glycerol fatty acid ester(s)
    18.
    发明专利
    Use of mixts. of poly:glycerol fatty acid ester(s) 未知

    公开(公告)号：DE4023593A1

    公开(公告)日：1992-01-30

    申请号：DE4023593

    申请日：1990-07-25

    Applicant: BASF AG

    Inventor： OPPENLAENDER KNUT DR ,  WEGNER BRIGITTE DR ,  FROSCH FRANZ DR ,  WEKEL HANS-ULRICH DR

    IPC: A61K8/06 ,  A61K8/39 ,  A61K9/00 ,  A61K9/107 ,  A61K47/14 ,  A61Q19/00 ,  C07C69/33 ,  C09K23/00 ,  C09K23/34

    Abstract: The use of mixts. (I) of polyglycerol (PG) fatty acid esters obtd. by partial esterification fo PG mixts. (PGM) with at least one 12-22C fatty acid or 16-22C unsatd. fatty acid as emulsifiers in cosmetic and pharmaceutical prepns. is new. PGM comprises (wt.%): monoglycerol (A) (0-5), diglycerol (B) (15-40), triglycerol (C) (30-55), tetraglycerol (D) (10-25), pentaglycerol (E) (0-15), hexaglycerol (F) (0-10) and higher PG (0-5). TGhe unsatd. fatty acid (mixt.) may contain up to 10 wt.% of 16-22C satd. fatty acid and the deg. of esterification of the fatty acids is 20-70%. The amounts of PG in the mixts. are pref. (wt.%): (A) (0-5), (B) (20-40), (C) (35-55), (D) (10-20), (E) (5-10), (F) (1-5) and higher PG (0-5). The fatty acid (mixt.) comprises at least 40 wt.% stearic acid or at least 60 wt.% oleic or erucic acid. The deg. of esterification is 25-50%.

    20.
    发明专利
    未知

    公开(公告)号：DE59207829D1

    公开(公告)日：1997-02-20

    申请号：DE59207829

    申请日：1992-07-22

    Applicant: BASF AG

    Inventor： MEYER HARALD DR ,  DENZINGER WALTER ,  SANNER AXEL DR ,  REINHARDT ROLF-DIETER DR ,  FROSCH FRANZ DR ,  RAUBENHEIMER HANS-JUERGEN

    IPC: A01N59/12 ,  A61K8/73 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q5/12 ,  C08F220/34 ,  C08F226/00 ,  C08F251/00 ,  C11D3/00 ,  C11D3/22 ,  C11D3/37 ,  A61K7/48 ,  A61K7/06

    Abstract: Polymers of ethylenically unsaturated compounds containing at least one covalently bonded N atom in the molecule, polymerised in the presence of monosaccharides, oligosaccharides, polysaccharides or derivatives thereof, obtainable by free-radical-initiated copolymerisation of (A) monomers or monomer mixtures from the group consisting of (a) N-vinylimidazoles which are substituted on the heterocyclic ring by up to three C1- to C12-alkyl radicals and can be present in N-quaternary form or in salt form, (b) five- to eight-membered N-vinyllactams which can be substituted on the ring by up to three C1- to C12-alkyl radicals, (c) dialkylaminoalkyl acrylates or methacrylates which have a total of up to 30 C atoms in the dialkylaminoalkyl radical and can be present in N-quaternary form or in salt form, (d) N-(dialkylaminoalkyl)acrylamide or N-(dialkylaminoalkyl)methacrylamide which has a total of up to 30 C atoms in the dialkylaminoalkyl radical and can be present in N-quaternary form or in salt form, and (e) diallyl-C1- to C12-alkylamines or salts thereof or diallyldi(C1- to C12-alkyl) ammonium compounds, where as further comonomers to (A) additionally (f) monoethylenically unsaturated C3- to C10-carboxylic acids and alkali metal salts, alkaline earth metal salts or ammonium salts thereof, (g) monoethylenically unsaturated C3- to C10-carboxylic acid esters and (h) small amounts of compounds containing at least two ethylenically unsaturated, non-conjugated double bonds in the molecule can be present, in the presence of (B) monosaccharides, oligosaccharides, polysaccharides, thermally or mechanically treated, oxidatively, hydrolytically or enzymatically degraded polysaccharides, oxidised, hydrolytically or enzymatically degraded polysaccharides, chemically modified mono-, oligo- and polysaccharides or mixtures of the aforementioned compounds (B) in the ratio by weight (A):(B) of (95 to 20):(5 to 80). The polymers are suitable for use as film-forming conditioners in cosmetic preparations and as stabilisers for perfumes and perfume oils.

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