Abstract:
The invention relates to benzylidene pyrazolones of formula (I), wherein the substituents and index n have the following meanings: R = optionally substituted C1-C6 alkyl; R = optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, halogen, nitro, cyano; R = hydrogen, halogen, nitro, cyano, a group NR R , OCOR , NR COR ,CO2R , -COSR , -CONR R , C1-C4-alkoxyiminoalkyl, C1-C6 alkoxycarbonyl, optionally substituted C1-C6 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C1-C6 alkylthio, optionally substituted C2-C6 alkenyl, optionally substituted phenyl, optionally substituted phenoxy, an optionally substituted 5- or 6-membered saturated or unsaturated heterocycle which can contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulphur atoms as ring members; R = C1-C6 alkyl, C1-C4 halogen alkyl; or R and R = an optionally substituted saturated or unsaturated 2- or 3-membered bridge which can contain one sulphur atom which can be oxidized into sulfoxide or sulfone, R = hydrogen or optionally substituted C1-C6 alkyl; R = hydrogen, C1-C6 alkyl or C1-C4 halogenalkyl; n = 0, 1 or 2; X = hydrogen, chlorine or bromine. The compounds to which claim is laid are available in both a trans and a cis form or can be a mixture of these isomers.
Abstract:
The invention relates to pyrazoles of formula (I) wherein said variables can represent the following: R = hydrogen, nitro, halogen, cyano, rhodano or an aliphatic radical; R = a substituted sulphur, nitrogen or phosphor atom; R = hydrogen, halogen or an alliphatic radical; R , R = hydrogen, nitro, halogen, cyano, rhodano ar an aliphatc radical; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R , R , R = hydrogen, C1-C6-alkyl, whereby at the most R , R , R represent hydrogen; in addition to the tautomers and agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.
Abstract translation:本发明提供了式(I)的吡唑类,其中变量尤其包括:R 1氢,硝基,卤素,氰基,罗多诺或脂肪族基团; R 2是取代的硫,氮或磷原子; R 3是氢,卤素或脂族基团; R 4,R 5是氢,硝基,卤素,氰基,rhodano或脂族基团; R 6是氢,卤素,C 1 -C 6烷基,C 1 -C 6烷氧基,C 3 -C 8环烷基; R 7,R 8,R 9,氢,C 1 -C 6烷基,其中基团R 7,R 8,R 9中至多一个是氢; 和它们的互变异构体和农业上有用的盐。 此外,本发明涉及制备式(I)化合物的方法,含有它们的组合物,以及式(I)化合物和组合物用于防治含有它们的有害植物的用途。
Abstract:
The invention relates to tricyclic pyrazolone derivatives of the formula (I) in which the variables have the following meaning: R is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, halogen, cyano or nitro; X is O or NR ; R is hydrogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro or C1-C3-alkylsulfonyl, phenylsulfonyl possibly substituted with C1-C3-alkyl, halogen, cyano, nitro; R , R are hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, NR R , C2-C6-alkoxyalkyl, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyl, halogen, cyano, nitro, phenyl possibly substituted with C1-C3-alkyl, halogen, cyano or nitro; R is hydrogen or C1-C4-alkyl; R is hydrogen, C1-C6-alkyl or halogen; R is hydrogen or C1-C6-alkyl; R is C1-C6-alkyl or C1-C6-alkoxy; l is 0, 1 or 2; n is 1 or 2; R is a rest of the formulas (IIa) or (IIb), in which the variables have the meanings stated in claim I. The invention also relates to methods for the preparation of said tricyclic pyrazolone derivatives, preparations containing same and the use of said derivatives or of preparations containing same as herbicides.
Abstract:
The invention relates to cycloalkyl-substituted benzoyl pyrazoles of formula (I) wherein said variables can, for example, have the following meanings: R = hydrogen, nitro, halogen, cyano, rhodano or an optionally substituted aliphatic radical; R = an optionally substituted aliphatic radical, halogen, nitro, in addition to substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-halogenalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkinyl; R , R = hydrogen, nitro, halogen, cyano, rhodano, an optionally substituted aliphatic radical or substituted sulfonyl or amino groups; R = hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R = a cyclic ring system with 3 - 14 ring atoms; R = hydroxy or a substituted hydroxy group; in addition to tautomers or agriculturally useful salts thereof. The invention also relates to methods for the production of compounds of formula (I), agents containing said compounds, the use of compounds of formula (I) and agents containing said compounds as pesticides.
Abstract:
The invention relates to a method for producing pyrazolylbenzoyl derivatives of formula (I), wherein the substituents have the meanings given in the description; characterised in that a pyrazolylbenzoyl derivative of formula (II), wherein the substituents R , R , R , A, B and D have the meanings given above, is treated with an inorganic or organic acid at a pH value
Abstract:
The invention relates to 3-(heterocyclyl)-benzoylpyrazole derivatives of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R is nitro, halogen, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkyl-sulfonyl; R , R , R , R are hydrogen, alkyl or halogenalkyl; R is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarbonyloxy, (alkylthio)carbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R , R are alkyl; R is hydrogen or alkyl; and R is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to a method for producing these compounds and to their use or the use of products containing them for combating undesirable plants.
Abstract:
The invention concerns benzoyl derivatives of formula (I) in which the variables have the following meanings: R1, R2: hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkylthio halide, alkylsulphinyl, alkylsulphinyl halide, alkylsulphonyl, or C1-C6 alkylsulphonyl halide; R3: hydrogen, halogen or alkyl; R4, R5: hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl or carbonyl, wherein the six last-mentioned groups can be substituted; X: O, S, NR9, CO or CR10R11; Y: O, S, NR12, CO or CR13R14; R15: optionally substituted pyrazole which is bonded in position 4 and carries a hydroxy or sulphonyloxy group in position 5. The invention also concerns: the salts of these 3-heterocyclyl-substituted benzoyl derivatives which can be used fo r agricultural purposes; processes and intermediate products for preparing these substances; agents containing them; and the use as herbicides of these derivatives or agents containing them.
Abstract:
Herbicidal mixture containing a) a herbicidally effective amount of a 3 heterocyclyl-substituted benzoyl derivative of formula (I), wherein the variables have the following meanings: R1, R2 = hydrogen, haloge n, C1-C6 alkyl, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 halogen alkyl, C1-C6 alkoxy, C1-C6 halogenalkoxy; R3 = hydrogen, halogen, C1 - C6 alkyl; X = a heterocycle from the group of isoxazolyl, 4,5-dihydroisoxazolyl and thiazolyl, whereby said heterocycle can be substituted once or more with halogen, C1-C6 alkyl, C1-C4 alkoxy, C1-C4 halogenalkyl, C1-C4 halogenalkoxy, C1-C4 alkylthio; R4 = a cross-linke d pyrazol in position 4 of formula (II), whereby R5 = hydrogen or C1-C6 alkyl and R6 = C1-C6 alkyl, or the environmentally compatible salts thereof; b) a fertiliser containing nitrogen in a synergistically effective quantity and c) an adjuvant in a synergistically effective quantity.
Abstract:
Substituted 2-benzoylcyclohexane-1,3-diones of the formula Iwhere:R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, -OR3, -OCOR3, -OSO2R3, -S(O)nR3, -SO2OR3, -SO2N(R3)2, -NR3SO2R3 or -NR3COR3;R3 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl or phenyl-C1-C6-alkyl; where the abovementioned alkyl radicals may be partially or fully halogenated and/or may carry one to three of the following groups:hydroxyl, mercapto, amino, cyano, R3, -OR3, -SR3, -N(R3)2, =NOR3, -OCOR3, -SCOR3, -NR3COR3, -CO2R3, -COSR3, -CON(R3)2, C1-C4-alkyliminooxy, C1-C4-alkoxyamino, C1-C4-alkylcarbonyl, C1-C4-alkoxy-C2-C6-alkoxycarbonyl, C1-C4-alkylsulfonyl, heterocyclyl, heterocyclyloxy, phenyl, benzyl, hetaryl, phenoxy, benzyloxy and hetaryloxy, where the eight last mentioned radicals may in turn be substituted;n is 0, 1 or 2;Q is a cyclohexane-1,3-dione ring with or without substitution which is attached in position 2;X1 is a straight-chain or branched C1-C6-alkylene, a C2-C6-alkenylene or a C2-C6-alkynylene chain, where the abovementioned alkylene, alkenylene or alkynylene radicals may be partially halogenated and/or may carry one to three of the following groups:-OR4, -OCOR4, -OCONHR4 or -OSO2R4;except for those of the abovementioned alkenylene radicals where the double bond is alpha,beta to the phenyl ring and where Het is linked to the double bond via the beta position;R4 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, phenyl-C1-C6-alkyl, where the abovementioned alkyl, alkenyl or alkynyl radicals may be partially or fully halogenated and/or may be substituted by one or more of the following radicals:hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy;Het is a three- to six-membered partially or fully saturated heterocyclic group or a three- to six-membered heteroaromatic group having up to three hetero atoms selected from the group consisting of:nitrogen, oxygen or sulfur,where the abovementioned heterocyclic or heteroaromatic group may be partially or fully halogenated and/or may be substituted by R5;R5 is hydrogen, hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy, where the alkyl radicals may in each case be substituted by in each case one or more of the following radicals:cyano, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy;and agriculturally useful salts thereof, processes and intermediates for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and compositions comprising them for controlling harmful plants are described.