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公开(公告)号:DE102006009838A1
公开(公告)日:2007-09-06
申请号:DE102006009838
申请日:2006-03-01
Applicant: BASF AG
Inventor: MAAS STEFFEN , JOHANN THORSTEN , KOCH MICHAEL , SIRCH TILMAN , SCHLITTER STEPHAN , RITTINGER STEFAN , STEINIGER MICHAEL
IPC: C07C29/141 , B01J23/72 , C07C31/18 , C07C31/20
Abstract: A process for catalytically hydrogenating methylolalkanals of the general formula in which R1 and R2 are each independently a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase over a hydrogenation catalyst, which comprises setting a pH of from 7.0 to 9.0 in the hydrogenation effluent by adding at least one tertiary amine, an inorganic base or an inorganic or organic acid to the hydrogenation feed.
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公开(公告)号:DE102005049135A1
公开(公告)日:2007-04-19
申请号:DE102005049135
申请日:2005-10-14
Applicant: BASF AG
Inventor: JOHANN THORSTEN , MAAS STEFFEN , SCHLITTER STEPHAN , SIRCH TILMAN , KOCH MICHAEL , RITTINGER STEFAN , STEINIGER MICHAEL , PETERSEN HERMANN
IPC: B01J35/02 , B01J37/03 , C07C29/141
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公开(公告)号:ES2241684T3
公开(公告)日:2005-11-01
申请号:ES00987470
申请日:2000-12-28
Applicant: BASF AG
Inventor: DERNBACH MATTHIAS , KRATZ DETLEF , DR STAMMER ACHIM , HAAKE MATHIAS , KOCH MICHAEL , SCHULZ GERHARD
IPC: C07B61/00 , C07C29/141 , C07C29/80 , C07C29/90 , C07C31/22
Abstract: Procedimiento para la mejora del índice de color de alcoholes polivalentes del grupo constituido por trimetiloletano, trimetilolpropano, trimetilolbutano, neopentilglicol y pentaeritrita, en especial trimetilolpropano, mediante hidrogenado catalítico, caracterizado porque el alcohol polivalente empleado en el hidrogenado se purificó mediante destilación tras su obtención.
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公开(公告)号:BR0016758A
公开(公告)日:2002-09-24
申请号:BR0016758
申请日:2000-12-28
Applicant: BASF AG
Inventor: DERNBACH MATTHIAS , KRATZ DETLEF , STAMMER ACHIM , HAAKE MATHIAS , KOCH MICHAEL , SCHULZ GERHARD
IPC: C07B61/00 , C07C29/141 , C07C29/80 , C07C29/90 , C07C31/22
Abstract: A process for greatly improving the color index of polyhydric alcohols, especially trimethylolpropane, by hydrogenation comprises using, in the hydrogenation, an alcohol which has already been purified by distillation. The catalysts used are those conventionally employed in hydrogenations, preferably copper, nickel, palladium or ruthenium catalysts.
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公开(公告)号:DE10104224A1
公开(公告)日:2002-08-01
申请号:DE10104224
申请日:2001-01-31
Applicant: BASF AG
Inventor: HAAKE MATHIAS , SCHWAB EKKEHARD , KOCH MICHAEL , MUELLER HANS-JOACHIM , STROEZEL MANFRED
IPC: B01J21/18 , B01J23/44 , B01J32/00 , B01J35/02 , B01J35/06 , B01J35/10 , C07B35/02 , C07C29/17 , C07C51/487 , C07C63/26 , B01J37/00 , C07C31/125
Abstract: A process for the purification of crude terephthalic acid comprises catalytic hydrogenation using a catalyst material (I) comprising a ca bon supported hydrogenation metal whereby the carbon support comprises carbon fibers. Independent claims are included for: (1) the catalyst material (I) whereby the carbon support has a BET surface area of less than 500 Micro 2>/g; (2) a reactor (II) containing a flat catalyst material in the form of cloth, textile and/or felt comprising a hydrogenation metal applied to carbon fibers and having at least two edges opposite to each other to which the catalyst material is stably affixed or containing the catalyst material in the form of parallel fibers or bands; and (3) a process for the selective hydrogenation of carbon-carbon double or triple bonds and/or hydrogenatable functional groups using the catalyst material (I) or reactor (II).
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公开(公告)号:DE10055180A1
公开(公告)日:2002-05-29
申请号:DE10055180
申请日:2000-11-08
Applicant: BASF AG
Inventor: DERNBACH MATTHIAS , KOCH MICHAEL , SCHULZ GERHARD , WEIGL HAGEN , MAAS STEFFEN
Abstract: The invention relates to a method for catalytically hydrating a poly- or monomethylol alkanal of the general formula (I), wherein R is the same or different and may represent a substituted or unsubstituted aliphatic hydrocarbon with 6 to 22 carbon atoms, an aryl or arylalkyl group with 6 to 22 carbon atoms or a methylol group, in the presence of a copper-containing catalyst. The inventive method is characterized in that the poly- or monomethylol alkanal containing batch to be hydrated has a total content of up to 5 ppm of metal ions of the groups 3 to 14 of the periodic system.
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公开(公告)号:AU2370501A
公开(公告)日:2001-07-09
申请号:AU2370501
申请日:2000-12-28
Applicant: BASF AG
Inventor: DERNBACH MATTHIAS , KRATZ DETLEF , STAMMER ACHIM , HAAKE MATHIAS , KOCH MICHAEL , SCHULZ GERHARD
IPC: C07B61/00 , C07C29/141 , C07C29/80 , C07C29/90 , C07C31/22
Abstract: A process for greatly improving the color index of polyhydric alcohols, especially trimethylolpropane, by hydrogenation comprises using, in the hydrogenation, an alcohol which has already been purified by distillation. The catalysts used are those conventionally employed in hydrogenations, preferably copper, nickel, palladium or ruthenium catalysts.
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公开(公告)号:CA2660334A1
公开(公告)日:2008-02-28
申请号:CA2660334
申请日:2007-08-24
Applicant: BASF AG
Inventor: RUDOLF PETER , BENDER MICHAEL , KOCH MICHAEL
IPC: B01J23/72 , B01D53/64 , B01J27/04 , B01J27/043 , B01J37/20 , C07C5/09 , C07C7/148 , C07C7/163 , C07C7/167 , C10G70/02
Abstract: The invention relates to a method for eliminating at least one of the com ponents selected from among the group comprising oxygen, nitrogen oxides, ac etylenes, and dienes, from a gas mixture containing said at least one compon ent in addition to hydrogen, one or several olefins that are no dienes, and other optional gas components. According to said method, the gas mixture is contacted with a catalyst in a reaction zone. The disclosed method is charac terized in that the catalyst contains copper(I) sulfide.
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公开(公告)号:AT380231T
公开(公告)日:2007-12-15
申请号:AT02020725
申请日:2002-09-14
Applicant: BASF AG
Inventor: KOCH MICHAEL , SCHWAB EKKEHARD , TRUEBENBACH PETER , SCHAEFER HARALD
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公开(公告)号:DE102005053232A1
公开(公告)日:2007-05-10
申请号:DE102005053232
申请日:2005-11-06
Applicant: BASF AG
Inventor: KOCH MICHAEL , SCHINDLER GOETZ-PETER , WESSEL HELGE , NEUMANN DIRK
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