Abstract:
The invention relates to tricyclic cyclohexanedione derivatives of formula (I) in which the substituents have the following meaning: R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6 alkyl, C1-C6 alkoxy, C1-C6 haloalkyl, C1-C6 haloalkoxy, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano, nitro or C1-C3 alkylsulfonyl or phenylsulfonyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R , R is hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 haloalkylthio, C1-C6 alkylsulfinyl, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, NR R , C2-C6 alkoxyalkyl, C1-C6 alkoxycarbonyl, C1-C6 alkylcarbonyl, halogen, cyano, nitro, phenyl that is optionally substituted with C1-C3 alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4 alkyl; R is hydrogen, C1-C6 alkyl or halogen; R is hydrogen or C1-C6 alkyl; R is C1-C6 alkyl or C1-C6 alkoxy; 1 is 0, 1 or 2; n is 1 or 2; R is substituted (3-oxo-1-cyclohexene-2-yl)carbonyl or substituted (1,3-dioxo-2-cyclohexyl)methylidene. The invention also relates to the agriculturally useful salts of the compounds (I), to methods for producing said tricyclic cyclohexanedione derivatives and to the intermediates for their production. The invention encompasses agents containing the inventive compounds and the use of said derivatives or of agents containing them for weed control.
Abstract:
The invention relates to methods for producing sulfonamides of formula I, wherein the variables have the designations cited in the description, by reacting m-nitro-benzoic acid chlorides of formula II with aminosulfons of formula III, under the influence of B equivalents of base IV. Said method is characterised in that, during step a) the aminosulfon of formula III is reacted with B1 equivalents of base IV, and during step b), the reaction mixture resulting from step a) is reacted with m-nitro-benzoic acid chlorides of formula II and B2 equivalents of base IV; B, B1 and B2 having the designations cited in the description.
Abstract:
The invention relates to pyrazoles of formula (I) wherein said variables can represent the following: R = hydrogen, nitro, halogen, cyano, rhodano or an aliphatic radical; R = a substituted sulphur, nitrogen or phosphor atom; R = hydrogen, halogen or an alliphatic radical; R , R = hydrogen, nitro, halogen, cyano, rhodano ar an aliphatc radical; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R , R , R = hydrogen, C1-C6-alkyl, whereby at the most R , R , R represent hydrogen; in addition to the tautomers and agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.
Abstract translation:本发明提供了式(I)的吡唑类,其中变量尤其包括:R 1氢,硝基,卤素,氰基,罗多诺或脂肪族基团; R 2是取代的硫,氮或磷原子; R 3是氢,卤素或脂族基团; R 4,R 5是氢,硝基,卤素,氰基,rhodano或脂族基团; R 6是氢,卤素,C 1 -C 6烷基,C 1 -C 6烷氧基,C 3 -C 8环烷基; R 7,R 8,R 9,氢,C 1 -C 6烷基,其中基团R 7,R 8,R 9中至多一个是氢; 和它们的互变异构体和农业上有用的盐。 此外,本发明涉及制备式(I)化合物的方法,含有它们的组合物,以及式(I)化合物和组合物用于防治含有它们的有害植物的用途。
Abstract:
The invention relates to tricyclic pyrazolone derivatives of the formula (I) in which the variables have the following meaning: R is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro or C1-C3-alkylsulfonyl, phenylsulfonyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro; R , R are hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, NR R , C2-C6-alkoxyalkyl, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyl, halogen, cyano, nitro, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4-alkyl; R is hydrogen, C1-C6-alkyl or halogen; R is hydrogen or C1-C6-alkyl; R is C1-C6-alkyl or C1-C6-alkoxy; l is 0, 1 or 2; n is 1 or 2; R is a rest of the formulas (IIa) or (IIb), in which the variables have the meanings stated in claim I. The invention also relates to methods for the preparation of said tricyclic pyrazolone derivatives, preparations containing same and the use of said derivatives or of preparations containing same as herbicides.
Abstract:
The invention relates to cycloalkyl-substituted benzoyl pyrazoles of formula (I) wherein said variables can, for example, have the following meanings: R = hydrogen, nitro, halogen, cyano, rhodano or an optionally substituted aliphatic radical; R = an optionally substituted aliphatic radical, halogen, nitro, in addition to substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-halogenalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkinyl; R , R = hydrogen, nitro, halogen, cyano, rhodano, an optionally substituted aliphatic radical or substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R = a cyclic ring system with 3 - 14 ring atoms; R = hydroxy or a substituted hydroxy group; in addition to tautomers or agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.
Abstract:
The invention relates to a method for producing pyrazolylbenzoyl derivatives of formula (I), wherein the substituents have the meanings given in the description; characterised in that a pyrazolylbenzoyl derivative of formula (II), wherein the substituents R , R , R , A, B and D have the meanings given above, is treated with an inorganic or organic acid at a pH value
Abstract:
The invention relates to 3-(heterocyclyl)-benzoylpyrazole derivatives of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R is nitro, halogen, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkyl-sulfonyl; R , R , R , R are hydrogen, alkyl or halogenalkyl; R is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, (alkylthio)carbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R , R are alkyl; R is hydrogen or alkyl; and R is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to a method for producing these compounds and to their use or the use of products containing them for combating undesirable plants.
Abstract:
The invention relates to a method for the production of 3-phenyl(thio)uracils and dithiouracils of formula I, wherein the variables have the meanings cited in the description, characterized in that carbamates of formula II, wherein variables X1, X3, Ar and A have the above-mentioned meanings and L1 represents a nucleophilically displaceable nucleofuge, can be reacted with enamines of formula III, wherein variables X2, R1, R2 and R3 have the above-mentioned meanings and L2 represents a nucleophilically displaceable nucleofuge. The invention also relates to intermediate products for the production thereof.
Abstract:
The invention relates to 3-(4,5-dihydroisoxazole-5-yl)benzoylpyrazole of the formula (I) and agriculturally useful salts thereof: (see formula I) wherein R1, R2 represent hydrogen, nitro, halogen, cyano, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl or halogenalkylsulfonyl; R3 represents hydrogen, halogen or alkyl; R4 represents hydrogen or alkyl; R5, R6 represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the latter six groups can be substituted; R7 represents halogen, cyano, hydroxy, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfinyl, halogenalkylsulfinyl, alkylsulfonyl, halogenalkylsulfonyl, amino, alkylamino, dialkylamino, dialkoxymethyl, hydroxyiminoalkyl, alkoxyiminoalkyl or optionally substituted carbonyl; R11 represents optionally substituted pyrazole that is bound in the 4 position and that carries a hydroxy group or a derivative thereof in the 5 position. The invention also relates to methods and intermediate products for preparing the 3-(4,5-dihydroisoxazole-5-yl)benzoylpyrazole, to agents containing them and the use of said derivatives or agents containing them for combating undesired plants.
Abstract:
The invention relates to 3-(heterocyclyl)-substituted benzoylpyrazols of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R1 is alkyl; R2, R3, R4, R5 are hydrogen, alkyl or alkyl halide; R6 is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R7 is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, alkylthiocarbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R8, R9 are alkyl; R10 is hydrogen or alkyl; and R11 is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to intermediate products and methods for producing the inventive compounds and to the use of these compounds or products containing them for combating undesirable plants.