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公开(公告)号:DE50307656D1
公开(公告)日:2007-08-23
申请号:DE50307656
申请日:2003-05-21
Applicant: BASF AG
Inventor: WULFF DIRK , FELDTHUSEN JENSEN JESPER , AUCHTER GERHARD , WILDBURG GERALD , FINK RALF
IPC: C08F285/00 , C08F2/22 , C08F257/02 , C08F265/04 , C08F291/00 , C08L51/00 , C09J151/00
Abstract: The invention relates to a method for producing an aqueous polymer dispersion having a polymer solids content of >=50% by weight by carrying out the radically initiated aqueous emulsion polymerization of ethylenically unsaturated compounds (monomers). The inventive method is characterized in that: a) a mixture is provided in a polymerization vessel and contains a partial quantity 1 consisting of: deionized water, 0.001 to 0.5 parts by weight of a polymer with a weighted average particle diameter of =80% [polymerization step A], and; b) afterwards, a monomer emulsion containing partial quantity 2, which consists of deionized water, 0.1 to 5 parts by weight of dispersants and 90 to 99.5 parts by weight of monomers, is fed under polymerization conditions to the obtained reaction mixture [polymerization step B], whereby; c) the total amount of the monomers used for the polymerization is equal to 100 parts by weight, and the total amount of deionized water is
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公开(公告)号:ES2261687T3
公开(公告)日:2006-11-16
申请号:ES02742906
申请日:2002-04-20
Applicant: BASF AG
Inventor: WULFF DIRK , JAHNS EKKEHARD , ROCKEL HARALD , SCHEHLMANN VOLKER
Abstract: Procedimiento para la obtención de microcápsulas con un núcleo de cápsula que contiene substancias hidrosolubles orgánicas, y una envoltura de cápsula que es un condensado de resinas de formaldehído, y/o sus éteres alquílicos, mediante condensación de resinas de formaldehído en la fase hidrófila de una emulsión de agua en aceite en presencia de un coloide de protección, caracterizado porque el coloide de protección es un polímero de injerto que es obtenible mediante injerto de polímeros (A) a partir de a) un 40 a un 95 % en peso de mónomeros aromáticos monovinílicos, b) un 5 a 60 % en peso de ácidos carboxilícos con insaturación monoetilénica con 3 a 6 átomos de carbono, anhídrido de ácido maléico y/o anhídrido de ácido itacónico, y c) un 0 a un 20 % en peso de otros mónomeros con insaturación monoetilénica, con la condición de que la suma de porcentajes ponderales (a) a (c) ascienda siempre a 100, y los polímeros A) presenten un peso molecular (media numérica) de 500 a 20.000, con mezclasde mónomeros constituidas por a) un 70 a un 100 % en peso de acrilato y/o metacrilato de alcoholes monovalentes que contienen 1 a 20 átomos de carbono, b) un 0 a un 15 % en peso de ácidos carboxilícos con insaturación monoetilénica con 3 a 6 átomos de carbono, anhídrido de ácido maléico y/o anhídrido de ácido itacónico, c) un 0 a un 10 % en peso de monoacrilato y/o monometacrilato de alcoholes al menos divalentes, d) un 0 a un 15 % en peso de mónomeros aromáticos monovinílicos, y e) un 0 a un 7, 5 % en peso de acrilamida y/o metacrilamida, con la condición de que la suma de porcentajes ponderales a) a e) ascienda siempre a 100, empleándose los mónomeros en una cantidad de un 97, 5 a un 50 % en peso, referido a la mezcla de polímero A) y mónomeros.
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公开(公告)号:DE102004058070A1
公开(公告)日:2006-06-08
申请号:DE102004058070
申请日:2004-12-01
Applicant: BASF AG
Inventor: SCHUMACHER KARL-HEINZ , JUNG MARTIN , RUCKPAUL MARKUS , WULFF DIRK , DUESTERWALD UWE
IPC: C09J133/12 , C08J3/24 , C08J5/12 , C09J7/02
Abstract: Disclosed is a radiation-curable polymer that is composed of a) at least 60 percent by weight of C1 to C 18 alkyl (meth)acrylates, b) 3 to 8 percent by weight of at least one ethylenically unsaturated acid, c) 0.10 to 0.23 percent by weight of an ethylenically unsaturated, copolymerizable photoinitiator, and d) 0 to 30 additional monomers.
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公开(公告)号:DE50206386D1
公开(公告)日:2006-05-24
申请号:DE50206386
申请日:2002-04-20
Applicant: BASF AG
Inventor: WULFF DIRK , JAHNS EKKEHARD , ROECKEL HARALD , SCHEHLMANN VOLKER
Abstract: Microcapsules having a capsule core comprising water-soluble organic substances, and a capsule coating which is a condensate of formaldehyde resins and/or alkyl ethers thereof, a process for their preparation, their use, and compositions comprising the microcapsules.
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公开(公告)号:AU2003247284A1
公开(公告)日:2003-12-12
申请号:AU2003247284
申请日:2003-05-21
Applicant: BASF AG
Inventor: WULFF DIRK , JENSEN JESPER FELDTHUSEN , AUCHTER GERHARD , WILDBURG GERALD , FINK RALF
IPC: C08F2/22 , C08F257/02 , C08F265/04 , C08F285/00 , C08F291/00 , C08L51/00 , C09J151/00
Abstract: The invention relates to a method for producing an aqueous polymer dispersion having a polymer solids content of >=50% by weight by carrying out the radically initiated aqueous emulsion polymerization of ethylenically unsaturated compounds (monomers). The inventive method is characterized in that: a) a mixture is provided in a polymerization vessel and contains a partial quantity 1 consisting of: deionized water, 0.001 to 0.5 parts by weight of a polymer with a weighted average particle diameter of =80% [polymerization step A], and; b) afterwards, a monomer emulsion containing partial quantity 2, which consists of deionized water, 0.1 to 5 parts by weight of dispersants and 90 to 99.5 parts by weight of monomers, is fed under polymerization conditions to the obtained reaction mixture [polymerization step B], whereby; c) the total amount of the monomers used for the polymerization is equal to 100 parts by weight, and the total amount of deionized water is
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公开(公告)号:DE10134491A1
公开(公告)日:2003-01-02
申请号:DE10134491
申请日:2001-06-25
Applicant: BASF AG
Inventor: WULFF DIRK , JAHNS EKKEHARD
Abstract: Microcapsules (I) comprise a core, containing a water soluble organic substance, and a capsule sheath that is a condensate of formaldehyde resins and/or their alkylethers. Independent claims are also included for: (i) a process for the production of the microcapsules (I) by condensation of the formaldehyde resins in the hydrophilic phase of a water-in-oil emulsion in the presence of a protective colloid; and (ii) polymer compositions comprising 0.1-50 wt.% microcapsules (I) containing water soluble coloring agents or conventional additives.
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公开(公告)号:DE10120480A1
公开(公告)日:2002-10-31
申请号:DE10120480
申请日:2001-04-25
Applicant: BASF AG
Inventor: WULFF DIRK , JAHNS EKKEHARD
IPC: B01J13/18 , B01J13/20 , B01J13/02 , A61K9/50 , C08J3/20 , C09D5/06 , C09D151/06 , C09D161/28
Abstract: Microcapsules (I) comprise a core, containing a water soluble organic substance, and a capsule sheath that is a condensate of formaldehyde resins and/or their alkylethers. Independent claims are also included for: (i) a process for the production of the microcapsules (I) by condensation of the formaldehyde resins in the hydrophilic phase of a water-in-oil emulsion in the presence of a protective colloid; and (ii) polymer compositions comprising 0.1-50 wt.% microcapsules (I) containing water soluble coloring agents or conventional additives.
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公开(公告)号:DE10034893A1
公开(公告)日:2002-01-31
申请号:DE10034893
申请日:2000-07-18
Applicant: BASF AG
Inventor: KOLTZENBURG SEBASTIAN , WULFF DIRK , ROECKEL HARALD , SCHROF WOLFGANG , ROSSMANITH PETER , MAECHTLE WALTER
Abstract: The invention relates to combinatory methods for producing an array of n aqueous polymer dispersions by emulsion polymerization and for producing an array of m formulations of polymer dispersions, in addition to the arrays themselves. The methods are carried out at n or m spatially separated locations for the n or m formulations. To carry out the emulsion polymerization, monomers, an initiator, a dispersant and optionally additional components are reacted with one another in water, which acts as the reaction medium. To produce the formulations, aqueous polymer dispersions are mixed with other aqueous polymer dispersions and/or additional components. In all methods, each one of the n or m formulations differs from the other formulation in at least one respective parameter, which can influence the characteristics of the polymer dispersions or formulations that are obtained. The advantage of the invention is that said method allows a large number of aqueous polymer dispersions and formulations to be produced and characterized. This accelerates the development of aqueous polymer dispersions and formulations with optimized characteristics.
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公开(公告)号:BRPI0517066A
公开(公告)日:2008-09-30
申请号:BRPI0517066
申请日:2005-10-27
Applicant: BASF AG
Inventor: SCHICKER PETRA , WIDMAIER RALF , MUELLER BETTINA , WULFF DIRK , GERNERT PETER , KORB HARDY
Abstract: The present invention relates to microcapsule dispersions comprising microcapsules in a hydrophobic solvent, wherein the microcapsules have a capsule core, comprising a water-soluble organic substance, and a capsule shell which is composed essentially of reaction products of polyisocyanates with polyfunctional amines, and also to a process for preparing them and additionally to microcapsules obtainable from the corresponding microcapsule dispersions.
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公开(公告)号:BR0211818A
公开(公告)日:2004-07-27
申请号:BR0211818
申请日:2002-08-06
Applicant: BASF AG
Inventor: WULFF DIRK , JAHNS EKKEHARD , SCHEHLMANN VOLKER
IPC: A61K8/30 , A61K8/11 , A61K8/14 , A61K8/37 , A61K8/72 , A61Q1/00 , B01J13/16 , C08G18/28 , C08G18/32 , C08G18/36 , C09D17/00 , C09K23/34 , C08G18/79
Abstract: The present invention relates to microcapsule dispersions comprising microcapsules having a capsule core comprising water-soluble organic substances, and a capsule coating which essentially consists of polyurethane and/or polyurea, in a hydrophobic solvent which consists of 50 to 100% by weight of glycerol ester oils and 0 to 50% by weight of solvents miscible with glycerol ester oils, and to a process for their preparation.
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