MATERIAL ESTRUCTURAL POROSO METALO-ORGANICO A BASE DE PIRROLES Y PIRIDINONAS.

    公开(公告)号:ES2334851T3

    公开(公告)日:2010-03-16

    申请号:ES07729020

    申请日:2007-05-11

    Applicant: BASF SE

    Abstract: Proceso para la preparación de un material estructural metal orgánico poroso que contiene al menos un compuesto orgánico enlazado de manera coordinada con al menos un ión metálico, que comprende el paso de oxidación de al menos un ánodo que contiene un metal correspondiente a al menos un ión metálico en un medio de reacción en presencia del, al menos uno, compuesto orgánico, y el, al menos uno, compuesto orgánico es un sistema de anillo que se selecciona del grupo compuesto de **(Ver fórmula)** donde el sistema de anillo no está sustituido tiene uno o varios sustituyente seleccionados independientemente del grupo compuesto de halógeno, alquilo de C1-6, fenilo, NH2, NH(alquilo de C1-6), N(alquilo de C1-6)2, OH, Ofenilo y Oalquilo de C1-6, donde los sustituyentes alquilo de C1-6 y fenilo no están sustituidos o tienen uno o más sustituyentes seleccionados independientemente del grupo que se compone de halógeno, NH2, NH(alquilo de C1-6), N(alquilo de C1-6)2, OH, Ofenilo y Oalquilo de C1-6 y donde el metal es cinc.

    PROCESS FOR THE INDUSTRIAL ISOLATION OF PROPENE

    公开(公告)号:CA2728314A1

    公开(公告)日:2010-01-28

    申请号:CA2728314

    申请日:2009-07-17

    Applicant: BASF SE

    Abstract: The present invention relates to a method for technical extraction of propene from a gas stream containing at least propene and propane, the step comprising bringing the gas stream into contact with an adsorbent material comprising a porous metal-organic structural material containing at least one at least bidentate organic compound that is coordinatively bonded to at least one metal ion, wherein the adsorbent material becomes loaded up with propane and the gas stream thereby exhibits an elevated propene content, wherein the at least bidentate organic component is an imidazolate that is unsubstituted or that contains one or more substituents independently selected from the group consisting of halogen, C1-6 alkyl, phenyl, NH2, NH(C1-6 alkyl), N(C1-6 alkyl)2, OH, O-phenyl and O-C1-6 alkyl. The present invention also relates to the use of such a porous metal-organic structural material for technical extraction of propene from a gas stream containing at least propene and propane by way of propane depletion of the gas stream.

    13.
    发明专利
    未知

    公开(公告)号:DE502007001988D1

    公开(公告)日:2009-12-24

    申请号:DE502007001988

    申请日:2007-05-11

    Applicant: BASF SE

    Abstract: Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls.

    14.
    发明专利
    未知

    公开(公告)号:AT448334T

    公开(公告)日:2009-11-15

    申请号:AT07729020

    申请日:2007-05-11

    Applicant: BASF SE

    Abstract: Processes comprising: (i) providing an anode comprising zinc; and (ii) oxidizing the anode in a reaction medium in the presence of at least one organic compound to form a porous metal organic framework comprising the least one organic compound coordinated to at least one zinc ion; wherein the at least one organic compound comprises a ring system selected from the group consisting of compounds corresponding to the following structures wherein the ring system optionally bears one or more substituents selected independently from the group consisting of halogens, C1-6-alkyls, phenyl, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls, and wherein each C1-6-alkyl and phenyl substituent may independently and optionally bear one or more substituents selected independently from the group consisting of halogens, NH2, NH(C1-6-alkyls), N(C1-6-alkyls)2, OH, O-phenyl and O-C1-6-alkyls.

    MAGNESIUM BUTYLISOPHTHALATE AS POROUS METAL ORGANIC FRAMEWORK

    公开(公告)号:CA2668619A1

    公开(公告)日:2008-05-15

    申请号:CA2668619

    申请日:2007-11-05

    Applicant: BASF SE

    Abstract: The present invention relates to a porous metal organic framework materia l formed of Mg2+ ions which is coordinatively bonded by 5-tert.-butylisophth alate ions, during formation of a framework structure. The invention also re lates to methods for the production and application thereof, for example, fo r storage, separation, or the controlled release of a substance such as a ga s or gas mixture.

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