公开(公告)号：AU8389501A

公开(公告)日：2002-01-08

申请号：AU8389501

申请日：2001-06-27

Applicant: BASF AG

Inventor： RICHTER WOLFGANG ,  KROKOSZINSKI ROLAND ,  MULLER ROLF ,  MCATEE MICHAEL

IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: Disclosed is a method for the hydroformylation of olefins comprising 2 to 8 atoms, whereby a) an inflow containing olefins and a gas mixture containing hydrogen and carbon monoxide are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, b) the reaction product which is released from the raw hydroformylation product is redirected into the reaction zone during the extraction of a gaseous recovery flow. The inventive method is characterised in that c) the recovery flow is brought into intimate contact with a wash liquid in order to eliminate the unreacted olefins contained therein, the wash liquid being a vented hydroformylation product, and the olefin-charged wash liquid and the raw hydroformylation product are redirected for regeneration. Said inventive method enables unreacted olefins to be reclaimed to a large extent from the recovery flow.

公开(公告)号：AU8190901A

公开(公告)日：2002-01-08

申请号：AU8190901

申请日：2001-06-27

Applicant: BASF AG

Inventor： WALZ HELMUT ,  SCHONMANN WILLI ,  MULLER ROLF ,  KROKOSZINSKI ROLAND

IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: Olefins having from 2 to 8 carbon atoms are hydroformylated in a process in which (i) an olefin-containing feed in which a proportion of a saturated hydrocarbon having from 2 to 8 carbon atoms is present and also carbon monoxide and hydrogen are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, (ii) a stream consisting essentially of unreacted olefin and saturated hydrocarbon is separated off from the output from the reaction zone, (iii) the stream is separated into an olefin-enriched fraction and an olefin-depleted fraction by rectification, and (iv) at least part of the olefin-enriched fraction is recirculated to the reaction zone.

公开(公告)号：ES2217185T3

公开(公告)日：2004-11-01

申请号：ES01962789

申请日：2001-06-27

Applicant: BASF AG

Inventor： RICHTER WOLFGANG ,  KROKOSZINSKI ROLAND ,  MULLER ROLF ,  MCATEE MICHAEL

IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: Disclosed is a method for the hydroformylation of olefins comprising 2 to 8 atoms, whereby a) an inflow containing olefins and a gas mixture containing hydrogen and carbon monoxide are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, b) the reaction product which is released from the raw hydroformylation product is redirected into the reaction zone during the extraction of a gaseous recovery flow. The inventive method is characterised in that c) the recovery flow is brought into intimate contact with a wash liquid in order to eliminate the unreacted olefins contained therein, the wash liquid being a vented hydroformylation product, and the olefin-charged wash liquid and the raw hydroformylation product are redirected for regeneration. Said inventive method enables unreacted olefins to be reclaimed to a large extent from the recovery flow.

公开(公告)号：CA2366457A1

公开(公告)日：2000-10-05

申请号：CA2366457

申请日：2000-03-28

Applicant: BASF AG

Inventor： MULLER ROLF ,  SCHONMANN WILLI

IPC: C07C45/50 ,  C07C45/82 ,  C07C47/02

Abstract: The present invention relates to a method for separating a liquid crude aldehyde mixture by distillation. Said mixture contains unbranched and branched aldehydes. In a first distillation column, the product mixture is separated into a first product flow of branched aldehyde, a product flow of unbranched aldehyde and an additional product flow which contains unbranched aldehyde and the high-boiling components. In a second distillation column whose product flow is smaller by a factor of 50 to 200 than the product flow from the first distillation column, the additional product flow is then separated into a product flow of unbranched aldehyde and a high-boiling product flow.

公开(公告)号：ES2282631T3

公开(公告)日：2007-10-16

申请号：ES03729477

申请日：2003-01-16

Applicant: BASF AG

Inventor： RICHTER WOLFGANG ,  MULLER ROLF ,  KROKOSZINSKI ROLAND

IPC: C07C45/50 ,  C07B61/00 ,  C07C29/16 ,  C07C31/02 ,  C07C45/00 ,  C07C47/02

Abstract: Procedimiento para el hidroformilado, en el que se hace reaccionar continuamente al menos una olefina con 2 a 6 átomos de carbono con monóxido de carbono e hidrógeno en presencia de un catalizador de hidroformilado en una zona de reacción, que contiene una fase líquida, y de la fase líquida se extrae una corriente S), de esta corriente se extrae calor, y a continuación se devuelve un componente material a la zona de reacción, continuando la reacción en la corriente S) al menos hasta la extracción de calor, y alimentándose a esta corriente monóxido de carbono y/o hidrógeno, antes de que la misma se empobrezca en éstos en tal medida que los componentes remanentes entren en reacciones secundarias indeseables, y/o el hidroformilado se detenga esencialmente.

公开(公告)号：MY131979A

公开(公告)日：2007-09-28

申请号：MYPI20013045

申请日：2001-06-27

Applicant: BASF AG

Inventor： WALZ HELMUT DR ,  SCHONMANN WILLI DR ,  MULLER ROLF ,  KROKOSZINSKI ROLAND DR

IPC: C07C45/50 ,  C07B61/00 ,  C07C47/02

Abstract: OLEFINS HAVING FROM 2 TO 8 CARBON ATOMS ARE HYDROFORMYLATED IN A PROCESS IN WHICH (I) AN OLEFIN-CONTAINING FEED IN WHICH A PROPORTION OF A SATURATED HYDROCARBON HAVING FROM 2 TO 8 CARBON ATOMS IS PRESENT AND ALSO CARBON MONOXIDE AND HYDROGEN ARE FED INTO A REACTION ZONE AND REACTED IN THE PRESENCE OF A HYDROFORMYLATION CATALYST, (II) A STREAM CONSISTING ESSENTIALLY OF UNREACTED OLEFIN AND SATURATED HYDROCARBON IS SEPARATED OFF FROM THE OUTPUT FROM THE REACTION ZONE, (III) THE STREAM IS SEPARATED INTO AN OLEFIN-ENRICHED FRACTION AND AN OLEFIN-DEPLETED FRACTION BY RECTIFICATION, AND (IV) AT LEAST PART OF THE OLEFIN-ENRICHED FRACTION IS RECIRCULATED TO THE REACTION ZONE.(FIG 1)

公开(公告)号：MY131816A

公开(公告)日：2007-09-28

申请号：MYPI20010492

申请日：2001-02-05

Applicant: BASF AG

Inventor： WALCZUCH KARL-HEINZ ,  MULLER ROLF ,  KROKOSZINSKI ROLAND DR ,  GEISSLER BERNHARD DR

IPC: C07C45/50 ,  C07B61/00 ,  C07C47/02

Abstract: A LIQUID OUTPUT FROM A CONTINUOUS HYDROFORMYLATION, WHICH COMPRISES ESSENTIALLY ALDEHYDES, HIGH-BOILING BY-PRODUCTS,A HOMOGENEOUSLY DISSOLVED HYDROFORMYLATION CATALYST, UNREACTED OLEFINS, LOW-BOILING BYPRODUCTS AND DISSOLVED SYNTHESIS GAS, IS WORKED UP BY A PROCESS IN WHICH A) THE LIQUID HYDROFORMYLATION OUTPUT IS DEPRESSURIZED IN A FIRST DEPRESSURIZATION STAGE TO A PRESSURE WHICH IS FROM 2 TO 20 BAR BELOW THE REACTOR PRESSURE, RESULTING IN SEPARATION INTO A LIQUID PHASE AND A GAS PHASE, AND B) THE LIQUID PHASE OBTAINED IN THE FIRST DEPRESSURIZATION STAGE IS DEPRESSURIZED IN A SECOND DEPRESSURIZATION STAGE TO A PRESSURE WHICH IS LOWER THAN THE PRESSURE OF THE FIRST DEPRESSURIZATION STAGE, RESULTING IN SEPARATION INTO A LIQUID PHASE COMPRISING ESSENTIALLY HIGH-BOILING BY-PRODUCTS OF THE HYDROFORMYLATION, THE HOMOGENEOUSLY DISSOLVED HYDROFORMYLATION CATALYST AND SMALL AMOUNTS OF HYDROFORMYLATION PRODUCT AND UNREACTED OLEFIN AND A GAS PHASE 25 COMPRISING ESSENTIALLY THE MAJOR PART OF THE HYDROFORMYLATION PRODUCT, UNREACTED OLEFIN AND LOW-BOILING BY-PRODUCTS.(FIG 1)

公开(公告)号：ES2254478T3

公开(公告)日：2006-06-16

申请号：ES01967099

申请日：2001-06-27

Applicant: BASF AG

Inventor： RICHTER WOLFGANG ,  KROKOSZINSKI ROLAND ,  MULLER ROLF ,  GEISSLER BERNHARD

IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: Procedimiento para la obtención de productos de hidroformilación de olefinas con 2 hasta 8 átomos de carbono, en el que a) se alimenta una materia prima hidrocarbonada en una zona de craqueo/deshidrogenación y se somete a un craqueo térmico y/o catalítico y/o a una deshidrogenación obteniéndose un gas de disociación que contiene olefinas, b) se somete al gas de disociación, o fracciones del mismo, a una separación en, al menos, una corriente hidrocarbonada enriquecida en olefina con i átomos de carbono y, al menos, una corriente hidrocarbonada empobrecida en olefina con i átomos de carbono, c) se alimenta la corriente hidrocarbonada, enriquecida en olefina con i átomos de carbono, con monóxido de carbono e hidrógeno en una zona de hidroformilación y se hace reaccionar en presencia de un catalizador para la hidroformilación, d) se separa, a partir de la descarga procedente de la zona de hidroformilación, una corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por hidrocarburo con i átomos de carbono saturado, e) se recila la corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por el hidrocarburo con i átomos de carbono saturado, al menos en parte hasta la etapa b), significando i un número entero desde 2 hasta 8.

公开(公告)号：ES2152557T3

公开(公告)日：2001-02-01

申请号：ES96929290

申请日：1996-08-21

Applicant: BASF AG

Inventor： BORGEL FRANZ ,  MULLER ROLF ,  KROKOSZINSKI ROLAND

IPC: B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: PCT No. PCT/EP96/03665 Sec. 371 Date May 29, 1998 Sec. 102(e) Date May 29, 1998 PCT Filed Aug. 21, 1996 PCT Pub. No. WO97/07086 PCT Pub. Date Feb. 27, 1997A process for the purification of a substantially liquid effluent containing aldehydes and unconverted olefins coming from a hydroformylation reactor following low-pressure hydroformylation of C2-C20 olefins or olefin mixtures containing different isomers of the respective olefins, said hydroformylation being catalyzed by means of a phosphorous rhodium catalyst homogeneously dissolved in the reaction medium and carried out at a temperature of from 50 DEG to 150 DEG C. and a pressure of from 2 to 30 bar.