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公开(公告)号:DE4217509A1
公开(公告)日:1993-12-02
申请号:DE4217509
申请日:1992-05-27
Applicant: BASF AG
Inventor: STAENGLE MICHAEL DR , LAUN MARTIN DR , TESCH HELMUT DR , SCHORNICK GUNNAR DR , ALTSTAEDT VOLKER DR
Abstract: Resin mixts. (I) contain (A) 100 pts.wt. polyfunctional epoxy cpd(s)., (B) 2-206 pts.wt. N-contg. hardener, (C) 3-30 pts.wt. thermoplastic or rubber which is soluble in (A), and (D) 0.3-10 pts.wt. finely divided silica. Pref., (B) is an aromatic diamine or dicyandiamide and thermoplastic (C) is a polyether-sulphone; (D) has specific surface (BET) 50-500 m2/g and particle size 5-50 nm, and is pref. hydrophilic silica. Pref., (A) are diglycidyl ethers of Bisphenol A, Bisphenol F or dicyclopentadienylphenol (e.g., DER 332, Epikote 828, Araldite PY 306, Tactix 556, etc. (RTM)), Araldite MY 721 (RTM: tetraglycidyldiaminodiphenylmethane), triglycidyl-p-amino-phenol or triglycidyltriphenylmethane). (B) is, e.g., 4,4'-diamino-diphenylsulphone (DDS) or dicyandiamide, (C) is polyether-sulphone, (D) is Cab-O-Sil M5 or Aerosil 200 (RTM). USE/ADVANTAGE - Epoxy resin mixts. are used for the prodn. of prepregs for fibre-reinforced composites. Mixts. have improved rheological properties, i.e., relatively constant high viscosity under curing conditions (so that the resin does not run out) combined with a sufficiently low viscosity for the impregnation stage.
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公开(公告)号:DE4039715A1
公开(公告)日:1992-06-17
申请号:DE4039715
申请日:1990-12-13
Applicant: BASF AG
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公开(公告)号:DE3568586D1
公开(公告)日:1989-04-13
申请号:DE3568586
申请日:1985-07-01
Applicant: BASF AG
Inventor: TESCH HELMUT DR , HEYM MANFRED DR , DOERFLINGER WALTER , STUTZ HERBERT DR , NEUMANN PETER DR , NISSEN DIETMAR DR , SCHAEFER GERHARD DR
IPC: C08G59/00 , C08G59/18 , C08G59/50 , C08J3/24 , C08J5/24 , C09D163/00 , C09J163/00
Abstract: A solvent-free curable composition has a long shelf life and consists of A 100 parts by weight of an epoxy resin and B from 10 to 100 parts by weight of, as a curing agent for the epoxy resin, an aromatic diamine containing groups, with or without C from 0.01 to 5 parts by weight of an accelerator, the curing agent for the epoxy resin being finely dispersed in the latter and preferably having a particle size of less than 10 mu m. The preferred epoxy resin curing agent is 4,4'-diaminodiphenyl ketone. The curable composition is used in particular for the preparation of fiber-reinforced materials.
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公开(公告)号:DE3444099A1
公开(公告)日:1986-06-05
申请号:DE3444099
申请日:1984-12-04
Applicant: BASF AG
Inventor: MITULLA KONRAD DR , TESCH HELMUT DR , SCHMITT BURGHARD DR , MAEDER HANS-JOACHIM DR , HAMBRECHT JUERGEN DR
Abstract: High molecular weight polyphenylene ethers are prepared from monohydric phenols by a conventional polycondensation, by a method in which the resulting polymers are reacted with an epoxide of the general formula (I) (I) where R1 and R2 can be identical or different and are each alkyl, cycloalkyl, aryl, aryloxy, alkoxy or carboxyalkyl, each of which may contain a further epoxide group, or C3-C20-alkyl-substituted amino, or R1 is hydrogen and R2 is one of the above groups, or R1 and R2 form part of a cycloalkyl ring.
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公开(公告)号:DE3327823A1
公开(公告)日:1985-02-21
申请号:DE3327823
申请日:1983-08-02
Applicant: BASF AG
Inventor: TESCH HELMUT DR , HENNE ANDREAS DR , HEYM MANFRED DR , STUTZ HERBERT DR
IPC: C07D233/60 , C07D521/00 , C08G59/68 , C08K5/3445 , C08L63/00 , C08G59/40 , C08G59/46 , C08K5/34 , C08J5/00 , C08J5/04
Abstract: A curable composition consisting of A. 100 parts by weight of an epoxy resin, B. from 4 to 100 parts by weight of a conventional curing agent for epoxy resins, and C. from 0.1 to 5 parts by weight of an N-acylimidazole which possesses an aromatic acyl component which is substituted at the two positions ortho to the carbonyl group can be used to produce moldings, coatings, finishes, adhesives and composite fiber materials.
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公开(公告)号:DE19711447A1
公开(公告)日:1998-09-24
申请号:DE19711447
申请日:1997-03-19
Applicant: BASF AG
Inventor: KRAUS RUPERT DR , REIF MARTIN DR , BRUCHMANN BERND DR , TESCH HELMUT DR
IPC: C07C263/10 , C07C265/14 , C08G18/76 , C07C265/12 , C07C263/18
Abstract: Isocyanates (I) having a light colour are produced by reacting an amine with phosgene, the amine being pre-treated with solid inorganic substances (II) containing Lewis acid and/or Bronsted acid centres prior to mixing. Also claimed is a polyurethane prepared from (I).
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公开(公告)号:AT140448T
公开(公告)日:1996-08-15
申请号:AT93117851
申请日:1993-11-04
Applicant: BASF AG
Inventor: LEHRICH FRIEDHELM DR , POHL SIEGMUND , BRUCHMANN BERND DR , TESCH HELMUT DR , MINGES ROLAND DR , SWOBODA JOHANN DR , GENZ MANFRED DR , SCHOLZ GUENTER DR , STREU JOACHIM DR
IPC: C07C265/10 , C07C265/12 , C07C267/00 , C08G18/00 , C08G18/02 , C08G18/71 , C08K5/29
Abstract: The invention relates to novel 4,4'-disubstituted bis(2,6-diisopropylphenyl)carbodiimides of the formula (I) in which R is a 1-methyl-1-phenylethyl, phenoxy or tert-butyl radical, to a process for their preparation and to their use as stabilisers with respect to the hydrolytic degradation of ester group-containing products of addition and condensation polymerisation, and to the novel compounds which can be used to prepare them, namely 4-(1-methyl-1-phenylethyl)-2,6-diisopropylphenyl, 4-phenoxy-2,6-diisopropylphenyl and 4-tert-butyl-2,6-diisopropylphenyl isocyanates.
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公开(公告)号:AT70847T
公开(公告)日:1992-01-15
申请号:AT85115150
申请日:1985-11-29
Applicant: BASF AG
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公开(公告)号:DE3842306A1
公开(公告)日:1990-06-21
申请号:DE3842306
申请日:1988-12-16
Applicant: BASF AG
Inventor: WEBER THOMAS DR , HECKMANN WALTER DR , MERTES JUERGEN DR , TESCH HELMUT DR , ALTSTAEDT VOLKER DR , EBERLE WOLFGANG DR , FOLDA THOMAS DR , STUTZ HERBERT DR , RECKER HANS-GERT DR
Abstract: The invention relates to curable, impact-modified epoxy resin mixtures comprising A. an aromatic epoxide compound, B. an amine curing agent, C. 10 to 40 % by weight of an aromatic, thermoplastic oligomer containing reactive groups, preferably a polyether sulfone, and D. 0.1 to 10 % by weight of a high-molecular-weight emulsifier, preferably a phenoxy resin, an epoxy resin or a thermoplastic copolymer, which is compatible both with the epoxide compound A and with the oligomer C. The epoxy resin mixtures are suitable for the production of high-performance composite materials.
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公开(公告)号:DE3802979A1
公开(公告)日:1989-08-10
申请号:DE3802979
申请日:1988-02-02
Applicant: BASF AG
Inventor: GERTH DALE DR , ITTEMANN PETER DR , TESCH HELMUT DR
Abstract: The heat-curable resin composition comprises… A) a polyfunctional, aromatic ester of cyanic acid,… B) a monofunctional, aromatic ester of cyanic acid,… C) a thermoplastic polymer,… D) optionally a bismaleimide and… E) optionally an epoxy resin.
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