New cyclohexene-1,2-di:carboxylic acid derivs.

    公开(公告)号:DE4238001A1

    公开(公告)日:1994-07-21

    申请号:DE4238001

    申请日:1992-11-11

    Applicant: BASF AG

    Abstract: Substd. cyclohexene-1,2-dicarboxylic acid derivs. of formula (I), and their salts are new. Where T = CONR1R2 or CN; R1, R2 = H; R, 3-6C alkenyl, or 3-6C alkynyl, all opt. substd. by 1-3 halo, CN, NH2, SH, OH, OR, RSO, RSO2, RCO, COOH, ROCO, RNH, (R)2N, RNHCO, (R)2NCO, (RO)(HO)PO, (RO)2PO, or Ar); or Ar' when R1 is H or R, R2 may also be OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-7C cycloalkoxy 5-7 cycloalkenyloxy, 1-6C haloalkoxy, 3-6C halo alkenyloxy, 3-7C cycloalkyl-1-6C alkoxy, RCOO, 1-6C cyanoalkoxy, etc.; NR1R2 = a 3-8 membered non-aromatic heterocycle contg. 1-3N atoms and/or one O or S atom and opt. 1-2 CO gps., the ring being opt. substd. by 1-3R; Ar = phenyl or a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1O or 1S) both opt. substd. on every substitutable atom by OH, halo, CN, NO2, CF3, R or RO; Ar' as Ar except that the heterocycle contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S, and only C-atoms may be substd. R = 1-6C alkyl; R3 = H or R; R4 = H or halo; R5 = H, halo, NO2, CN or CF3; R6 = a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1-2O and 1-2S, and in which 1-2 CH2 gps. are opt. replaced by CO), opt. C-substd. by R, 2-6C alkenyl, 2-6C alkynyl, RO, RS, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-6C alkenylthio, 3-6C alkynylthio, ROCO, NO2, NH2, halo, 1-4C alkylamino, di(1-4C)alkylamino, CN, 1-6C cyanoalkyl, 1-6C haloalkyl or 1-6C haloalkyloxy; ACN, ACOB, OR9, C(O)R10, C(S)R10, C(NR16)R10, A = straight chain 2-4C alkenylene or 2-4C alkynylene, both opt. substd. by 1-2 halo, CN, R, 1-6C haloalkyl, OH, RO, RCOO, ROCO or RCO; B = H, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, OR17, SR17, phenyl (opt. substd. by 1-3R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO), 1-6C alkoxy-1-6C alkyl, di(1-6C alkoxy)-1-6C alkyl, 1-6C alkylthio-1-6C alkyl or NR18R19; R17 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, 1-6C cyanoalkyl, 3-6C haloalkenyl, ROCO, 1-6C alkoxy(1-6C)alkyl, 1-6C alkoxycarbonyl (1-6C) alkyl, 1-6C alkoxyimino(1-6C)alkyl, or phenyl (opt. substd. by 1-3 R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO); R18, R19 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, RCO, ROCO, 1-6C alkoxy (1-6C)alkyl, or phenyl (opt. substd. by 1-3R, 3-6C alkenyl, halo, CN, NO2, RO or ROCO); R9 = 1-6C cyanoalkyl RQ, 1-6C haloalkyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C haloalkynyl, 1-6 alkoxycarbonyl-2-6C alkyl, ROQOCOQ, 1-6C alkoxyimino (1-6C)alkyl, or phenyl, phenyl-Q, 3-8 membered heterocyclyl or heterocyclyl-Q (where the heterocycles contain 1-4 heteroatoms, etc.; R10 = H, CN, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, ROCO, ROCOQ, or phenyl (opt. substd. by 1-3 halo, CN, NO2, R, 3-6C alkenyl, 1-6C haloalkyl, RO or ROCO); R16 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-7C cycloalkyl, 1-6C haloalkyl, phenyl (opt. substd. by 1-3R, halo, CN, 2-6C alkenyl, NO2, 1-6C haloalkyl, 1-6C alkoxy, or ROCO), ROQ, OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 5-7C cycloalkoxy, 5-7C cycloalkenyloxy, etc.; R5+R6 = an opt. unsatd. 3-5 membered carbon chain which opt. contains 1-2O, S, N, CO or 1-6C alkoximino gps. and which is opt. substd. by 1-2 CN, NO2, NH2, halo, R, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C cyanoalkyl, RCOQ, phenyl-Q or 3-8 membered heterocyclyl-1-6C alkyl, where the heterocycle is opt. unsatd. and contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S; provided that when T is CONR1R2 then R9 is not 3-6C alkynyl and R16 is not 1-6C alkoxy, and when T is CN then R9 is not 1-6C haloalkoxy.

    13.
    发明专利
    未知

    公开(公告)号:DE58906691D1

    公开(公告)日:1994-02-24

    申请号:DE58906691

    申请日:1989-09-15

    Applicant: BASF AG

    Abstract: The invention relates to aromatic carboxylic acid derivatives of the formula … … in which the radical … … is an optionally substituted quinoline, naphthalene, thiophene or pyridine radical, R is hydrogen, alkylideneaminoxy, optionally substituted cycloalkylideneaminoxy, succinyliminoxy, optionally substituted alkenyloxy, alkynyloxy, azolyl, alkylsulphonylamino, alkoxycarbonylalkoxy, N-azolylalkoxy, optionally substituted alkoxy, optionally substituted phenylalkoxy, hydroxyl or the radical … …, where … … is one equivalent of an alkali metal, alkaline earth metal or organic ammonium ion, R and R are alkyl, halogenoalkyl, alkoxy, halogenoalkoxy or alkylthio, X is oxygen or sulphur, Y and Z are nitrogen or the methine group and R and R are hydrogen, halogen, alkyl, halogenoalkyl, nitro, alkoxy, optionally substituted alkenyloxy, acylamino, alkylamino, dialkylamino or arylamino, process for the preparation thereof and the use thereof for controlling undesired plant growth.

    16.
    发明专利
    未知

    公开(公告)号:DE3841432A1

    公开(公告)日:1990-06-21

    申请号:DE3841432

    申请日:1988-12-09

    Applicant: BASF AG

    Abstract: The invention relates to novel pyridine derivatives, to processes for their preparation and to their use for controlling undesired plant growth. … The pyridine derivatives have the formula … … in which R stands for alkylideneaminoxy which is unsubstituted, or monosubstituted or disubstituted by alkoxy, alkylthio or phenyl, cycloalkylideneaminoxy which is unsubstituted, or monosubstituted or disubstituted by alkyl, succinyliminoxy, or azolyl which is unsubstituted, or monosubstituted or disubstituted by alkyl or halogen, R and R stand for alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio, R stands for hydrogen, halogen, alkyl, haloalkyl or alkoxy and Z stands for nitrogen or the methine group.

    18.
    发明专利
    未知

    公开(公告)号:DE3741273A1

    公开(公告)日:1989-06-15

    申请号:DE3741273

    申请日:1987-12-05

    Applicant: BASF AG

    Abstract: N-Phenyltetrahydrophthalimides of the general formula I … … in which:… R denotes hydrogen or halogen,… R denotes halogen,… A denotes a substituent of the formula … … in which:… X denotes oxygen or sulphur,… n denotes the numbers 0 or 1,… R denotes hydrogen or a C1-C3-alkyl or C1-C6-alkoxycarbonyl optionally substituted by halogen, cyano, hydroxyl, mercapto, C1-C6-alkoxycarbonyl, C1-C4-alkoxy, C1-C4-alkylthio, C3-C6-alkenyloxy, C3-C6-alkenylthio, C3-C6-alkynyloxy, C3-C6-alkynylthio or C1-C4-acyloxy, denotes hydroxyl or carboxyl or denotes a C1-C4-alkoxy-C1-C2-alkyl or C1-C4-alkylthio-C1-C2-alkyl substituted in the alkyl ether or thio ether moiety by C1-C6-alkoxycarbonyl,… R denotes hydrogen or C1-C3-alkyl,… Z denotes methyleneoxymethylene, methylenethiomethylene or ethenylene (-CH=CH-),… R denotes hydrogen or C1-C3-alkyl and… R denotes hydrogen or C1-C3-alkyl, a process for their preparation and their use as herbicides.

    19.
    发明专利
    未知

    公开(公告)号:DE3724395A1

    公开(公告)日:1989-02-02

    申请号:DE3724395

    申请日:1987-07-23

    Applicant: BASF AG

    Abstract: 3-Phenylpropionic acid derivatives of the formula I … … in which… R represents hydrogen or halogen,… R represents halogen,… R represents C2-C6-alkyl which is unsubstituted or substituted by halogen, C1-C4-alkoxy or C1-C4-alkylthio, or represents C1-C6-alkyl which is unsubstituted or substituted by C5-C7-cycloalkyl, furthermore represents C5-C7-cycloalkyl, C3-C6-alkenyl or C3-C6-alkynyl, or together with R represents a C2-C4-alkylene chain,… R represents hydrogen or C2-C6-alkyl which is unsubstituted or substituted by halogen, C1-C4-alkoxy or C1-C4-alkylthio, C1-C6-alkyl which is unsubstituted or substituted by C5-C7-cycloalkyl, or represents C3-C7-cycloalkyl, C3-C6-alkenyl or C3-C6-alkynyl, unsubstituted or substituted by halogen, or represents halogen, or in which R together with R and the carbon atom of this substitutent forms C3-C6-cycloalkyl which can be interrupted by an oxygen atom or a sulphur atom,… R represents C1-C6-alkyl which is unsubstituted or substituted by halogen, C1-C4-alkoxy or C1-C4-alkylthio, cyano or acyl (COR ) or alkoxycarbonyl (CO2R ), where… R is C1-C6-alkyl or together with R is a C3-C5-alkylene chain and… R is C2-C6-alkyl which is unsubstituted or substituted by halogen, C1-C4-alkoxy or C1-C4-alkylthio, or is C1-C6-alkyl which is unsubstituted or substituted by C5-C7-cycloalkyl, or is furthermore C5-C7-cycloalkyl, C3-C6-alkenyl or C3-C6-alkynyl,… with the proviso that R and R cannot simultaneously denote hydrogen when R is cyano or CO2R ,… their preparation, and their use as herbicides.

    20.
    发明专利
    未知

    公开(公告)号:DE3639563A1

    公开(公告)日:1988-06-01

    申请号:DE3639563

    申请日:1986-11-20

    Applicant: BASF AG

    Abstract: Novel N-arylsulfonyl-N'-pyrimidyl-ureas of the formula where A is a radical of the formula where R1 is hydrogen, halogen, cyano, nitro, haloalkyl, alkyl, alkoxy, CO-R4, S(O)m-alkyl or SO2R5, R2 is hydrogen, halogen, methyl, ethyl, methoxy or ethoxy, R3 is hydrogen, halogen, nitro or methoxy, R4 is hydrogen, alkyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, phenoxy, benzyloxy or alkoxy which is unsubstituted or substituted by halogen atoms or alkoxy, R5 is alkoxy, phenoxy or benzyloxy which is unsubstituted or substituted by 1 to 3 halogen atoms, m is one of the integers 0, 1 and 2, R6 is oxygen or sulfur, R7 is hydrogen or alkyl, X is alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or halogen, Y is the methyne group -CH= and Z is azolyl linked via nitrogen, salts of these compounds, and their use for combating the growth of unwanted plants.

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