公开(公告)号：DE10035828A1

公开(公告)日：2002-02-21

申请号：DE10035828

申请日：2000-07-22

Applicant: BASF AG

Inventor： SCHMIDT ANDREAS ,  PFEFFINGER JOACHIM ,  KLOETZER MATTHIAS ,  KRASE VOLKER ,  PFAB PETER ,  GUETTES BERND

IPC: C07B43/00 ,  C08J11/28 ,  C07B43/10 ,  C07C263/12 ,  C07C263/20 ,  C07C269/00 ,  C07C269/08 ,  C07C271/06

Abstract: Aminolytic degradation of cross-linked polymer derived from 4-20C diisocyanates having urea, isocyanurate and optionally urethane and/or isocyanate structural units comprises reaction of polymer with aliphatic 8-30C mono- or diamines at 150-450 deg C whereby the reaction is carried out until the polymer has up to 20% of the initial isocyanurate, allophanate or urethane structural units. A process for the aminolytic degradation of cross-linked polymer (P), derived from 4-20C diisocyanates and optionally 1-20C aliphatic alcohols, having urea, isocyanaurate and optionally urethane and/or isocyanate structural units comprises reaction of polymer (P) with aliphatic 8-30C mono- or diamines (A) at 150-450 deg C whereby the reaction is carried out until the polymer is converted to reaction products having upto 20% of the initial isocyanurate, allophanate or urethane structural units.

公开(公告)号：DE19961973A1

公开(公告)日：2001-06-28

申请号：DE19961973

申请日：1999-12-22

Applicant: BASF AG

Inventor： GASSAN MICHAEL ,  GUETTES BERND ,  SANDER MICHAEL ,  KRAUS RUPERT ,  PLAUMANN HEINZ ,  ROTERMUND UDO ,  BIEDERMANN ANJA ,  SEITZ CHRISTIAN ,  REICHELT MICHAEL ,  HEMPEL RENATE

IPC: C08G12/40 ,  C08G18/76

Abstract: An agent for the surface modification of fillers for polyamide compositions comprises: (A) an amino-functional silane, a bis-aminosilane a tertiary aminosilane or an oligomer of these; (B) a mixture of an amino-functional silane, bis-aminosilane and/or tertiary aminosilane and an alkyl-, alkenyl- or polyether-functional silane and optionally an oligomer of these; or (C) a mixture of an alkyl-functional silane and an alkenyl-functional silane and optionally an oligomer of these. An agent for the surface modification of fillers for polyamide compositions comprises either: (A) an agent comprising: (i) an amino-functional silane of formula (Ia); (ii) a bis-aminosilane (Ib); (iii) a tertiary aminosilane (Ic); or an oligomer of (Ia)-(Ic) with a degree of oligomerization (DO) of 2-20; (B) a mixture of: (i) a component comprising (a) an amino-functional silane of formula (IIa), (b) a secondary aminosilane (IIb) and/or (c) a tertiary aminosilane (IIc); and (ii) a component comprising either (a) an alkyl-functional silane of formula (III), (b) an alkenyl-functional silane of formula (IV), (c) a polyether-functional silane of formula (V); and optionally (iii) an oligomer of (IIa)-(IIc) and (III)-(V) with a DO of 2-20; or (C) a mixture of: (i) an alkyl-functional silane of formula (IIIa); and (ii) an alkyl-functional silane of formula (IV); and optionally (iii) an oligomer of (IIIa) and (IV) with a DO of 2-20. RNH-(CH2)3-Si(Me)x(Z)3-x (Ia) Z = 1-3C alkoxy, OH or Cl; x = 0 or 1; and R = 1-20C alkyl, 5-12C cycloalkyl or 6-12C aryl. R-Si(Me)x(Z)3-x (IIa) Z = 1-3C alkoxy, OH or Cl; x = 0 or 1; R = H2N((CH2)2NH)y(CH2)3; and y = 0-2. R'-Si(Me)x(Z)3-x (IIIa) Z = 1-3C alkoxy, OH or Cl; x = 0-1; and R' = optionally fluorinated 1-16C alkyl or cycloalkyl. CH2=CH(CH2)n-Si(Me)x(Z)3-x (IV) Z = 1-3C alkoxy, OH or Cl; x = 0 or 1; and n = 0-20. R(OCH2CHR')nO(CH2)mSi (Me)x(Z)3-x (V) z = 1-3C alkoxy, OH or Cl; x = 0 or ; R = 1-4C alkyl; R' = H or Me; n = 5-20; and m = 2 or 3. Independent claims are also included for the following: (1) a filler surface-modified with the above agent; (2) an article comprising the surface-modified filler; (3) a filled polyamide composition produced using the surface-modified filler; and (4) an article based on the filled polyamide composition.

公开(公告)号：DE19745527A1

公开(公告)日：1999-04-22

申请号：DE19745527

申请日：1997-10-15

Applicant: BASF AG

Inventor： GUETTES BERND ,  HINZ WERNER DR ,  SCHERZER DIETRICH DR ,  TISCHER GERLINDE

IPC: C08B37/00 ,  C08B37/16 ,  C08G18/48 ,  C08G18/66 ,  C08G18/64 ,  C08G18/32 ,  C08G18/38 ,  C09D175/04 ,  C08L75/04

Abstract: Polyurethane containing one or more cyclic polysaccharides with 2-14 sugar units in which at least one of the hydroxyl groups in each unit is alkoxylated. Independent claims are also included for: (a) a process for the production of this PUR by reacting polyisocyanates with compounds containing at least two reactive hydrogens in presence of a premixed combination of alkoxylated cyclic polysaccharide(s) as above (ACP) and amine(s); (b) complexes of amines and ACP; (c) a process for the production of these complexes by bringing the ACP and amine into contact; (d) polyurethane obtained by process (a); (e) foam, fibres, film, coatings, paints and moldings containing PUR as above.

公开(公告)号：CA2246634A1

公开(公告)日：1999-04-08

申请号：CA2246634

申请日：1998-10-07

Applicant: BASF AG

Inventor： GUETTES BERND ,  FRITZ RALF ,  REICHELT MICHAEL ,  PRETZSCH REGINA

IPC: C07F9/40 ,  C08G18/28 ,  C08G18/38 ,  C08G18/66 ,  C08K5/5333 ,  C08G18/65 ,  C07F9/655

Abstract: Dialkyl hydroxyalkanephosphonates are prepared by a process in which a phosphonate is reacted with an aldehyde in the presence of a basic catalyst. Polyurethanes, in particular polyurethane foams, are prepared using dialkyl hydroxyalkanephosphonates.

公开(公告)号：DE19630787A1

公开(公告)日：1998-02-05

申请号：DE19630787

申请日：1996-07-31

Applicant: BASF AG

Inventor： GUETTES BERND ,  DINSCH STEFAN ,  KNORR GOTTFRIED DR ,  SEIFERT HOLGER DR

IPC: C08J9/12 ,  C08G18/50 ,  C08G18/65 ,  C08G101/00 ,  C08G18/66 ,  C08G65/26 ,  C08L75/04 ,  C08J9/04 ,  E04B1/76 ,  F25D23/06

Abstract: A process for the production of polyurethanes (PUR) with improved curing properties, by reacting (a) unmodified and/or modified di- and/or poly-isocyanates with (b) polyether-polyols based on aromatic amines and obtained by stepwise alkylene oxide addition using special amine combinations (b1) and optionally other co-initiators, optionally together with other high-mol.wt. compounds with at least two reactive hydrogens, and optionally (c) chain extenders and/or crosslinkers, in presence of (d) blowing agents, (e) catalysts and (f) other additives etc. (b1) comprises a mixture of amines of the diphenylmethane series (MDA), containing amines with 4, 3, more than 4, and 2 nuclei in amounts of 5-20, 15-30, 20-35 and 25-50 wt% respectively (total 100 wt%), in combination with other aromatic amines.

公开(公告)号：DE19605510A1

公开(公告)日：1997-08-21

申请号：DE19605510

申请日：1996-02-15

Applicant: BASF AG

Inventor： FRITZ RALF DR ,  GUETTES BERND ,  PRETZSCH REGINA ,  REICHELT MICHAEL ,  SCHUSTER MARITA

IPC: C07C41/03 ,  C08G18/50 ,  C08G18/64 ,  C08G59/14 ,  C08G59/62 ,  C08G65/26 ,  C08G65/28 ,  C07C43/13 ,  C07C43/178 ,  C07C43/23 ,  C08G18/48 ,  C08G18/58 ,  C08G59/04 ,  C08L75/00 ,  C09K21/14

Abstract: The production of bromine-containing polyols (I) comprises reacting organic compounds (II) containing at least one bromine atom and at least one hydroxyl group with organic compounds (III) containing at least two epoxide groups. Also claimed are polyols (I) obtained by this process.

公开(公告)号：DE19601410A1

公开(公告)日：1997-07-24

申请号：DE19601410

申请日：1996-01-17

Applicant: BASF AG

Inventor： HEINRICH HORST ,  GUETTES BERND ,  SCHUSTER MARITA

IPC: C08G18/10 ,  C08G18/40 ,  C08G18/42 ,  C08G18/76 ,  C08G18/30 ,  C08G18/65 ,  C08G18/48 ,  C08G18/82 ,  B29C67/20 ,  C08L75/06 ,  C08L75/08 ,  C08J9/08

Abstract: A process for the production of flexible polyurethane foam by reacting (a) unmodified and/or modified isocyanate compounds with (b) high-mol. wt. compounds with at least 2 reactive hydrogen atoms and optionally (c) low-mol. wt. chain extenders and/or crosslinkers, in presence of (d) blowing agents, (e) catalysts, (f) fire retardants and optionally (g) other additives etc. In this process, component (a) comprises prepolymers obtained by reaction of (a1) polyester-polyols and/or polyether-ester-polyols with (a2) aromatic diisocyanates, followed by a special after-treatment.

公开(公告)号：DE4318962A1

公开(公告)日：1994-12-15

申请号：DE4318962

申请日：1993-06-08

Applicant: BASF AG

Inventor： HINZ WERNER DR ,  HENN ROLF DR ,  KEPPELER UWE DR ,  GUETTES BERND

IPC: C08G18/48 ,  C08G18/66 ,  C08G65/26 ,  C08G65/28 ,  C08G65/333 ,  C08J9/14 ,  C08L75/08

Abstract: The invention relates to a process for the production of rigid polyurethane foams by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts and optionally f) auxiliaries and/or additives, where the relatively high-molecular-weight compounds containing at least two reactive hydrogen atoms (b) are polyoxyproylene-polyols and/or polyoxyethylene-polyoxypropylene-polyols containing up to 20 % by weight, based on the weight of the alkylene oxide units, of pendant oxyethylene units containing secondary hydroxyl groups, and having a functionality of from 3.8 to 4.1, a hydroxyl number of from 385 to 410 mg of KOH/g, a viscosity of from 1,700 to 2,400 mPas at 25@C, preparable by anionic polymerisation of 1,2-propylene oxide and, where appropriate, ethylene oxide onto an initiator (starter) molecule mixture comprising sucrose, pentaerythritol and diethylene glycol.

公开(公告)号：AT260309T

公开(公告)日：2004-03-15

申请号：AT97111491

申请日：1997-07-08

Applicant: BASF AG

Inventor： GUETTES BERND ,  DINSCH STEFAN ,  STEINCHEN KARL-HEINZ ,  HOEPPNER GERD ,  WAGNER KLAUS ,  LARBIG HARALD ,  LUTTER HEINZ-DIETER

IPC: C08G18/48 ,  C08G65/28 ,  C08G65/30

Abstract: A process for the production of flexible polyurethane foam comprises reacting: (a) optionally modified polyisocyanates with: (b) compounds with reactive hydrogens, and (c) optionally chain extenders and/or crosslinkers, in presence of: (d) blowing agents, (e) catalysts, (f) fire retardants, and optionally: (g) other additives etc. At least 10 wt% of the compounds used in this process comprises polyether-polyols obtained by base-catalysed reaction of lower alkylene oxides with hydroxy-functional starters and subjected, during or after alkylene oxides-addition and with a water content of not more than 0.1 wt.%, to distillation at temperatures above 49 degrees C.

公开(公告)号：DE59610390D1

公开(公告)日：2003-06-05

申请号：DE59610390

申请日：1996-05-30

Applicant: BASF AG

Inventor： DINSCH STEFAN ,  PRETZSCH REGINA ,  WINKLER JUERGEN ,  GUETTES BERND ,  STEINCHEN KARL-HEINZ

IPC: C08G18/48 ,  C08G18/50 ,  C08G65/26

Abstract: The prodn. of aromatic polyether-polyols (I) comprises alkoxylation at 70-135 degrees C and 0.1-1.0 MPa of an H-functional starter consisting of a mixt. of at least 95 wt% 2,3- and 3,4- toluylenediamine (TDA), 0.5-4 wt% 2,4- and 2,6-TDA and 0.1-1.5 wt% volatile fractions from TDA prodn. Also claimed are polyols (I) obtd. by this process.