公开(公告)号：ES2095051T3

公开(公告)日：1997-02-01

申请号：ES93909900

申请日：1993-05-06

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  DENZINGER WALTER ,  SANNER AXEL ,  RICHTER HANS ,  RAUBENHEIMER HANS-JUERGEN ,  FROSCH FRANZ

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/81 ,  A61K47/32 ,  A61Q5/00 ,  A61Q5/06 ,  A61Q11/00 ,  C08F16/16 ,  C08F20/02 ,  C08F22/10 ,  C08F216/16 ,  C08F216/18 ,  C08F222/04 ,  C08F222/06 ,  C08F222/14 ,  C11D3/37 ,  C11D17/08 ,  A61K7/00

Abstract: Copolymers contain, as characteristic polymerized monomer units, (a) 2 to 50 mol % vinylalkylether with 3 to 30 C atoms in the molecule; (b) 10 to 88 mol % monoethylenically unsaturated dicarboxylic acid anhydrides and (c) 10 to 88 mol % dialkylesters of monoethylenically unsaturated dicarboxylic acids. A process is disclosed for producing these copolymers by copolymerizing the monomers (a), (b) and (c) at temperatures between 40 and 180 C in the presence of radical-building initiators. Also disclosed is the use of the copolymers as film forming resins in hair sprays and in the form of alkaline metal, ammonium or alkaline earth metal salts as thickeners for aqueous systems, such as cosmetic and pharmaceutical compositions, textile printing pastes, liquid washing and cleaning agents.

公开(公告)号：DE19534494A1

公开(公告)日：1997-03-20

申请号：DE19534494

申请日：1995-09-18

Applicant: BASF AG

Inventor： PAULUS WOLFGANG DR ,  BINDER HORST ,  ETZBACH KARL-HEINZ DR ,  SCHUHMACHER PETER DR ,  SIEMENSMEYER KARL DR ,  BLEYL INGO ,  HAARER DIETRICH PROF DR ,  MEYER HARALD DR ,  SIMMERER JUERGEN

IPC: C09K11/06 ,  C09K19/12 ,  C09K19/32 ,  C09K19/34 ,  C09K19/60 ,  H01L31/101 ,  H01L33/08 ,  H01L51/00 ,  H01L51/30 ,  H01L29/76 ,  H01L33/00

Abstract: Transistor has parallel planar source and drain electrodes (1, 2) which are 0.01-100 mu m apart, gate electrode(s) (3) which have the same dimensions as the source and drain electrodes and are placed parallel to and between them, and a layer (4) of discotic columnar liquid crystalline material (I) between the source and drain electrodes with the columnar axis oriented perpendicular to the surface of these electrodes. Also claimed is electronic or electro-optical equipment contg. this transistor.

公开(公告)号：DE59207287D1

公开(公告)日：1996-11-07

申请号：DE59207287

申请日：1992-11-13

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  SANNER AXEL DR ,  REINHARDT ROLF-DIETER DR ,  FROSCH FRANZ DR ,  RAUBENHEIMER HANS-JUERGEN

IPC: A61K8/72 ,  A61K8/00 ,  A61Q5/00 ,  A61Q90/00 ,  C02F1/56 ,  C04B24/26 ,  C08F8/44 ,  C08F26/06 ,  C09K8/035 ,  C09K8/46 ,  C09K8/88 ,  C11B3/00 ,  C11B13/00 ,  H01B1/12 ,  A61K7/06

公开(公告)号：ES2074608T3

公开(公告)日：1995-09-16

申请号：ES91108922

申请日：1991-05-31

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  SANNER AXEL DR ,  RAUBENHEIMER HANS-JUERGEN ,  FROSCH FRANZ DR

IPC: C08F4/32 ,  A61K8/72 ,  A61K8/81 ,  C08F2/06 ,  C08F4/28 ,  C08F4/34 ,  C08F8/12 ,  C08F8/14 ,  C08F16/12 ,  C08F20/02 ,  C08F22/10 ,  C08F216/12 ,  C08F216/18 ,  C08F222/02 ,  C08F222/06 ,  C08F222/16

Abstract: The preparation of copolymers of monoalkyl maleates or maleic acid and salts thereof and vinyl alkyl ethers by free-radical copolymerisation of maleic anhydride and vinyl alkyl ethers and subsequent reaction with alkanol or water and optionally metal hydroxides and/or oxides, where the vinyl alkyl ether component is in excess in the reaction mixture in each phase of the polymerisation, the free-radical copolymerisation is carried out in acetone, and the acetone is removed by distillation during or after the esterification or hydrolysis, the polymerisation initiators used being carboxylic acid peroxy esters derived from carboxylic acids having at least 8 carbon atoms. The copolymers obtained are used in cosmetic preparations.

公开(公告)号：DE59207829D1

公开(公告)日：1997-02-20

申请号：DE59207829

申请日：1992-07-22

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  DENZINGER WALTER ,  SANNER AXEL DR ,  REINHARDT ROLF-DIETER DR ,  FROSCH FRANZ DR ,  RAUBENHEIMER HANS-JUERGEN

IPC: A01N59/12 ,  A61K8/73 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q5/12 ,  C08F220/34 ,  C08F226/00 ,  C08F251/00 ,  C11D3/00 ,  C11D3/22 ,  C11D3/37 ,  A61K7/48 ,  A61K7/06

Abstract: Polymers of ethylenically unsaturated compounds containing at least one covalently bonded N atom in the molecule, polymerised in the presence of monosaccharides, oligosaccharides, polysaccharides or derivatives thereof, obtainable by free-radical-initiated copolymerisation of (A) monomers or monomer mixtures from the group consisting of (a) N-vinylimidazoles which are substituted on the heterocyclic ring by up to three C1- to C12-alkyl radicals and can be present in N-quaternary form or in salt form, (b) five- to eight-membered N-vinyllactams which can be substituted on the ring by up to three C1- to C12-alkyl radicals, (c) dialkylaminoalkyl acrylates or methacrylates which have a total of up to 30 C atoms in the dialkylaminoalkyl radical and can be present in N-quaternary form or in salt form, (d) N-(dialkylaminoalkyl)acrylamide or N-(dialkylaminoalkyl)methacrylamide which has a total of up to 30 C atoms in the dialkylaminoalkyl radical and can be present in N-quaternary form or in salt form, and (e) diallyl-C1- to C12-alkylamines or salts thereof or diallyldi(C1- to C12-alkyl) ammonium compounds, where as further comonomers to (A) additionally (f) monoethylenically unsaturated C3- to C10-carboxylic acids and alkali metal salts, alkaline earth metal salts or ammonium salts thereof, (g) monoethylenically unsaturated C3- to C10-carboxylic acid esters and (h) small amounts of compounds containing at least two ethylenically unsaturated, non-conjugated double bonds in the molecule can be present, in the presence of (B) monosaccharides, oligosaccharides, polysaccharides, thermally or mechanically treated, oxidatively, hydrolytically or enzymatically degraded polysaccharides, oxidised, hydrolytically or enzymatically degraded polysaccharides, chemically modified mono-, oligo- and polysaccharides or mixtures of the aforementioned compounds (B) in the ratio by weight (A):(B) of (95 to 20):(5 to 80). The polymers are suitable for use as film-forming conditioners in cosmetic preparations and as stabilisers for perfumes and perfume oils.

公开(公告)号：DE4213972A1

公开(公告)日：1993-11-04

申请号：DE4213972

申请日：1992-04-29

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  SANNER AXEL DR ,  FROSCH FRANZ DR ,  RICHTER HANS DR

IPC: C08K5/41 ,  C08F16/12 ,  C08F216/14 ,  C08K3/00 ,  C08K3/30 ,  C08K3/32 ,  C08K5/00 ,  C08K5/1535 ,  C08L29/10 ,  C08L33/02 ,  C08L35/00 ,  C08L35/08 ,  C08K5/13

Abstract: PCT No. PCT/EP93/00954 Sec. 371 Date Sep. 30, 1994 Sec. 102(e) Date Sep. 30, 1994 PCT Filed Apr. 20, 1993 PCT Pub. No. WO93/22374 PCT Pub. Date Nov. 11, 1993A process for stabilizing a copolymer of maleic acid or maleic anhydride and vinyl alkyl ethers against a reduction in molecular weight in aqueous solution or in the solution of an organic solvent by adding 0.001 to 10% by weight, based on the copolymer, of a reducing agent, a tert-butyl-containing phenol or a mixture thereof.

公开(公告)号：DE4207900A1

公开(公告)日：1993-09-16

申请号：DE4207900

申请日：1992-03-12

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  DENZINGER WALTER ,  SANNER AXEL DR ,  HARTMANN HEINRICH DR

IPC: C07D319/12 ,  A61K8/00 ,  A61K8/72 ,  A61K8/81 ,  A61Q5/00 ,  C08F2/10 ,  C08F20/02 ,  C08F20/34 ,  C08F20/52 ,  C08F26/10 ,  C08F28/00 ,  C08F220/04 ,  C08F220/06 ,  C08F220/34 ,  C08F220/58 ,  C08F220/60 ,  C08F222/06 ,  C08F226/06 ,  C08F226/10 ,  C08F226/12 ,  C08F228/02 ,  C11D3/37

Abstract: A process for producing copolymers from monoethylenically unsaturated monomers containing acid groups and from N-vinyl lactames and possibly from other monoethylenically unsaturated monomers by copolymerising the monomers in the presence of radical-forming polymerisation initiators in the manner of solution polymerisation in water at a pH of at least 6. An alkaline metal or earth metal base or a mixture thereof is used to adjust the pH of the aqueous reaction solution.

公开(公告)号：DE4138763A1

公开(公告)日：1993-05-27

申请号：DE4138763

申请日：1991-11-26

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  SANNER AXEL DR ,  REINHARDT ROLF-DIETER DR ,  FROSCH FRANZ DR ,  RAUBENHEIMER HANS-JUERGEN

IPC: A61K8/72 ,  A61K8/00 ,  A61Q5/00 ,  A61Q90/00 ,  C02F1/56 ,  C04B24/26 ,  C08F8/44 ,  C08F26/06 ,  C09K8/035 ,  C09K8/46 ,  C09K8/88 ,  C11B3/00 ,  C11B13/00 ,  H01B1/12

公开(公告)号：DE4343177A1

公开(公告)日：1995-06-22

申请号：DE4343177

申请日：1993-12-17

Applicant: BASF AG

Inventor： TROPSCH JUERGEN DR ,  MEYER HARALD DR ,  RAUBENHEIMER HANS-JUERGEN ,  HOESSEL PETER DR ,  SANNER AXEL DR

IPC: B01D21/01 ,  C02F1/56 ,  C08F2/04 ,  C08F2/06 ,  C08F2/10 ,  C08F4/04 ,  C08F4/28 ,  C08F20/34 ,  C08F26/10 ,  C08F220/34 ,  C08F220/38 ,  C08F226/06 ,  C08F226/10

Abstract: Prepn. of quat. copolymers of (A) 20-99 wt.% N-vinyl lactam(s); (B) 1-80 wt.% dialkylaminoalkyl (meth)acrylate(s) in quat. form and (C) 0-50 wt.% free radical polymerisable comonomer(s) is effected by: (i) quaternising monomer(s) (B) with an alkylating agent; and then (ii) copolymerising the quaternised monomer(s) with (A) and (C).

公开(公告)号：DE4216318A1

公开(公告)日：1993-11-18

申请号：DE4216318

申请日：1992-05-16

Applicant: BASF AG

Inventor： MEYER HARALD DR ,  DENZINGER WALTER ,  SANNER AXEL DR ,  RICHTER HANS DR ,  RAUBENHEIMER HANS-JUERGEN ,  FROSCH FRANZ DR

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/81 ,  A61K47/32 ,  A61Q5/00 ,  A61Q5/06 ,  A61Q11/00 ,  C08F16/16 ,  C08F20/02 ,  C08F22/10 ,  C08F216/16 ,  C08F216/18 ,  C08F222/04 ,  C08F222/06 ,  C08F222/14 ,  C11D3/37 ,  C11D17/08 ,  A61K9/20

Abstract: Copolymers contain, as characteristic polymerized monomer units, (a) 2 to 50 mol % vinylalkylether with 3 to 30 C atoms in the molecule; (b) 10 to 88 mol % monoethylenically unsaturated dicarboxylic acid anhydrides and (c) 10 to 88 mol % dialkylesters of monoethylenically unsaturated dicarboxylic acids. A process is disclosed for producing these copolymers by copolymerizing the monomers (a), (b) and (c) at temperatures between 40 and 180 DEG C in the presence of radical-building initiators. Also disclosed is the use of the copolymers as film forming resins in hair sprays and in the form of alkaline metal, ammonium or alkaline earth metal salts as thickeners for aqueous systems, such as cosmetic and pharmaceutical compositions, textile printing pastes, liquid washing and cleaning agents.