公开(公告)号：DE102010041026A1

公开(公告)日：2011-03-24

申请号：DE102010041026

申请日：2010-09-20

Applicant: BASF SE

Inventor： BACKES RENE ,  WLOKA VERONIKA

IPC: C07B43/00 ,  C07B41/04 ,  C07D207/267

公开(公告)号：ZA201801041B

公开(公告)日：2021-04-28

申请号：ZA201801041

申请日：2018-02-15

Applicant: BASF SE

Inventor： GORDILLO ALVARO ,  WERHAN HOLGER ,  DEHN RICHARD ,  BLANK BENOIT ,  TELES JOAQUIM HENRIQUE ,  SCHUNK STEPHAN A ,  PIEPENBRINK MARKUS ,  BACKES RENE ,  ZHANG LEI

Abstract: A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5′-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

公开(公告)号：CA3003764A1

公开(公告)日：2017-05-11

申请号：CA3003764

申请日：2016-11-03

Applicant: BASF SE

Inventor： GORDILLO ALVARO ,  BOHN MARTIN ALEXANDER ,  SCHUNK STEPHAN A ,  JEVTOVIKJ IVANA ,  WERHAN HOLGER ,  DUFERT SVENIA ,  PIEPENBRINK MARKUS ,  BACKES RENE ,  DEHN RICHARD

IPC: C07D307/46

Abstract: The present invention relates to a process for preparing a mixture comprising 5-(hydroxy- methyl)furfural (HMF) and one or more HMF esters of formula (I, the process comprising the following steps: (A-1) preparing or providing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, and as the solvent or as a co-solvent for said carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II) (A-2) subjecting said starting mixture to reaction conditions so that at least one of said one, two or more carbohydrate compounds reacts, and a fraction of said amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results comprising 5-(hydroxymethyl)furfural and/or said one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of said amount of one or more carboxylic acid esters of formula (II) wherein the starting mixture prepared or provided in step (A-1) comprises a total amount of carboxylic acid esters of formula (II) of at least 50 wt.-%, based on the total weight of the starting mixture.

公开(公告)号：CA2856864A1

公开(公告)日：2013-06-20

申请号：CA2856864

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENE ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: A process for preparing 5-hydroxymethylfurfural (HMF), characterized in that a) solutions (called starting solution hereinafter) comprising a hexose and an organic solvent having a boiling point greater than 200°C (at standard pressure) (called high boilers for short) and steam are supplied to a reaction vessel, b) a conversion of the hexose to HMF in the presence of steam with simultaneous distillative removal of the HMF is effected in the reaction vessel and c) the distillate obtained is an aqueous, HMF-containing solution (called distillate hereinafter).

公开(公告)号：CA2856466A1

公开(公告)日：2013-06-20

申请号：CA2856466

申请日：2012-12-11

Applicant: BASF SE

Inventor： BACKES RENE ,  BLANK BENOIT ,  KINDLER ALOIS ,  FELDNER CARMEN

IPC: C07D307/46

Abstract: A process for preparing 5-hydroxymethylfurfural (HMF), characterized in that a) solutions (called starting solution hereinafter) comprising one or more saccharides and an organic solvent having a boiling point greater than 200°C (at standard pressure) (called high boiler for short) and water and a solvent having a boiling point greater than 60°C and less than 200°C (at standard pressure, called low boiler for short) are supplied to a reaction vessel, b) a conversion of the hexose to HMF in the presence of steam with simultaneous distillative removal of the HMF is effected in the reaction vessel and c) the distillate obtained is an aqueous, HMF containing solution (called distillate hereinafter).

公开(公告)号：AT478060T

公开(公告)日：2010-09-15

申请号：AT08761344

申请日：2008-06-24

Applicant: BASF SE

Inventor： WABNITZ TOBIAS ,  BREUNINGER DANIEL ,  HEIMANN JENS ,  BACKES RENE ,  PINKOS ROLF

IPC: C07D307/06

Abstract: The present invention provides a process for preparing 2-methyltetrahydrofuran by one-stage hydrogenation of furfural with a hydrogen-comprising gas in the presence of a structured bed of at least one copper catalyst and at least one catalyst which comprises at least one noble metal from groups 8, 9 and/or 10 of the periodic table of the elements applied on a support material.

公开(公告)号：EP2643281A4

公开(公告)日：2014-06-04

申请号：EP11843794

申请日：2011-11-21

Applicant: BASF SE

Inventor： BONNEKESSEL MELANIE ,  DITRICH KLAUS ,  DÄUWEL JÜRGEN ,  SORG ACHIM ,  LADNER WOLFGANG ,  COOPER BRYAN ,  BACKES RENE

IPC: C12P41/00 ,  C07C35/08 ,  C12N11/14 ,  C12P7/02

CPC classification number: C12N11/14 ,  C12P7/02 ,  C12P41/004 ,  C12Y301/01003