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公开(公告)号:CA2244271C
公开(公告)日:2005-11-29
申请号:CA2244271
申请日:1997-01-20
Applicant: BASF AG
Inventor: STAATZ HARTMUT , SCHOLL STEPHAN , POLT AXEL WERNER , MOHR JURGEN , VANSANT FRANS , KRUGER SIEGFRIED
Abstract: The invention concerns a method of vaporizing a fluid containing vaporizable oxidation-sensitive compounds in a vaporizer in which, for vaporization purposes, the fluid is brought into contact with a heated solid surface, direct contact between the resultant vapour phase and the heated solid surface axing largely prevented. The invention further concerns a vaporizer comprising a heatable solid surface (16), a device (2, 3) for heating the solid surface, and a device (10) for feeding a fluid containing vaporizable compounds to the healable solid surface. The fluid-feeding device is designe d and disposed (12, 14, 18) in the vaporizer such that direct contact between the resultant vapour phase and the healable solid surface is largely prevented.
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公开(公告)号:TR200003855T2
公开(公告)日:2001-10-22
申请号:TR200003855
申请日:1999-06-12
Applicant: BASF AG
Inventor: BOECKH DIETER , EHLE MICHAEL , ROSER ANGELIKA , MOHR JURGEN , CLEARY JAMES ALBERT , ZHANG SHULIN , GOSSELINK EUGENE PAUL
Abstract: The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:-(R1O)m(R2O)nR3wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one -(R1O) unit is attached to the backbone prior to attachment of an -(R2O) unit and further provided m+n is at least 12.
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公开(公告)号:AU2162899A
公开(公告)日:1999-07-19
申请号:AU2162899
申请日:1998-12-17
Applicant: BASF AG
Inventor: MOHR JURGEN , DOCKNER TONI
IPC: C07C41/02 , C07B61/00 , C07C29/128 , C07C41/03 , C07C213/04 , C07C217/50 , C08G65/10 , C08G73/02 , C08G73/04
Abstract: In a process for preparing alkoxylated amines or alcohols in which a reaction mixture comprising an amine or an alcohol or a mixture of two or more amines and/or alcohols and an alkylene oxide, or a mixture of two or more different alkylene oxides, is reacted in one or more successive reaction steps, at least one of the reaction steps is carried out in the presence of a basic catalyst and, in at least one of the reaction steps, formic acid or a salt of formic acid or a mixture of two or more thereof is present in the reaction mixture or the reaction mixture is admixed with formic acid or a salt of formic acid, or a mixture of two or more thereof, after the alkoxylation is complete. The alkoxylates prepared by the process of the present invention have a light color and a low odor.
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公开(公告)号:CA2311127A1
公开(公告)日:1999-07-08
申请号:CA2311127
申请日:1998-12-17
Applicant: BASF AG
Inventor: MOHR JURGEN , DOCKNER TONI
IPC: C07C41/02 , C07B61/00 , C07C29/128 , C07C41/03 , C07C213/04 , C07C217/50 , C08G65/10 , C08G73/02 , C08G73/04
Abstract: The invention relates to a method for producing oxalkylated amines or alcohols, whereby a reaction mixture containing an amine or an alcohol or a mixture of two or more amines and/or alcohols and an alkylene oxide or a mixture of two or more different alkylene oxides are made to react in one or several successive reaction steps. At least one of the steps of the reaction occurs in the presence of a basic catalyst and the reaction mixture in at least one of the reaction steps contains formic acid or a formic acid salt or a mixture of the two or more or the reaction mixture is mixed with formic acid or a formic acid salt or a mixture of the two or more when oxalkylation is finished. The alkoxylates obtained using the inventive method have little natural colour or odour.
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公开(公告)号:BR9509248A
公开(公告)日:1997-10-21
申请号:BR9509248
申请日:1995-09-26
Applicant: BASF AG
Inventor: MOHR JURGEN , KNAUF WOLFGANG , BLAZER WOLF-DIETER , OPPENLANDER KNUTT , SLOTMAN WILHELMUS
Abstract: PCT No. PCT/EP95/03809 Sec. 371 Date Apr. 7, 1997 Sec. 102(e) Date Apr. 7, 1997 PCT Filed Sep. 26, 1995 PCT Pub. No. WO96/11225 PCT Pub. Date Apr. 18, 1996The preparation of alkoxylates of oligoamines or polyamines by a two-stage procedure where, in the first stage, one molecule of alkylene oxide per NH group is added onto the oligoamines or polyamines in the presence of water, alcohols or acids or a mixture thereof in the absence of a neutral or basic catalyst and, in the second stage, after removal of water and acids reaction with further alkylene oxide is carried out in the presence of a conventional neutral or basic catalyst, entails, before the second stage is carried out, an organic solvent or diluent or a mixture thereof from the group of (a) alcohols and phenols and their alkoxylates, (b) polyalcohols based on ethylene oxide, propylene oxide, butylene oxide or a mixture thereof, (c) N-substituted carboxamides, (d) alkanolmonoamines and alkanolpolyamines and their alkoxylates, (e) other alkoxylates of oligoamines or polyamines, (f) aromatic hydrocarbons, (g) aliphatic hydrocarbons, (h) ethers and (i) sulfones or sulfoxides being added.
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公开(公告)号:MX9700809A
公开(公告)日:1997-05-31
申请号:MX9700809
申请日:1995-07-28
Applicant: BASF AG
Inventor: HARREUS ALBRECHT , GOTZ NORBERT , HARTMANN HORST , MOHR JURGEN , GEHRER EUGEN , LAUTH GUNTER , RANG HARALD
IPC: B01J31/02 , C07B61/00 , C07C249/12 , C07C251/38 , C07C251/44 , C07C251/54
Abstract: La presente invencion se relaciona con la preparacion de 0-(2-hidroxialquil) oximas de la formula I, en donde R1 y R2 son alquilo o R1 y R2 y el átomo de C comun son un cicloalquilo de 5 a 7 miembros; R3 es alquilo, ocasionando que una cetoxima II reaccione con un oxido de olefina III en la presencia de una amina terciaria o con un carbonato IV en la presencia de un catalizador. Los productos finales (I) son adecuados para usarse como intermediarios para agentes de proteccion de cosechas. (Ver Formula).
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公开(公告)号:AU3381395A
公开(公告)日:1996-03-04
申请号:AU3381395
申请日:1995-07-28
Applicant: BASF AG
Inventor: HARREUS ALBRECHT , GOTZ NORBERT , RANG HARALD , HARTMANN HORST , MOHR JURGEN , GEHRER EUGEN , LAUTH GUNTER
IPC: B01J31/02 , C07B61/00 , C07C249/12 , C07C251/38 , C07C251/44 , C07C251/54
Abstract: Preparation of O-(2-hydroxyalkyl) oximes of formula (I), (R and R are alkyl or R and R and the common C atom are 5-membered to 7-membered cycloalkyl; R is alkyl) by causing a ketoxime II to react with an olefin oxide III in the presence of a tertiary amine or with a carbonate IV in the presence of a catalyst. The end products (I) are suitable for use as intermediates for crop protection agents.
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公开(公告)号:ES2203138T3
公开(公告)日:2004-04-01
申请号:ES99923434
申请日:1999-04-22
Applicant: BASF AG
Inventor: BIRNBACH STEFAN , DOCKNER TONI , MOHR JURGEN , BENFER REGINA , BIEG WALTER , PETERS JARREN
IPC: C07D317/36 , C07D317/38
Abstract: A process for the continuous production of 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in the liquid phase in the presence of a catalyst comprises conducting the reaction in a two-part reactor in whose first part the reaction is taken with backmixing to a conversion of not less than 80% of the oxirane II and in whose second part the reaction is completed under nonbackmixing conditions, and passing the carbon dioxide in countercurrent to the oxirane II in the entire reactor.
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公开(公告)号:ES2174615T3
公开(公告)日:2002-11-01
申请号:ES99927964
申请日:1999-06-12
Applicant: BASF AG
Inventor: BOECKH DIETER , EHLE MICHAEL , ROSER ANGELIKA , MOHR JURGEN , CLEARY JAMES ALBERT , ZHANG SHULIN
Abstract: The present invention relates to an alkoxylated polyalkyleneimine soil dispersant having the formula: wherein R is C2-C6 linear alkylene, C3-C6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:-(R1O)m(R2O)nR3wherein R1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R2 is ethylene; R3 is hydrogen, C1-C4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x and y are each independently from about 4 to about 200; provided at least one -(R1O) unit is attached to the backbone prior to attachment of an -(R2O) unit and further provided m+n is at least 12.
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公开(公告)号:AU6229301A
公开(公告)日:2001-11-26
申请号:AU6229301
申请日:2001-05-16
Applicant: BASF AG
Inventor: BADER JOACHIM , BECHTOLSHEIMER HANS-HEINRICH , BRUCKER ARMIN , DOCKNER TONI , IFFLAND GABRIELE , KLINK HANS , MARTIN STEFAN , MOHR JURGEN , MUGRAUER HANS-MARTIN
Abstract: Alkali metal ions are separated off from alkoxylates containing alkali metal ions by a process comprising:a) dilution of the alkali metal-containing alkoxylate with an inert solvent,b) treatment of the alkali metal-containing solution of the alkoxylate with a cationic exchanger in order to obtain a substantially alkali metal-free solution of the alkoxylate, andc) removal of the solvent from the substantially alkali metal-free solution of the alkoxylate in order to obtain a substantially alkali metal-free and substantially solvent-free alkoxylate.
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