公开(公告)号：US3679739A

公开(公告)日：1972-07-25

申请号：US3679739D

申请日：1969-06-13

Applicant: BASF AG

Inventor： SCHULZ GERHARD ,  MATTHIAS GUENTHER

IPC: C07C69/12 ,  C07C67/00 ,  C07C69/14

CPC classification number: C07C67/46 ,  C07C2601/14 ,  C07C69/14

Abstract: Production of esters of acetic acid by reaction of ketenes with alcohols in the presence of metal sulfides. The products are valuable intermediates, for example for adhesives and photographic film, and some of them are important solvents, for example for surface coatings.

Abstract translation: 在金属硫化物存在下，通过烯酮与醇反应制备乙酸酯。 该产品是有价值的中间体，例如粘合剂和照相胶片，其中一些是重要的溶剂，例如表面涂料。

公开(公告)号：JPH10174874A

公开(公告)日：1998-06-30

申请号：JP29677597

申请日：1997-10-29

Applicant: BASF AG

Inventor： WULFF-DOERING JOACHIM ,  MELDER JOHANN-PETER ,  SCHULZ GERHARD ,  VOIT GUIDO ,  GUTSCHOVEN FRANK ,  HARDER WOLFGANG

IPC: B01J23/89 ,  C07B61/00 ,  C07C209/02 ,  C07C209/14 ,  C07C209/16 ,  C07C209/26 ,  C07C211/10 ,  C07C211/13 ,  C07C213/02 ,  C07C215/14

Abstract: PROBLEM TO BE SOLVED: To provide an amination catalyst small in the content of nickel and/or cobalt and having high selectivity and high stability about ethylene diamine obtained by aminating monoethanol amine with ammonia. SOLUTION: The catalyst is carried on a porous metal oxide carrier. And the catalyst contains 0.1-6wt.% cobalt, nickel or the mixture, 0.001-25wt.% ruthenium, 0-10wt.% copper and 0-5wt.% accelerator selected from iron, rhodium, palladium, platina, iridium, osmium, silver, gold, chromium, molybdenum, tungsten, rhenium, zinc, cadmium, lead, manganese, tin lithium, sodium, potassium, rubidium, cesium, phosphorus, arsenic, antimony, bismuth, tellurium, thallium and the mixture per total weight of the catalyst.

公开(公告)号：JP2002220363A

公开(公告)日：2002-08-09

申请号：JP2001369143

申请日：2001-12-03

Applicant: BASF AG

Inventor： MELDER JOHANN-PETER DR ,  SCHULZ GERHARD

IPC: C07C213/02 ,  C07C213/00 ,  C07C213/04 ,  C07C213/08 ,  C07C215/08 ,  C07C215/12

Abstract: PROBLEM TO BE SOLVED: To provide an economical and efficient method for producing one or more ethanolamines (I) from one or more ethanolamines (II) different from ethanolamine (I). SOLUTION: The method for producing one or more ethanolamines (I) selected from a group consisting of monoethanolamine, diethanolamine and triethanolamine by converting one or more ethanolamines (II) which are selected from a group consisting of monoethanoamine, diethanolamine, triethanolamine, O,N,N-tris(2-hydroxyethyl)ethanolamine, N-(2-aminoethyl)ethanolamine, N-(2- hydroxyethyl) piperazine, N-(2-hydroxyethyl)morpholine and N,N'-bis(2- hydroxyethyl)piperazine, and are different from ethanolamine (I), is characterized by treating with strong base, if necessary, in the presence of ammonia.

公开(公告)号：JP2001294562A

公开(公告)日：2001-10-23

申请号：JP2001067448

申请日：2001-03-09

Applicant: BASF AG

Inventor： RUIDER GUENTHER ,  ROSS KARL-HEINZ DR ,  MELDER JOHANN-PETER DR ,  SCHULZ GERHARD ,  GUTSCHOVEN FRANK ,  BUSKENS PHILIPP DR

IPC: C07C213/10 ,  C07C215/08 ,  C07C215/12 ,  C07C215/14

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an alkanolamine diminished in discoloration determined by e.g. APHA color number and improved in color stability over a long storage period. SOLUTION: This method for producing an alkanolamine comprises the following steps: step (a): the original alkanolamine is treated with an effective amount of phosphorous acid, hypophosphorous acid or a compound thereof at an elevated temperature for 5 min or longer, and subsequently, step b: the resultant alkanolamine is distilled in the presence of an effective amount of one of the above phosphorus compounds.

公开(公告)号：JP2001097934A

公开(公告)日：2001-04-10

申请号：JP2000265450

申请日：2000-09-01

Applicant: BASF AG

Inventor： RUIDER GUENTHER ,  ROSS KARL-HEINZ DR ,  BREITSCHEIDEL BORIS DR ,  MAIER HEIKE ,  SCHULZ GERHARD ,  HUBER SYLVIA

IPC: B01J35/02 ,  C07B61/00 ,  C07C213/10 ,  C07C215/08 ,  C07C215/10 ,  C07C215/12 ,  C07C215/14

Abstract: PROBLEM TO BE SOLVED: To find out an economical, selective and efficient method for producing an alkanolamine having improved color quality as opposed to a conventional method. SOLUTION: This method for producing the alkanolamine having the improved color quality and good in color stability comprises using a supported heterogeneous catalyst comprising a noble metal of Re, Ru, Rh, Pd, Os, Ir, Pt and/or Ag and a carrier material selected from the group of active carbon, α-aluminum oxide, zirconium dioxide and titanium dioxide as a hydrogenating catalyst in which the catalyst has a prescribed hardness of at least 10 N cutting hardness and prescribed strengths of at least 30 N laterial pressure strength and at least 25 N stamping strength in the case of active carbon as the carrier material in the method for producing the alkanolamine having the improved color quality by treating an alkanolamine using hydrogen at a high temperature in the presence of the hydrogenating catalyst. Thereby, the alkanolamine is economically produced.

公开(公告)号：US3865846A

公开(公告)日：1975-02-11

申请号：US10624471

申请日：1971-01-13

Applicant: BASF AG

Inventor： SCHULZ GERHARD ,  MATTHIAS GUENTHER ,  KASPER WERNER ,  HAARER ERICH

IPC: C07C45/88 ,  C07C49/88 ,  C07D315/00 ,  C07D3/00

CPC classification number: C07D315/00 ,  C07C45/88 ,  C07C49/88

Abstract: The continuous production of diketene by dimerizing ketene in diketene containing ketene as a solvent using specific temperature conditions and concentrations. Diketene prepared by the process is a starting material for the production of acetoacetic esters, dyes, solvents and pesticides.

Abstract translation: 通过使用特定的温度条件和浓度将乙烯酮二烯化在含乙烯酮作为溶剂的双烯酮中连续生产双烯酮。

公开(公告)号：US3668246A

公开(公告)日：1972-06-06

申请号：US3668246D

申请日：1968-08-12

Applicant: BASF AG

Inventor： BERDING CHRISTOPH ,  GUENTHERT PAUL ,  KOEHLER WALDEMAR ,  SCHULZ GERHARD

IPC: C07C101/20

Abstract: Continuous production of alkali metal salts of nitrilotriacetic acid from an alkali metal cyanide, formaldehyde and ammonia by reaction of the components in at least two stages, the alkali metal cyanide being reacted with formaldehyde in stoichiometric or substantially stoichiometric ratio at temperatures of 50* to 200* and pressures of from atmospheric pressure to 50 atmospheres gauge in the presence of an excess of ammonia in the first stage and (while simultaneously removing ammonia) further amounts of alkali metal cyanide and formaldehyde being allowed to act at temperatures of 60* to 110*C in one or more subsequent stages, 5 to 35 mole percent of the total amount of alkali metal cyanide required being replaced by free hydrocyanic acid and/or hydroxyacetonitrile.

Abstract translation: 在至少两个阶段通过组分的反应从碱金属氰化物，甲醛和氨连续生产次氮基三乙酸的碱金属盐，碱金属氰化物与化学计量或基本上化学计量比的甲醛与50至200℃的温度反应 DEG和在大气压至50大气压的压力下，在第一阶段存在过量的氨的情况下，（同时除去氨），另外量的碱金属氰化物和甲醛允许在60〜110℃的温度下作用 在一个或多个后续阶段中，所需的碱金属氰化物的总量的5-35摩尔％被游离氢氰酸和/或羟基乙腈代替。

公开(公告)号：US3483214A

公开(公告)日：1969-12-09

申请号：US3483214D

申请日：1967-12-28

Applicant: BASF AG

Inventor： SPERBER HEINRICH ,  SCHULZ GERHARD ,  PALM CHRISTOF ,  KOEHLER WALDEMAR

IPC: C07D323/06 ,  C07D19/00

CPC classification number: C07D323/06

公开(公告)号：US3689543A

公开(公告)日：1972-09-05

申请号：US3689543D

申请日：1969-08-08

Applicant: BASF AG

Inventor： BERDING CHRISTOPH ,  GUENTHERT PAUL ,  SCHULZ GERHARD ,  KOEHLER WALDEMAR

IPC: C07C101/20

CPC classification number: C11D3/33

Abstract: Production of alkali metal salts of nitrilotriacetic acid from an alkali metal cyanide, formaldehyde and ammonia by reaction in at least two stages, the alkali metal cyanide being reacted with formaldehyde in approximately stoichiometric ratio of 50* to 200* C. and 2 to 50 atmospheres gauge in the presence of an excess of ammonia in the first stage and the resultant solution (after decompression to atmospheric pressure) being treated in one or more further stages with further amounts of alkali metal cyanide and formaldehyde at 60* to 110* C. while removing ammonia at the same time.

Abstract translation: 通过至少两个阶段的反应，从碱金属氰化物，甲醛和氨生产次氮基三乙酸的碱金属盐，使碱金属氰化物与甲醛反应，化学计量比约为50至200℃和2至50个大气压 在第一阶段存在过量的氨，并在所得溶液（在减压至大气压之后）在一个或多个其它阶段用更多量的碱金属氰化物和甲醛在60℃至110℃下进行处理，同时 同时去除氨。

公开(公告)号：US3607930A

公开(公告)日：1971-09-21

申请号：US3607930D

申请日：1968-07-08

Applicant: BASF AG

Inventor： BERDING CHRISTOPH ,  GUENTHERT PAUL ,  KOEHLER WALDEMAR ,  SCHULZ GERHARD

IPC: C07C101/20

CPC classification number: C11D3/33

Abstract: A continuous process for the production of alkali metal salts of nitrilotriacetic acid by reaction in a first stage of alkali metal cyanide, formaldehyde and excess ammonia at superatmospheric pressure and elevated temperature to form an aminoacetic acid solution, followed by depressurizing and treating the solution obtained with further amounts of alkali metal cyanide and formaldehyde while removing the ammonia formed until conversion to nitrilotriacetic acid is complete.