公开(公告)号：ZA9710682B

公开(公告)日：1998-07-17

申请号：ZA9710682

申请日：1997-11-27

Applicant: CLOROX CO

Inventor： ALVAREZ VINCENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D ,  C07D

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：AU5686998A

公开(公告)日：1998-06-22

申请号：AU5686998

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G ,  MITCHELL JAMES D

IPC: C07D295/14 ,  C01B13/02 ,  C07D295/02 ,  C07D295/15 ,  C11D1/62 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/00 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34

Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butyl morpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is contacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.

公开(公告)号：CA2273093A1

公开(公告)日：1998-06-04

申请号：CA2273093

申请日：1997-11-18

Applicant: BASF AG ,  CLOROX CO

Inventor： CASELLA VICTOR M ,  CHOY CLEMENT K ,  PERKINS SARAH A ,  SMITH WILLIAM L ,  KLOTTER KEVIN A ,  PETERSON DAVID ,  BROCKEL ULRICH ,  ZIELSKE ALFRED G ,  PETRIN MICHAEL J ,  PHILLIPPI MARTIN A ,  FOLAND LAFAYETTE D ,  HUESTIS SUSAN P ,  SCHONHERR MICHAEL ,  DELINE JAMES E ,  KAARET THOMAS W ,  SEELMANN-EGGEBERT HANS PETER ,  SIBERT WILLIAM P

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/12 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/06 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  B29C59/00 ,  B29C67/00 ,  C07D265/12 ,  C07D295/12 ,  C07D211/26 ,  C07D295/26 ,  C07D211/34 ,  C11D7/38 ,  D04H1/64

Abstract: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of formula (I), wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, aluminum silicate, or mixtures thereof.

公开(公告)号：CZ9700622A3

公开(公告)日：1997-07-16

申请号：CZ62297

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

CPC classification number: C07D295/15 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  D06L4/12 ,  D06L4/17 ,  H04B7/0619

公开(公告)号：TR9600485A2

公开(公告)日：1996-12-21

申请号：TR9600485

申请日：1996-06-07

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

CPC classification number: C07D295/15 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  D06L4/12 ,  D06L4/17 ,  H04B7/0619

公开(公告)号：MX217641B

公开(公告)日：2003-11-18

申请号：MX9905080

申请日：1999-05-31

Applicant: CLOROX CO

Inventor： DELINE JAMES E ,  ZIELSKE ALFRED G ,  SUDBURY BARRY A ,  SMITH WILLIAM L ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  ALVAREZ VINCENT E ,  FOLAND LAFAYETTE D

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：AU1881402A

公开(公告)日：2002-04-18

申请号：AU1881402

申请日：2002-02-28

Applicant: BASF AG ,  CLOROX CO

Inventor： CASELLA VICTOR M ,  ZIELSKE ALFRED G ,  SMITH WILLIAM L ,  SEELMANN-EGGEBERT HANS PETER ,  SCHONHERR MICHAEL ,  SIBERT WILLIAM P ,  PHILLIPPI MARTIN A ,  PETRIN MICHAEL J ,  PETERSON DAVID ,  PERKINS SARAH A ,  KLOTTER KEVIN A ,  HUESTIS SUSAN P ,  FOLAND LAFAYETTE D ,  DELINE JAMES E ,  CHOY CLEMENT K ,  BROCKEL ULRICH

IPC: B29C59/00 ,  B29C67/00 ,  C01B3/00 ,  C07D211/26 ,  C07D211/34 ,  C07D265/12 ,  C07D295/12 ,  C07D295/26 ,  C11D3/39 ,  C11D7/38 ,  D04H1/64

公开(公告)号：BR9714879A

公开(公告)日：2000-10-17

申请号：BR9714879

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KLOTTER KEVIN A ,  LLER JOSEPH M ,  LLER MICHAEL M ,  NDINGER KLAUS M ,  PHILLIPPI MARTIN A ,  RULAND ALFRED ,  SCHOFER WOLFGANG ,  RMANN GREGOR SCH ,  WIDDER RUDI ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D265/12 ,  C07D291/00 ,  C07D295/15 ,  C11D3/39 ,  C07D295/12 ,  C07D211/26 ,  C07D211/34

Abstract: A process for the preparation of a compound having the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of a pH control substantially prevents formation of an undesirable protonated intermediate.

公开(公告)号：MX9905076A

公开(公告)日：2000-04-30

申请号：MX9905076

申请日：1999-05-31

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KLOTTER KEVIN A ,  MUELLER JOSEF ,  MUELLER MICHAEL ,  MUENDINGER KLAUS ,  PHILLIPPI MARTIN A ,  RULAND ALFRED ,  SCHAEFER WOLFGANG ,  SCHUERMANN GREGOR ,  WIDDER RUDI ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D265/12 ,  C07D291/00 ,  C07D295/15 ,  C11D3/39

Abstract: A process for the preparation of a compound having the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of a pH control substantially prevents formation of an undesirable protonated intermediate.

公开(公告)号：ZA9710684B

公开(公告)日：1998-07-22

申请号：ZA9710684

申请日：1997-11-27

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  KLOTTER KEVIN A ,  MULLER MICHAEL ,  MUNDINGER KLAUS ,  PERKINS SARAH A ,  PHILIPPI MARTIN A ,  SCHOLTISSEK MARTIN ,  SCHONHERR MICHAEL ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/39 ,  C11D3/395 ,  D06L3/02 ,  D06L4/12 ,  C11D ,  C07D

Abstract: A substantially solid composition, the composition having therein a compound with the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure.